GB2577967B - Platinum group metal and base metal on a molecular sieve for PNA-SCR-ASC close-coupled systems - Google Patents
Platinum group metal and base metal on a molecular sieve for PNA-SCR-ASC close-coupled systems Download PDFInfo
- Publication number
- GB2577967B GB2577967B GB1911339.8A GB201911339A GB2577967B GB 2577967 B GB2577967 B GB 2577967B GB 201911339 A GB201911339 A GB 201911339A GB 2577967 B GB2577967 B GB 2577967B
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- GB
- United Kingdom
- Prior art keywords
- asc
- pna
- scr
- close
- molecular sieve
- Prior art date
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- Expired - Fee Related
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9431—Processes characterised by a specific device
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9436—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
- B01D53/9463—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick
- B01D53/9468—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick in different layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
- B01D53/9463—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick
- B01D53/9472—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick in different zones
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
- B01J29/042—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing iron group metals, noble metals or copper
- B01J29/043—Noble metals
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- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
- F01N3/0842—Nitrogen oxides
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/103—Oxidation catalysts for HC and CO only
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
- F01N3/2066—Selective catalytic reduction [SCR]
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- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/62—Synthesis on support in or on other molecular sieves
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- F01N2510/00—Surface coverings
- F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
- F01N2510/063—Surface coverings for exhaust purification, e.g. catalytic reaction zeolites
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F01N2510/00—Surface coverings
- F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
- F01N2510/068—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings
- F01N2510/0682—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings having a discontinuous, uneven or partially overlapping coating of catalytic material, e.g. higher amount of material upstream than downstream or vice versa
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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- F01N2510/00—Surface coverings
- F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
- F01N2510/068—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings
- F01N2510/0684—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings having more than one coating layer, e.g. multi-layered coatings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762478794P | 2017-03-30 | 2017-03-30 | |
| GB1805137.5A GB2563968B (en) | 2017-03-30 | 2018-03-29 | Platinum group metal and base metal on a molecular sieve for PNA-SCR-ASC close-coupled systems |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB201911339D0 GB201911339D0 (en) | 2019-09-25 |
| GB2577967A GB2577967A (en) | 2020-04-15 |
| GB2577967B true GB2577967B (en) | 2021-06-09 |
Family
ID=62142176
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1911339.8A Expired - Fee Related GB2577967B (en) | 2017-03-30 | 2018-03-29 | Platinum group metal and base metal on a molecular sieve for PNA-SCR-ASC close-coupled systems |
| GB1805137.5A Expired - Fee Related GB2563968B (en) | 2017-03-30 | 2018-03-29 | Platinum group metal and base metal on a molecular sieve for PNA-SCR-ASC close-coupled systems |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1805137.5A Expired - Fee Related GB2563968B (en) | 2017-03-30 | 2018-03-29 | Platinum group metal and base metal on a molecular sieve for PNA-SCR-ASC close-coupled systems |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10669910B2 (enExample) |
| EP (1) | EP3600626B1 (enExample) |
| JP (2) | JP7170658B2 (enExample) |
| CN (1) | CN110709152B (enExample) |
| BR (1) | BR112019020371A2 (enExample) |
| DE (1) | DE102018107777A1 (enExample) |
| GB (2) | GB2577967B (enExample) |
| RU (1) | RU2762284C2 (enExample) |
