GB2131605A - Thin film transistor - Google Patents
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- GB2131605A GB2131605A GB08326775A GB8326775A GB2131605A GB 2131605 A GB2131605 A GB 2131605A GB 08326775 A GB08326775 A GB 08326775A GB 8326775 A GB8326775 A GB 8326775A GB 2131605 A GB2131605 A GB 2131605A
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- deposited
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- drain region
- alloy
- thin film
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- 239000010409 thin film Substances 0.000 title claims abstract description 39
- 239000012212 insulator Substances 0.000 claims abstract description 42
- 230000005669 field effect Effects 0.000 claims abstract description 40
- 239000000758 substrate Substances 0.000 claims abstract description 32
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 26
- 239000010703 silicon Substances 0.000 claims abstract description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 238000010276 construction Methods 0.000 claims abstract description 13
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 13
- 239000011737 fluorine Substances 0.000 claims abstract description 13
- 229910045601 alloy Inorganic materials 0.000 claims description 56
- 239000000956 alloy Substances 0.000 claims description 56
- 239000004065 semiconductor Substances 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 29
- 239000004020 conductor Substances 0.000 claims description 27
- 238000000151 deposition Methods 0.000 claims description 20
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 12
- 101150068246 V-MOS gene Proteins 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 2
- 101100234822 Caenorhabditis elegans ltd-1 gene Proteins 0.000 claims 1
- 230000005684 electric field Effects 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 41
- 229910000808 amorphous metal alloy Inorganic materials 0.000 abstract description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 39
- 239000002184 metal Substances 0.000 description 39
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 22
- 229910021417 amorphous silicon Inorganic materials 0.000 description 18
- 239000010408 film Substances 0.000 description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 11
- 239000011810 insulating material Substances 0.000 description 11
- 229910000077 silane Inorganic materials 0.000 description 11
- 239000013078 crystal Substances 0.000 description 10
- 239000002019 doping agent Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 235000012431 wafers Nutrition 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 230000008021 deposition Effects 0.000 description 6
- 229910052732 germanium Inorganic materials 0.000 description 6
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000002178 crystalline material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910021419 crystalline silicon Inorganic materials 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- 108091006146 Channels Proteins 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910000878 H alloy Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 235000016768 molybdenum Nutrition 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000347389 Serranus cabrilla Species 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- VDRSDNINOSAWIV-UHFFFAOYSA-N [F].[Si] Chemical compound [F].[Si] VDRSDNINOSAWIV-UHFFFAOYSA-N 0.000 description 1
- 229910017817 a-Ge Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table
- H01L29/167—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table further characterised by the doping material
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- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/525—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections
- H01L23/5252—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections comprising anti-fuses, i.e. connections having their state changed from non-conductive to conductive
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
- H01L27/06—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration
- H01L27/0688—Integrated circuits having a three-dimensional layout
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- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78642—Vertical transistors
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- Thin Film Transistor (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
- Bipolar Transistors (AREA)
Abstract
A thin film, field effect transistor device of V-mos-like construction having a source region, a drain region, a gate insulator 80, a thin film 76 of deposited amorphous alloy including at least silicon and fluorine coupled to the source region, the drain region and the gate insulator and a gate electrode 84 in contact with the gate insulator. Preferably, the amorphous alloy also contains hydrogen and is a -Sia:Fb:Hc, where a is between 80 and 98 atomic percent, b is between 1 and 10 atomic percent and c is between 1 and 10 atomic percent. The field effect transistor can be deposited on various substrates with an insulator material between the active regions of the thin film, field effect transistor and a conducting substrate. <IMAGE>
Description
1 GB 2 131 605A 1
SPECIFICATION
Thin film transistor This application is devided from Application No. 8039608 which discloses and claims a thin film field effect transistor.
