GB387398A - Process for the manufacture of wetting, cleaning and emulsifying agents - Google Patents

Process for the manufacture of wetting, cleaning and emulsifying agents

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Publication number
GB387398A
GB387398A GB22802/31A GB2280231A GB387398A GB 387398 A GB387398 A GB 387398A GB 22802/31 A GB22802/31 A GB 22802/31A GB 2280231 A GB2280231 A GB 2280231A GB 387398 A GB387398 A GB 387398A
Authority
GB
United Kingdom
Prior art keywords
glycerine
sulphonated
ethers
fatty acids
esterification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22802/31A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of GB387398A publication Critical patent/GB387398A/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)

Abstract

Fatty acids containing at least ten carbon atoms in the molecule are sulphonated, before, during or after esterification with monoaryl or monoaralkyl ethers of glycol, mono- or di-aryl or aralkyl ethers of glycerine or glycerine mono, aryl- or aralkyl ethers which contain besides one free hydroxy group, one halogen atom. Similar products may be obtained by starting with esters of polyhydric alcohols completely esterified with fatty acids containing at least ten carbon atoms, and effecting esterification with the said glycol or glycerine ethers before, during or after sulphonation. In an example, oleic acid after esterification with glycerine monoxylenol ether is sulphonated with sulphuric monohydrate. Products are also obtained by (1) sulphonating oleic benzylglycol ester, (2) treating a mixture of olive oil and glycerine monoxylenol ether with sulphuric acid and (3) treating a mixture of coconut oil and glycerinemonoxylenol ether with sulphuric acid. The products are stated to be wetting, cleansing and emulsifying agents which may be used in the textile, leather, paper and allied industries. The Specification as open to inspection under Sect. 91 comprises also the production of sulphonated esters derived from any polyhydric alcohol containing alkyloxy, aryloxy, aralkyloxy or alkylcarboxylate residues. Esters of higher fatty acids with polyhydric alcohols, containing a hydroxy group in the alcoholic residue may also be sulphonated and then treated with alkylating, arylating and aralkylating agents. This subject-matter does not appear in the Specification as accepted.ALSO:Products stated to be emulsifying agents are obtained when fatty acids containing at least ten carbon atoms in the molecule are sulphonated, before, during or after esterification with monoaryl or monoaralkyl ethers of glycol, mono or di-aryl or aralkyl ethers of glycerine, or glycerine monoaryl or aralkyl ethers which contain besides one free hydroxy group, one halogen atom. Similar products may be obtained by starting with esters of polyhydric alcohols completely esterified with fatty acids containing at least ten carbon atoms and effecting esterification with the said glycol or glycerine ethers before, during or after sulphonation. In an example, oleic acid after esterification with glycerine monoxylenol ether is sulphonated with sulphuric monohydrate. Products are also obtained by (1) sulphonating oleic benzylglycolester, (2) treating a mixture of olive oil and glycerinemonoxylenolether with sulphuric acid and (3) treating a mixture of coconut-oil and glycerinemonoxylenolether with sulphuric acid. The Specification as open to inspection under Sect. 91 comprises also the production of sulphonated esters derived from any polyhydric alcohol containing alkyloxy, aryloxy, aralkyloxy or alkylcarboxylate residues. Esters of higher fatty acids with polyhydric alcohols, containing a hydroxy group in the alcoholic residue may also be sulphonated and then treated with alkylating, arylating and aralkylating agents. This subject-matter does not appear in the Specification as accepted.
GB22802/31A 1930-12-05 1931-08-12 Process for the manufacture of wetting, cleaning and emulsifying agents Expired GB387398A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH387398X 1930-12-05

Publications (1)

Publication Number Publication Date
GB387398A true GB387398A (en) 1933-02-09

Family

ID=4513840

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22802/31A Expired GB387398A (en) 1930-12-05 1931-08-12 Process for the manufacture of wetting, cleaning and emulsifying agents

Country Status (1)

Country Link
GB (1) GB387398A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4545939A (en) * 1983-07-01 1985-10-08 Lion Corporation Process for producing sulfonate of unsaturated fatty acid ester

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4545939A (en) * 1983-07-01 1985-10-08 Lion Corporation Process for producing sulfonate of unsaturated fatty acid ester

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