GB338182A - A process for the manufacture and production of new dyestuffs of the anthraquinone-acridone series - Google Patents
A process for the manufacture and production of new dyestuffs of the anthraquinone-acridone seriesInfo
- Publication number
- GB338182A GB338182A GB2418029A GB2418029A GB338182A GB 338182 A GB338182 A GB 338182A GB 2418029 A GB2418029 A GB 2418029A GB 2418029 A GB2418029 A GB 2418029A GB 338182 A GB338182 A GB 338182A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzacridones
- anthraquinone
- prepared
- ring closure
- trichloranthraquinone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
- C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
- C09B1/34—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated
Abstract
338,182. Johnson, J. Y., (I. G. Farbenindustrie Akt.-Ges.). Aug. 7, 1929. Halogenated anthraquinone-2.1-benzacridones. -4-Bz-3-4-5-tetrahalogenanthraquinone - 2 - 1 - benzacridones are prepared by treating anthraquinone-2-1-benzacridones halogenated at least in the Bz4-position and having the Bz2-position free from halogen, with halogenating agents in the presence of organic solvents. When using starting materials having the 4-position free only chlorinating agents are to be employed since bromine enters the 4-position only in small amounts. Or the same bodies may be obtained by condensing 1-4-dihalogenanthraquinone-2-carboxylic acids or their esters with 2-3-4-trihalogenanilines, acridone ring closure then being effected according to known methods. In examples (1) 1.4-dichloroanthraquinone-2-carobxylic acid benzyl ester is heated with 2-3-4-trichloraniline, the product saponified and ring-closed; (2) Bz-3-4-5-trichloranthraquinone-2.1 - benzacridone (prepared by condensation of 1-chloranthraquinone-2-carboxylic acid benzyl ester with 2-3-4- trichloraniline, saponification and ring closure) is treated in nitrobenzene and in presence of a little iodine with sulphuryl chloride; (3) Bz4- chloroanthraquinone-2-1-benzacridone (prepared by condensing 1-chloranthraquinone with 4-chlor- 2-aminobenzoic acid, followed by ring closure) is treated in nitrobenzene in presence of a little iodine with sulphuryl chloride. These products dye brilliant red shades which are distinguished by their high brilliancy; they also differ from the tetrachloro derivatives obtainable according to Specincations 5534/13 and 295,770 by being converted into Bz-3-4-5-trichloranthraquinone-2-1- benzacridones on treatment with diethylaniline and a little copper. Specifications 894/11, 327,758, 338,216, and 338,217, also are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2418029A GB338182A (en) | 1929-08-07 | 1929-08-07 | A process for the manufacture and production of new dyestuffs of the anthraquinone-acridone series |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2418029A GB338182A (en) | 1929-08-07 | 1929-08-07 | A process for the manufacture and production of new dyestuffs of the anthraquinone-acridone series |
Publications (1)
Publication Number | Publication Date |
---|---|
GB338182A true GB338182A (en) | 1930-11-07 |
Family
ID=10207672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2418029A Expired GB338182A (en) | 1929-08-07 | 1929-08-07 | A process for the manufacture and production of new dyestuffs of the anthraquinone-acridone series |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB338182A (en) |
-
1929
- 1929-08-07 GB GB2418029A patent/GB338182A/en not_active Expired
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