The present invention relates to a thin film, field effect transistor, and more specifically to a thin film, field effect transistor of the type formed from an amorphous alloy including at least silicon and fluorine. In this respect, reference is made to U.S. Patent No. 4,217,374 Stanford R. Ovshinsky and Masatsugu Izu entitled: AMORPHOUS SEMICONDUCTORS EQUIVALENT TO CRYSTALLINE SEMICONDUCTORS and U.S. Patent No. 4,226,898 Stanford R. Ovshinsky and Arun Madan, of the same title.
Silicon is the basis of the huge crystalline semiconductor industry and is the material which is utilized in substantially all the commercial integrated circuits now produced. When crystalline semiconductor technology reached a commercial state it became the foundation of the present huge semiconductor device manufacturing industry. This was due to the ability of the scientist to grow substantially defect-free germanium and particularly silicon crystals, and then turn them into extrinsic materials with p-type and n-type conductivity regions therein. This was accomplished by diffusing into such crystalline material parts per million of donor (n) or acceptor (p) dopant materials introduced as substitutional impurities into the substantially pure crystalline materials, to increase their electrical conductivity and to control their being either of a p or n conduction type.
Packing density (the number of devices per unit area of wafer surface) is also limited on the silicon wafers, because of the leakage current in each device and the power neces- sary to operate the devices, each of which generate heat which is undesirable. The silicon wafers do not readily dissipate heat. Also, the leakage current adversely affects the battery or power cell life-time in portable applica- tions.
In MOS type circuitry the switching speed is related directly to the gate length with the smallest length having the highest speed. The diffusion processes, photo[ ithog rophy and other crystalline manufacturing processes limit how short the gate length can be made.
Further, the packing density is extemely important because the cell size is exponentially related to the cost of each device. For instance, a decrease in die size by a factor of two results in a decrease in cost on the order of a factor of six.
In summary, crystal silicon transistor and integrated circuit parameters which are not variable as desired, require large amounts of material, high processing temperatures, are only producible only on relatively small area wafers and are expensive and time consuming to produce. Devices based upon amorphous silicon can eliminate these crystal silicon disadvantages. Amorphous silicon can be made faster, easier, at lower temperatures and in larger areas than can crystal silicon.
Accordingly, a considerable effort has been made to develop processes for readily depositing amorphous semiconductor alloys or films each of which can encompass relatively large areas, if desired, limited only by the size of the deposition equipment, and which could be The semiconductor fabrication processes for 105 doped to form p-type and n-type materials to making p-n junction cyrstals involve extremely complex, time consuming and expensive procedures as well as high processing temperatures. Thus, these crystalline materials used in transistors and other current control devices are produced under very carefully controlled conditions by growing individual single silicon or germanium crystals, where pn junctions are required by doping such single crystals with extremely small and critical amounts of dopants. These crystal growing processes produce relatively small crystal wafers upon which the integrated circuits are formed.
In wafer scale integration technology the small area crystal wafer limits the overall size of the integrated circuit which can be formed thereon. In applications requiring large scale areas, such as in the display technology, the crystal wafers cannot be manufactured with as large areas as required or desired. The devices are formed, at least in part, by diffusing p or n- type dopants into the substrate. Further, each device is formed between isolation chan- nels which are diffused into the substrate.
form p-n junction transistors and devices superior in cost and/or operation to those produced by their crystalline counterparts. For many years such work was substantially un- productive. Amorphous silicon or germanium (Group IV) films are normally four-fold coordinated and were found to have microvoids and dangling bonds and other defects which produce a high density of localized states in the energy gap thereof. The presence of a high density of localized states in the energy gap of amorphous silicon semiconductor films resulted in such films not being successfully doped or otherwise modified to shift the Fermi level close to the conduction or valence bands making them unsuitable for making p-n junctions for transistors and other current control device applications.
In an attempt to minimize the aforemen- tioned problems involved with amorphous silicon and germanium, W. E. Spear and P. G. Le Comber of Carnegie Laboratory of Physics, University of Dundee, in Dundee, Scotland did some work on -Substituti6nal Doping of Amorphous Silicon-, as reported in a paper 2 GB 2 131 605A 2 published in Solid State Communications, Vol.
