GB289564A - Improvements in and relating to the manufacture of triarylmethane dyestuffs - Google Patents
Improvements in and relating to the manufacture of triarylmethane dyestuffsInfo
- Publication number
- GB289564A GB289564A GB292427A GB292427A GB289564A GB 289564 A GB289564 A GB 289564A GB 292427 A GB292427 A GB 292427A GB 292427 A GB292427 A GB 292427A GB 289564 A GB289564 A GB 289564A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- oxy
- cresotinic
- naphthol
- cresotinic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/06—Hydroxy derivatives of triarylmethanes in which at least one OH group is bound to an aryl nucleus and their ethers or esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
Abstract
289,564. Carpmael, W., (I. G. Farbenindustrie Akt.-Ges.). Feb. 1, 1927. Triarylmethane dyestuffs are produced by joint oxidation in alkaline solution of a p-methylated aromatic oxycompound such as p-oxydiarylmethane or the corresponding hydrol and an oxyaromatic compound. In an example methylenedio-cresotinic acid and 2-oxynaphthalene-3 : 6-disulphonic acid are oxidized by means of air in the presence of an oxygen carrier such as copper sulphate. The resulting dyestuff dyes wool with after chroming a reddish-blue shade. Instead of methylenedi-o-cresotinic acid other p-oxydiarylmethanes may be used, such as methylenedi-ocresol, methylenedisalicylic acid, p-monooxydiphenyl methane, 4<1>-diethylamino-3-methyl-4-oxy- 5-carboxydiphenylmethane or 4<1>-oxy-3<1>-carboxynaphthyl - 3 - methyl - 4 - oxy-5-carboxyphenylmethane or hydrols thereof. Instead of 2-naphthol : 6-disulphonic acid other sulphonic acids and also carboxylic acids of 2-naphthol may be used. Phenols, alpha- and #-naphthol, polyoxynaphthols and polyoxyphenols may be used. According to a further example, p-cresotinic acid and ocresotinic acid are oxidized jointly whereby a dyestuff dyeing wool with after-chroming a reddish violet shade is obtained. p-Cresol or its derivatives may replace the p-cresotinic acid and instead of o-cresotinic acid, phenol, cresols, or their derivatives, oxyaromatic acids or mixtures thereof, for example a mixture of o-cresotinic acid and 2-oxy-3-naphthoic acid may be used. 4<1> - Oxy - 3<1> - carboxynaphthyl-3-methyl-4-oxy- 5-carboxyphenylmethane is obtained by condensation of o-cresotinic acid, alpha-oxynaphthoic acid and formaldehyde.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB292427A GB289564A (en) | 1927-02-01 | 1927-02-01 | Improvements in and relating to the manufacture of triarylmethane dyestuffs |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB292427A GB289564A (en) | 1927-02-01 | 1927-02-01 | Improvements in and relating to the manufacture of triarylmethane dyestuffs |
Publications (1)
Publication Number | Publication Date |
---|---|
GB289564A true GB289564A (en) | 1928-05-01 |
Family
ID=9748616
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB292427A Expired GB289564A (en) | 1927-02-01 | 1927-02-01 | Improvements in and relating to the manufacture of triarylmethane dyestuffs |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB289564A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4036863A (en) * | 1974-04-01 | 1977-07-19 | Polaroid Corporation | Trinapthylmethane compounds |
-
1927
- 1927-02-01 GB GB292427A patent/GB289564A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4036863A (en) * | 1974-04-01 | 1977-07-19 | Polaroid Corporation | Trinapthylmethane compounds |
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