GB385646A - Improved manufacture of a red pigment of iron oxide - Google Patents
Improved manufacture of a red pigment of iron oxideInfo
- Publication number
- GB385646A GB385646A GB19794/31A GB1979431A GB385646A GB 385646 A GB385646 A GB 385646A GB 19794/31 A GB19794/31 A GB 19794/31A GB 1979431 A GB1979431 A GB 1979431A GB 385646 A GB385646 A GB 385646A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ferric
- iron
- hydroxide
- under pressure
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000001054 red pigment Substances 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 150000004679 hydroxides Chemical class 0.000 abstract 4
- 150000002506 iron compounds Chemical class 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 239000001034 iron oxide pigment Substances 0.000 abstract 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000012266 salt solution Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 229960004887 ferric hydroxide Drugs 0.000 abstract 1
- 229940056319 ferrosoferric oxide Drugs 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/06—Ferric oxide [Fe2O3]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Iron (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
A process of obtaining iron oxide pigments by heating under pressure iron compounds after moistening with dilute ferric salt solutions, such as ferric chloride or sulphate, which if desired may be formed in the mixture by adding acids, is characterized in that the iron compounds used are iron rust, or ferric hydroxides of the same physical structure, having little water and of natural or artificial origin. Temperatures of 130-150 DEG C. or over with corresponding pressures up to 6 atmospheres are specified. The time of heating varies from 1 to 5 hours. There may be added sulphur up to 30 per cent of the total, either elementary or in chemical combination, for example, as iron sulphur compounds from which it is subsequently liberated. Operating in this manner, greater dilution of the reaction mixture may be used, a stiff cement-like paste being otherwise employed. Sulphur is subsequently extracted by a solvent. Suitable artificial ferric hydroxides may be obtained by slowly oxidizing divalent iron compounds, such as the hydroxide with oxygen in a moist acid atmosphere. Thus, a paste of ferrous sulphide and hydroxide and hydrochloric acid is treated with air in a rotary mixer at ordinary temperature. Suitable naturally-occurring ferric hydroxides are specified. In a statement of the prior art, the following attempted processes of producing iron oxide pigments are referred to:--calcination of iron rust, or of precipitated ferric hydroxide with or without ferric chloride; boiling ferric hydroxides under pressure up to 20 atmospheres with water or ferric salt solutions; conversion of ferrosoferric oxide under pressure with oxygen or gases containing it.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE385646X | 1930-07-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB385646A true GB385646A (en) | 1933-01-05 |
Family
ID=6370845
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19794/31A Expired GB385646A (en) | 1930-07-11 | 1931-07-09 | Improved manufacture of a red pigment of iron oxide |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB385646A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2633407A (en) * | 1947-08-25 | 1953-03-31 | Mineral Pigments Corp | Process for producing red unhydrated iron oxide |
US2665193A (en) * | 1948-11-22 | 1954-01-05 | Minnesota Mining & Mfg | Red iron oxide of high color purity and process of making same |
US2716595A (en) * | 1949-01-28 | 1955-08-30 | C K Williams & Co | Manufacture of red hydrous ferric oxide |
SG159428A1 (en) * | 2008-09-02 | 2010-03-30 | Cheng Kit Yew | Vci (vapor corrosion inhibitor) preservation methodology of armored vehicles, battle tanks, and transport vehicles over cycles of two years. |
-
1931
- 1931-07-09 GB GB19794/31A patent/GB385646A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2633407A (en) * | 1947-08-25 | 1953-03-31 | Mineral Pigments Corp | Process for producing red unhydrated iron oxide |
US2665193A (en) * | 1948-11-22 | 1954-01-05 | Minnesota Mining & Mfg | Red iron oxide of high color purity and process of making same |
US2716595A (en) * | 1949-01-28 | 1955-08-30 | C K Williams & Co | Manufacture of red hydrous ferric oxide |
SG159428A1 (en) * | 2008-09-02 | 2010-03-30 | Cheng Kit Yew | Vci (vapor corrosion inhibitor) preservation methodology of armored vehicles, battle tanks, and transport vehicles over cycles of two years. |
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