17, pp. 1193-1196, 1975, toward the end of reducing the localized states in the energy gap in amorphous silicon or germanium to make the same approximate more closely in trinsic crystalline silicon or germanium and of substitutionally doping the amorphous ma terials with suitable classic dopants, as in doping crystalline materials, to make them extrinsic and of p or n conduction types.
The reduction of the localized states was accomplished by glow discharge deposition of amorphous silicon films wherein a gas silane (SiH,) was passed through a reaction tube where the gas was decomposed by an r.f.
glow discharge and deposited on a substrate at a substrate temperature of about 500-600'K (227-327'C). The material so deposited on the substrate was an intrinsic amorphous material consisting of silicon and hydrogen. To produce amorphous material a gas of phosphine (PH3) for n-type conduction or a gas of diborane (1321-16) for p-type conduc tion were premixed with the silane gas and passed through the glow discharge reaction tube under the same operating conditions.
The gaseous concentration of the dopants used was between about 5 X 10-6 and 10-2 parts per volume. The material so de posited included supposedly substitutional phosphorus or boron dopant and was shown to be extrinsic and of n or p conduction type.
While it was not known by these resear chers, it is now known by the work of others that the hydrogen in the silane combines at an optimum temperature with many of the dangling bonds of the silicon during the glow discharge deposition, to substantially reduce the density of the localized states in the energy gap toward the end of making the electronic properties of the amorphous ma terial approximate more nearly those of the corresponding crystalline material.
D. 1. Jones, W. E. Spear, P. G. LeComber, S. Li, and R. Martins also worked on prepar ing a-Ge:H from Gel-14 using similar deposi tion techniques. The material obtained gave evideence of a high density of localized states in the energy gap thereof. Although the ma terial could be doped the efficiency was sub stantially reduced from that obtainable with a Si:H. In this work reported in Philosophical Magazine B. Vol. 39, p. 147 (1979) the authors conclude that because of the large density of gap states the material obtained is 120 -... a less attractive material than a-Si for doping experiments and possible applica tions.-- The incorporation of hydrogen in the above silane method not only has limitations based upon the fixed ratio of hydrogen to silicon in silane, but, most importantly, various Si:H bonding configurations introduce new anti bonding states which can have deleterious consequences in these materials. Therefore, there are basic limitations in reducing the density of localized states in these materials which are particularly harmful in terms of effective p as well as n doping. The resulting density of states of the siiane deposited materials leads to a narrow depletion width which in turn limits the efficiencies of devices whose operation depends on the drift of free carriers. The method of making these ma- terials by the use of only silicon and hydrogen also results in a high density of surface states which affects all the above parameters.
After the development of the glow discharge deposition of silicon from silane gas was carried out, work was done on the sputter deposition of amorphous silicon films in the atmosphere of a mixture of argon (required by the sputtering deposition process) and molecular hydrogen, to determine the results of such molecular hydrogen on the characteristics of the deposited amorphous silicon film. This research indicated that the hydrogen acted as a compensating agent which bonded in such a way as to reduce the localized states in the energy gap. However, the degree to which the localized states in the energy gap were reduced in the sputter deposition process was much less than that achieved by the silane deposition process described above.
The above described p and n dopant materials also were introduced in the sputtering process to produce p and n doped materials. These materials had a lower doping efficiency than the materials produced in the glow discharge process. Neither process produced efficient pdoped materials with sufficiently high acceptor concentrations for producing commerical p-n junction devices. The n-doping efficiency was below desirable acceptable commercial levels and the p-doping was particularly undesirable since it increased the number of localized states in the band gap.
Various methods of fabrication and construction of thin film transistors and devices have been proposed wherein the various films of the transistor are made of different materials having different electrical characteristics. For example, thin film transistors have been proposed utilizing nickel oxide films, silicon films, amorphous silicon films and amorphous silicon and hydrogen films formed from silane as above mentioned. Also, various geometrical configurations have been proposed such as a planar-MOS construction.
