GB357670A - Manufacture of sulphonated fatty-acid derivatives - Google Patents

Manufacture of sulphonated fatty-acid derivatives

Info

Publication number
GB357670A
GB357670A GB2089930A GB2089930A GB357670A GB 357670 A GB357670 A GB 357670A GB 2089930 A GB2089930 A GB 2089930A GB 2089930 A GB2089930 A GB 2089930A GB 357670 A GB357670 A GB 357670A
Authority
GB
United Kingdom
Prior art keywords
oleum
sulphonated
acetic anhydride
acid
anhydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2089930A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2089930A priority Critical patent/GB357670A/en
Publication of GB357670A publication Critical patent/GB357670A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Unsaturated hydroxy fatty oils, or the free fatty acids derived therefrom are first acylated in known manner, and then sulphonated by means of oleum, in the presence or absence of an organic acid anhydride. The products are used as emulsifying agents. In examples: (1) castor oil is acetylated by heating under reflux, with acetic anhydride, and sulphonated with oleum, or with a mixture of oleum and acetic anhydride; (2) ricinoleic acid is benzoylated and then sulphonated with a mixture of acetic anhydride and oleum.ALSO:Sulphonated fatty acid derivatives.-An unsaturated hydroxy fatty oil, or the free fatty acid derived therefrom is first acylated in known manner e.g. by means of an acid anhydride or chloride, and is then sulphonated with oleum, in the presence or absence of an organic acid anhydride. The products are wetting, cleansing and emulsifying agents, and are stable to alkalies, alkaline earths and to acids. In examples: (1) Castor oil is acetylated by heating, under reflux, with acetic anhydride, and after removal of the resulting acetic acid and the excess acetic anhydride is sulphonated with oleum or with a mixture of oleum and acetic anhydride; (2) ricinoleic acid is benzoylated by treatment with benzoyl chloride and caustic soda, and, after separation, is sulphonated with a mixture of acetic anhydride and oleum. According to the Provisional Specification any sulphonating agent may be employed and ketenes are mentioned as suitable acylating agents.
GB2089930A 1930-07-10 1930-07-10 Manufacture of sulphonated fatty-acid derivatives Expired GB357670A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2089930A GB357670A (en) 1930-07-10 1930-07-10 Manufacture of sulphonated fatty-acid derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2089930A GB357670A (en) 1930-07-10 1930-07-10 Manufacture of sulphonated fatty-acid derivatives

Publications (1)

Publication Number Publication Date
GB357670A true GB357670A (en) 1931-10-01

Family

ID=10153651

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2089930A Expired GB357670A (en) 1930-07-10 1930-07-10 Manufacture of sulphonated fatty-acid derivatives

Country Status (1)

Country Link
GB (1) GB357670A (en)

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