GB346896A - Manufacture of condensation products of the benzanthrone series - Google Patents
Manufacture of condensation products of the benzanthrone seriesInfo
- Publication number
- GB346896A GB346896A GB4200/30A GB420030A GB346896A GB 346896 A GB346896 A GB 346896A GB 4200/30 A GB4200/30 A GB 4200/30A GB 420030 A GB420030 A GB 420030A GB 346896 A GB346896 A GB 346896A
- Authority
- GB
- United Kingdom
- Prior art keywords
- give
- treated
- sodium
- ester
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
- C09B3/02—Benzathrones
- C09B3/04—Preparation by synthesis of the nucleus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Benzanthrone derivatives.-2-Aroyloxynaphthalene-3-carboxylic acids and derivatives thereof such as the esters and amides, are treated with acid-condensing agents to give the 1-aroyl-2-hydroxy compounds and subsequently ring-closed to give hydroxybenzanthrone carboxylic acids. According to examples, (1) the benzoic ester of 2 : 3-oxynaphthoic acid is melted with sodium-aluminium chloride, and the product after separating treated with boiling hydrochloric acid followed by sodium carbonate, to give 4-hydroxybenzanthrone-3-carboxylic acid; (2) the benzoic ester of 2 : 3-oxynaphthoic ethyl ester, obtained by benzoylating the ethyl ester, is treated with sodium-aluminium chloride, followed by concentrated hydrochloric acid and sodium carbonate, to give the same product as example 1; (3) the Bz-m-chlorobenzoic ester of 2 : 3-oxynaphthoic ethyl ester is treated with sodium-aluminium chloride and worked up as above.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE346896X | 1929-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB346896A true GB346896A (en) | 1931-04-23 |
Family
ID=6255630
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4200/30A Expired GB346896A (en) | 1929-02-07 | 1930-02-07 | Manufacture of condensation products of the benzanthrone series |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB346896A (en) |
-
1930
- 1930-02-07 GB GB4200/30A patent/GB346896A/en not_active Expired
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