The prior deposition of amorphous silicon, which has been altered by hydrogen from the silane gas in an attempt to make it more closely resemble crystalline silicon and which has been doped in a manner like that of doping crystalline silicon, has characteristics which in all important respects are inferior to those of doped crystalline silicon. As reported by Le Comber and Spear and others referenced above, in the silane based transistor devices the leakage current may be as low as 1 3 GB 2 131 605A 3 - 11 amperes, the saturation current appears to be about 5 X 10-6 amperes, the device switching frequency appears to be about 104 Hz and the stability is poor since the material degrades with time.
It has been proposed to make a solar cell which is essentially a photosensitive rectifier utilizing an amorphous alloy including silicon and fluorine in the aforementioned U.S. Pa tent No. 4,217,374, issued 8/12/80 for Amorphous Semiconductor Equivalent to Crys talline Semiconductors, Stanford R. Ovshinsky and Masatsugu Izu and U.S. Patent No.
4,276,898, issued 10/7/80 of the same title Stanford R. Ovshinsky and Arun Madan.
According to the present invention there is provided a thin film, field effect transistor device including a source region, a drain region, a gate insulator, a thin-film deposited semoconductor alloy coupled to said source region, said drain region and said gate insula tor, and a gate electrode in contact with said gate insulator having V-MOS like construction.
The field effect transistor can have various geometries including a V-MOS like construc tion of the invention and can be deposited on various substrates with an insulator between the active regions of the thin film, field effect transistor and a conducting substrate such as a metal. The transistors can be deposited on an insulator, a semiconductor, an insulated matal or an insulated semiconductor sub strate. Because of the capability be formed on various substrates and the low leakage and operating current, the transistors also can be formed on top of one another, i.e., stacked.
The thin film, field effect transistor can have various desirable characteristics depending upon the particular geometry chosen and thickness of the film of amorphous silicon fluorine material chosen such as, for example, a DC saturation current as low as 10-6 am peres and up to or greater than 10-4 am peres, an upper cut off frequency at least above 10 MHz, a high OFF resistance:ON resistance ratio of about 107, and a very low leakage current of about- 10 - 11 amps or less.
Further, the alloy does not degrade with time.
The invention includes a field effect transis tor as described above having a planar MOS like construction wherein said amorphous al loy layer is formed on said substrate; a first band of insulator material is formed on said amorphous alloy layer; a second band of insulator material is formed on said amor phous alloy layer and is spaced from said first band of insulator material; said source region is formed over said first band with at least a portion in contact with said alloy layer; said drain region is formed over said second band with at least a portion in contact with said alloy layer and is spaced from said source region; said gate insulator is formed over said source region, said drain region and in contact with said alloy layer between said source 130 region and said drain region; said gate electrode is formed in contact with at least a porition of said gate insulator; and a passivating layer is formed over at least a portion of the layers.
The invention also includes a field effect transistor as described above wherein said drain region layer is formed on at least a portion of said substrate; said source region, said amorphous semiconductor alloy layer and said drain region forming a diagonal surface; and said gate insulator being disposed substantially parallel to said diagonal surface and separating said gate electrode from said amor- phous semiconductor alloy layer for controlling the current conduction through said current conduction channel.
A preferred embodiment of this invention will now be described by way of example, with reference to the drawings accompanying this specification in which:
Figure 1 is a vertical sectional view of one embodiment of thin film deposited, field effect transistor made in accordance with the teach- ings of the present invention and having metal source and drain regions similar to a planar MOS-type transistor.
Figure 2 is a schematic circuit diagram of the transistor shown in Fig. 1.
Figure 3 is a vertical sectional view through a second embodiment of a thin film deposited, field effect transistor similar to the transistor shown in Fig. 1, having semiconductor source and drain regions.
Figure 4 is a schematic circuit diagram of the transistor shown in Fig. 3.
Figure 5 is a vertical sectional view of another embodiment of thin film deposited, field effect transistor similar to the transistor shown in Fig. 1, having metal source and drain regions similar to a V-MOS- type transistor.
