GB340519A - Process of preparing 2-amino-3-substituted-10-anthrones and n-substitution products thereof - Google Patents
Process of preparing 2-amino-3-substituted-10-anthrones and n-substitution products thereofInfo
- Publication number
- GB340519A GB340519A GB32275/30A GB3227530A GB340519A GB 340519 A GB340519 A GB 340519A GB 32275/30 A GB32275/30 A GB 32275/30A GB 3227530 A GB3227530 A GB 3227530A GB 340519 A GB340519 A GB 340519A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amino
- substituted
- anthrones
- derivatives
- benzyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C225/00—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
- C07C225/22—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
2-amino-3-substituted-10-anthrones and N-acidyl derivatives thereof are obtained by condensing 31-amino-41-substituted-benzyl-o-benzoic acids and N-acidyl derivatives thereof (Specification 314,804, [Class 2 (iii), Dyes &c.]), to close the ring, producing the 2 : 3 isomer practically free from 4 : 3 isomer. The condensation may be performed in sulphuric acid, oleum, or in acetic acid with dehydrating agents, such as phosphorus pentoxide or penta-chloride. According to examples, (1) the 3-chloro-, -ethoxy-, -methoxy-, derivatives are obtained by condensation of the corresponding 31-amino-41-substituted-benzyl-benzoic acids in sulphuric acid; (2) the N-acetyl-31-amino-41-chloro-benzyl-o-benzoic acid is prepared from the corresponding 31-amino compound and ring-closed with phosphorus pentoxide. N-phthaloyl, and 3-methyl-derivatives of the 10-anthrones are also specified.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US340519XA | 1928-07-02 | 1928-07-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB340519A true GB340519A (en) | 1930-12-29 |
Family
ID=21873999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB32275/30A Expired GB340519A (en) | 1928-07-02 | 1929-06-28 | Process of preparing 2-amino-3-substituted-10-anthrones and n-substitution products thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB340519A (en) |
-
1929
- 1929-06-28 GB GB32275/30A patent/GB340519A/en not_active Expired
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