GB359116A - Improvements in or relating to the manufacture of products resembling turkey red oils - Google Patents
Improvements in or relating to the manufacture of products resembling turkey red oilsInfo
- Publication number
- GB359116A GB359116A GB2549430A GB2549430A GB359116A GB 359116 A GB359116 A GB 359116A GB 2549430 A GB2549430 A GB 2549430A GB 2549430 A GB2549430 A GB 2549430A GB 359116 A GB359116 A GB 359116A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- catalyst
- products
- sulphonation
- effected
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
Products, which are stated to be wetting, penetrating, and emulsifying agents for use in the textile, leather, paper, and soap industries are prepared by sulphonating naphthenic acids or their esters after they have been treated with reducing agents. After the reduction, the saponifiable constituents may be removed prior to the sulphonation. In examples: (1) crude naphthenic acid is esterified with n-butyl alcohol and reduced in an autoclave with sodium and butyl alcohol. Saponifiable products are removed, and sulphonation effected with a mixture of sulphuric and chlorsulphonic acids: (2) crude naphthenic acid, together with carbon monoxide, is passed over a catalyst comprising manganous oxide and/or an element of Group VI, and the reduced product together with hydrogen passed over a second catalyst comprising nickel or nickelous oxide. The sulphonating agent employed contains acetic anhydride.ALSO:Products, which are stated to be wetting, penetrating and emulsifying agents for use in the textile, leather, paper, and soap industries are prepared by sulphonating naphthenic acids such as are obtained in the refining of petroleum with alkali, or their esters after they have been treated with reducing agents. The reduction may be effected by means of an alkali metal in the presence of an alcoholic solvent or by means of carbon monoxide or formic acid with or without a catalyst. After the reduction, the saponifiable constituents may be removed prior to the sulphonation, which may be effected with sulphuric acid, oleum or chlorsulphonic acid, possibly in the presence of diluents, e.g. carbon tetrachloride and/or dehydrating agents. In examples: (1) crude naphthenic acid is esterified with n-butyl alcohol and hydrochloric acid, and reduced in an autoclave with sodium and butyl alcohol. Saponifiable products are removed, and sulphonation effected with a mixture of sulphuric and chlorsulphonic acids: (2) crude naphthenic acid together with carbon monoxide is passed over a catalyst comprising manganous oxide and/or an element of Group VI, and the reduced product together with hydrogen passed over a second catalyst comprising nickel or nickelous oxide. The sulphonating agent employed contains acetic anhydride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2549430A GB359116A (en) | 1930-08-26 | 1930-08-26 | Improvements in or relating to the manufacture of products resembling turkey red oils |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2549430A GB359116A (en) | 1930-08-26 | 1930-08-26 | Improvements in or relating to the manufacture of products resembling turkey red oils |
Publications (1)
Publication Number | Publication Date |
---|---|
GB359116A true GB359116A (en) | 1931-10-22 |
Family
ID=10228594
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2549430A Expired GB359116A (en) | 1930-08-26 | 1930-08-26 | Improvements in or relating to the manufacture of products resembling turkey red oils |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB359116A (en) |
-
1930
- 1930-08-26 GB GB2549430A patent/GB359116A/en not_active Expired
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