Figure 6 is a schematic circuit diagram of the transistor shown in Fig. 5.
Figure 7 is a vertical sectional view through a second embodiment of a thin'film deposited, field effect transistor similar to the transistor shown in Fig. 5, having semiconductor source and drain regions.
Figure 8 is a schematic circuit diagram of the transistor shown in Fig. 7.
Figure 9 is a vertical sectional view through a thin film deposited, field effect transistor, similar in function to the transistors shown in
Figs. 1 -8 but having a different geometrical construction.
Referring now to the figures in greater detail, there is illustrated in Fig. 1 a thin film, field effect transistor 10 mad6 in accordance with the teachings of the present invention. As shown, the transistor 10 is formed on a substrate 12 of insulating material which could be a silicon material, a layer of polymer material or an insulator on top of a metal. Deposited on the substrate 12 in accordance 4 GB 2 131 605A 4 with the teachings of the present invention is a thin alloy layer 14 including silicon and fluorine which can also contain hydrogen and which can be doped to form an N or P type alloy. On top of this alloy layer 14 is a layer or band 16 of insulating material such as a field oxide and spaced therefrom is another layer or band 18 of insulating material such as a field oxide.
A channel or opening 20 is formed, as by conventional photolithography techniques, between the two bands 16 and 18. A source metal conductor 22 is deposited over the band 16 with a portion thereof in contact with the alloy layer 14 to form a Schottky barrier contact at the interface between the source metal 22 and the amorphous alloy layer 14.
In a similar manner a conductor or layer 24 of drain metal is deposited over the insulating band 18 with a portion thereof in contact with the alloy layer 14 spaced from the source metal 22. The interface between the drain metal 24 and the amorphous layer 14 creates another Schottky barrier contact. A gate insu- lator layer 26 of insulating material such as gate oxide or gate nitride 26 is deposited over the source metal 22 and drain metal 24 and in contact with the amorphous alloy layer 14 between the source and drain metal. On this layer 26 of gate insulating material is deposited a gate conductor 28 which can be made of any suitable metal such as aluminum or molybdenum. On the gate conductor another layer 30 of insulating material is deposited to passivate the device, which is identified as a field oxide.
The insulating layers 16 and 30 would be joined before the next adjacent transistor with the source 22 connected to an external con- ductor. The insulating layer 16 forms the insulator for the next device similar to the insulator 18 of the transistor 10 shown.
The gate insulator layer 26 and the bands 16 and 18 of insulating material referred to as being a field oxide can be made of a metal oxide, silicon dioxide or other insulator such as silicon nitride. The source metal 22 and drain metal 24 can be formed of any suitable conductive metal such as aluminum, molyb- denum or a high work function metal such as gold paladium, platinum or chormium. The gate insulator can be a nitride, silicon dioxide or silicon nitride material.
In accordance with the teachings of the present invention, an alloy containing silicon and fluorine which can also contain hydrogen is utilized for forming the amorphous alloy layer 14. This alloy provides the desirable characteristics enumerated before which can be utilized for many different circuits. The alloy layer 14 is preferably made of aSi Me ,:Fb, where a is between 80 and 98 atomic percent, b is between 1 and 10 atomic percent and c is between 1 and 10 atomic percent.
The alloy can be doped with a dopant from Group V or Group lit of the Periodic Table materials in an amount constituting between 10 and 1000 parts per million (ppm). The dopant materials and amount of doping can vary.
The thickness of the alloy layer 14 of amorphous material can be between 100 and 5000 Angstroms, one thickness utilized being 7 5 approximately 1000 Angstroms. The source metal 22 and the drain metal 24 can also have thicknesses ranging from 500 to 20,000 Angstroms with one utilized thickness being of approximately 2000 Angstroms. The gate conductor 28 although described as being made of metal, can be made of a doped semiconductor material if desired.
Depending upon the geometry of the various layers and thicknesses of the various layers, a field effect transistor can be constructed as described above wherein the leakage current is approximately 10 - 11 amperes thereby to provide a high OFF resistance and a DC saturation current of approximately 10-4 amperes.