| WO (1) | WO2018183604A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6693406B2 (ja) * | 2016-12-20 | 2020-05-13 | 三菱自動車工業株式会社 | 排気ガス浄化装置 |
| GB2562160B (en) * | 2017-03-20 | 2021-06-23 | Johnson Matthey Plc | Catalytic wall-flow filter with an ammonia slip catalyst |
| RU2770069C2 (ru) | 2017-03-29 | 2022-04-14 | Джонсон Мэтти Паблик Лимитед Компани | Катализатор предотвращения проскока аммиака (asc) с металлом платиновой группы в множестве слоев |
| GB201705158D0 (en) * | 2017-03-30 | 2017-05-17 | Johnson Matthey Plc | Catalyst article for use in a emission treatment system |
| US10926221B2 (en) * | 2017-03-30 | 2021-02-23 | Johnson Matthey Public Limited Company | Single brick SCR/ASC/PNA/DOC close-coupled catalyst |
| DE102018107545A1 (de) * | 2017-03-30 | 2018-10-04 | Johnson Matthey Public Limited Company | Asc/dec mit rückwärtig konzentrierter exothermenerzeugung |
| JP2020531241A (ja) * | 2017-08-31 | 2020-11-05 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG | 排気ガスを浄化するための受動的窒素酸化物吸着剤としてのパラジウム/白金/ゼオライト系触媒の使用 |
| US11141717B2 (en) | 2017-08-31 | 2021-10-12 | Umicore Ag & Co. Kg | Palladium/zeolite-based passive nitrogen oxide adsorber catalyst for purifying exhaust gas |
| BR112020017976A2 (pt) * | 2018-03-14 | 2020-12-22 | Johnson Matthey Public Limited Company | Artigo catalítico, sistema de exaustão, método para melhorar a conversão de nh3 de um gás de exaustão, e, método para tratamento de gás de exaustão |
| GB201805312D0 (en) * | 2018-03-29 | 2018-05-16 | Johnson Matthey Plc | Catalyst article for use in emission treatment system |
| US11161098B2 (en) * | 2018-05-18 | 2021-11-02 | Umicore Ag & Co. Kg | Three-way catalyst |
| JP7120959B2 (ja) * | 2019-04-22 | 2022-08-17 | トヨタ自動車株式会社 | 構造体 |
| EP3963187B1 (en) | 2019-04-30 | 2024-05-29 | BASF Corporation | Multi-functional catalysts for the oxidation of no, the oxidation of nh3 and the selective catalytic reduction of nox |
| WO2020241248A1 (ja) * | 2019-05-31 | 2020-12-03 | 三井金属鉱業株式会社 | 排ガス浄化用触媒及び該排ガス浄化用触媒を用いた排ガス浄化システム |
| US11167272B2 (en) | 2019-07-15 | 2021-11-09 | Ford Global Technologies, Llc | Exhaust treatment system including nickel-containing catalyst |
| EP4072709A1 (en) * | 2019-12-13 | 2022-10-19 | BASF Corporation | Zeolite with cu and pd co-exchanged in a composite |
| CN113600233B (zh) * | 2021-08-31 | 2023-03-28 | 东风商用车有限公司 | 一种金属掺杂钯分子筛催化剂及其制备方法、应用 |
| EP4415880A1 (en) * | 2021-10-12 | 2024-08-21 | Johnson Matthey (Shanghai) Chemicals Limited | Novel zoned catalysts for cng engine exhaust gas treatments with improved ammonia emission control |
| CN115501908B (zh) * | 2022-09-13 | 2023-11-03 | 东风商用车有限公司 | 具有低温NOx吸附功能的抗硫SCR催化剂及其应用 |
| DE102022004159A1 (de) * | 2022-11-09 | 2024-05-16 | Mercedes-Benz Group AG | Abgasanlage für eine Verbrennungskraftmaschine eines Kraftfahrzeugs sowie Kraftwagen mit einer solchen Abgasanlage |
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| GB2566568A (en) * | 2017-03-30 | 2019-03-20 | Johnson Matthey Plc | Single brick SCR/ASC/PNA/DOC close-coupled catalyst |
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2018
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- 2018-03-29 EP EP18724348.0A patent/EP3600626B1/en active Active
- 2018-03-29 CN CN201880031424.0A patent/CN110709152B/zh active Active
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| US20160367973A1 (en) * | 2015-06-18 | 2016-12-22 | Johnson Matthey Public Limited Company | Ammonia slip catalyst designed to be first in an scr system |
| US20160367941A1 (en) * | 2015-06-18 | 2016-12-22 | Johnson Matthey Public Limited Company | Zoned Exhaust System |
| GB2566568A (en) * | 2017-03-30 | 2019-03-20 | Johnson Matthey Plc | Single brick SCR/ASC/PNA/DOC close-coupled catalyst |
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|---|---|
| US10669910B2 (en) | 2020-06-02 |
| RU2019134056A (ru) | 2021-04-30 |
| JP7170658B2 (ja) | 2022-11-14 |
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| GB2563968B (en) | 2021-07-07 |
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| EP3600626B1 (en) | 2021-09-08 |
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| DE102018107777A1 (de) | 2018-10-04 |
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| CN110709152A (zh) | 2020-01-17 |
| RU2019134056A3 (enExample) | 2021-07-20 |
| GB2577967A (en) | 2020-04-15 |
| GB201911339D0 (en) | 2019-09-25 |
| JP2020515762A (ja) | 2020-05-28 |
| GB2563968A (en) | 2019-01-02 |
| US20180283250A1 (en) | 2018-10-04 |
| BR112019020371A2 (pt) | 2020-04-28 |
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