GB289564A - Improvements in and relating to the manufacture of triarylmethane dyestuffs - Google Patents

Improvements in and relating to the manufacture of triarylmethane dyestuffs

Info

Publication number
GB289564A
GB289564A GB292427A GB292427A GB289564A GB 289564 A GB289564 A GB 289564A GB 292427 A GB292427 A GB 292427A GB 292427 A GB292427 A GB 292427A GB 289564 A GB289564 A GB 289564A
Authority
GB
United Kingdom
Prior art keywords
acid
oxy
cresotinic
naphthol
cresotinic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB292427A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB292427A priority Critical patent/GB289564A/en
Publication of GB289564A publication Critical patent/GB289564A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00Diaryl- or thriarylmethane dyes
    • C09B11/04Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/06Hydroxy derivatives of triarylmethanes in which at least one OH group is bound to an aryl nucleus and their ethers or esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)

Abstract

289,564. Carpmael, W., (I. G. Farbenindustrie Akt.-Ges.). Feb. 1, 1927. Triarylmethane dyestuffs are produced by joint oxidation in alkaline solution of a p-methylated aromatic oxycompound such as p-oxydiarylmethane or the corresponding hydrol and an oxyaromatic compound. In an example methylenedio-cresotinic acid and 2-oxynaphthalene-3 : 6-disulphonic acid are oxidized by means of air in the presence of an oxygen carrier such as copper sulphate. The resulting dyestuff dyes wool with after chroming a reddish-blue shade. Instead of methylenedi-o-cresotinic acid other p-oxydiarylmethanes may be used, such as methylenedi-ocresol, methylenedisalicylic acid, p-monooxydiphenyl methane, 4<1>-diethylamino-3-methyl-4-oxy- 5-carboxydiphenylmethane or 4<1>-oxy-3<1>-carboxynaphthyl - 3 - methyl - 4 - oxy-5-carboxyphenylmethane or hydrols thereof. Instead of 2-naphthol : 6-disulphonic acid other sulphonic acids and also carboxylic acids of 2-naphthol may be used. Phenols, alpha- and #-naphthol, polyoxynaphthols and polyoxyphenols may be used. According to a further example, p-cresotinic acid and ocresotinic acid are oxidized jointly whereby a dyestuff dyeing wool with after-chroming a reddish violet shade is obtained. p-Cresol or its derivatives may replace the p-cresotinic acid and instead of o-cresotinic acid, phenol, cresols, or their derivatives, oxyaromatic acids or mixtures thereof, for example a mixture of o-cresotinic acid and 2-oxy-3-naphthoic acid may be used. 4<1> - Oxy - 3<1> - carboxynaphthyl-3-methyl-4-oxy- 5-carboxyphenylmethane is obtained by condensation of o-cresotinic acid, alpha-oxynaphthoic acid and formaldehyde.
GB292427A 1927-02-01 1927-02-01 Improvements in and relating to the manufacture of triarylmethane dyestuffs Expired GB289564A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB292427A GB289564A (en) 1927-02-01 1927-02-01 Improvements in and relating to the manufacture of triarylmethane dyestuffs

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB292427A GB289564A (en) 1927-02-01 1927-02-01 Improvements in and relating to the manufacture of triarylmethane dyestuffs

Publications (1)

Publication Number Publication Date
GB289564A true GB289564A (en) 1928-05-01

Family

ID=9748616

Family Applications (1)

Application Number Title Priority Date Filing Date
GB292427A Expired GB289564A (en) 1927-02-01 1927-02-01 Improvements in and relating to the manufacture of triarylmethane dyestuffs

Country Status (1)

Country Link
GB (1) GB289564A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4036863A (en) * 1974-04-01 1977-07-19 Polaroid Corporation Trinapthylmethane compounds

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4036863A (en) * 1974-04-01 1977-07-19 Polaroid Corporation Trinapthylmethane compounds

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