GB306575A - Process for the manufacture of ortho-cyanaryl-thioglycollic acids and intermediate products - Google Patents
Process for the manufacture of ortho-cyanaryl-thioglycollic acids and intermediate productsInfo
- Publication number
- GB306575A GB306575A GB3106627A GB3106627A GB306575A GB 306575 A GB306575 A GB 306575A GB 3106627 A GB3106627 A GB 3106627A GB 3106627 A GB3106627 A GB 3106627A GB 306575 A GB306575 A GB 306575A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amino
- acid
- group
- thioglycollic
- sulphocyano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
- C07C331/02—Thiocyanates
- C07C331/14—Thiocyanates having sulfur atoms of thiocyanate groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
306,575. Carpmael, A., (I. G. Farbenindustrie Akt.-Ges.). Nov, 18, 1927. o-Cyanosulphocyano, o-cyanomercapto- and ocyanothioglycollic-aryl derivatives.-An o-aminoarylsulphocyano compound in which the p-posiÀ tion to the amino group is occupied or forms part of a further ring, and which may be prepared according to Specifications 257,619 and 303,813, is diazotized and subjected to Sandmeyer's reaction in order to replace the amino group by a cyano group. The sulpho cyano group is then saponified by means of alkali and the resulting mercapto group finally coupled with chloracetic acid in order to give an o-cyanoarylthioglycollic acid. In examples, 1-methyl-2-amino-3-sulphocyano-5-chlorbenzene, 1-amino-2-sulphocyano-4- ethoxybenzene and 2-amino-1-sulphocyanonaphthalene are used as starting materials, 1-methyl- 2-cyano-5-chlorbenzene-3-thioglycollic acid, 1- ,C,yano-4-ethoxyber.zeiie-2-thiogiyeollic, acid and 2- cyanonaphthalene-1-thioglycollic acid being respectively produced. Specification 295,295 also is referred to.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3106627A GB306575A (en) | 1927-11-18 | 1927-11-18 | Process for the manufacture of ortho-cyanaryl-thioglycollic acids and intermediate products |
GB376827A GB306607A (en) | 1927-11-18 | 1927-11-18 | Process for the manufacture of ortho-cyanaryl thioglycollic acids and intermediate products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3106627A GB306575A (en) | 1927-11-18 | 1927-11-18 | Process for the manufacture of ortho-cyanaryl-thioglycollic acids and intermediate products |
Publications (1)
Publication Number | Publication Date |
---|---|
GB306575A true GB306575A (en) | 1929-02-18 |
Family
ID=10317449
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3106627A Expired GB306575A (en) | 1927-11-18 | 1927-11-18 | Process for the manufacture of ortho-cyanaryl-thioglycollic acids and intermediate products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB306575A (en) |
-
1927
- 1927-11-18 GB GB3106627A patent/GB306575A/en not_active Expired
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