In constructing the thin film, field effect transistor 10 shown in Fig. 1, the layers of material, and particularly the alloy layer 14, - are deposited by various deposition tech- niques, preferably by glow discharge.
A conventional schematic gate (G), source (S) and drain (D) circuit diagram of the field effect transistor 10 is illustrated in Fig. 2.
Referring now to Fig. 3, there is illustrated a planar constructed thin film, field effect transistor 40 which, like the transistor 10, is formed on an insulated substrate layer 42. On top of the substrate material 42 is deposited, such as by glow discharge, an alloy layer 44 including silicon and fluorine which also preferabiy includes hydrogen and can be of the N or P type. On this alloy layer 44 are deposited two layers of insulating material 46 and 48 which are referred to in Fig. 3 as being made of a field oxide with an opening 50 formed therebetween. Above the insulating layers 46 and 48 are deposited, respectively, a source alloy layer 52 and a drain alloy layer 54 which also include silicon and fluorine and preferably include hydrogen. The source 52 and the drain alloy 54 are N or P type amorphous alloys. An N-P or P-N junction is then formed at the interface where the layers 52 and 54 make contact with the alloy layer 12044.
After depositing the layers 52 and 54, a gate insulator layer 56 referred to as a gate oxide 56 is deposited over the source region 52, the exposed portion of the amorphous layer 44 and the drain region 54. Then a gate conductor 58 is deposited over the gate insulator 46 and a passivating insulating layer 60 is deposited on top of the gate conductor 58, identified as a field oxide.
A conventional schematic gate (G), source GB2131605A 5 (S) and drain (D) circuit diagram of the transistor 40 is illustrated in Fig. 4.
The difference between the transistor 40 and the transistor 10 is that the drain and source regions or conductors 52 and 54 of the transistor 40 are made of a semiconductor material and preferably an a-Si:F:H alloy.
In Fig. 5 there is illustrated a new V-MOS like construction illustrated in a thin film, field effect transistor 70 made in accordance with the teachings of the present invention. On a substrate layer 72 is first deposited a layer or band of drain metal 74 which has a central portion thereof cut or etched away. On top of the drain metal 74 is deposited a thin layer or band of amorphous alloy 76 which has a central portion cut or etched away aligned with the cut away portion of layer 74. Similarly, a layer of source metal 78 is deposited on the layer 76 and a corresponding central portion thereof is cut away. Alternately, all the layers can be etched in one step following the deposition of all the layers. Then a gate insulator 80 referred to as a gate oxide is deposited over the source metal 78 and in the resulting central V-cut space 82 and onto the inclined edges of the layer portions 74, 76 and 78 and over the exposed substrate 72. Then a gate conductor 84 is deposited on the gate insulator 82 and a layer 86 of insulating material identified as a field oxide is deposited over the gate metal conductor 84 as a passivating layer.
This particular V-MOS like construction with the open space 80 has the advantage that a very short distance L is established between the source metal 74 and' the drain metal 78 through the alloy layer 7.6. The layer thickness or distance L results in.a high operating frequency, and a higher saturation current than the transistor configuration of Figs. 1 and 3. The leakage current may increase over the configuration of Figs. 1 and 3.
A conventional schematic gate (G), source (S) and drain (D) diagram of the transistor 70 is shown in Fig. 6.
In Fig. 7 is illustrated pnother V-MOS like thin film, field effect transistor 90 formed on a substrate 92 with alloy layers 94, 96 and
98 having silicon and fluorine (N or P type) deposited on the substrate 92. The respective layers 94, 96 and 98 have a central portion 100 cut or etched away thereof. Then a gate insulator 102 identified as a gate oxide is deposited over the edge of the layer 98 and contacts the exposed edges of the layers 94, 96, and 98 and also the exposed portion of the substrate 92 as shown. A gate conductor 104 is deposited over the insulator layer 102 and lastly a layer 106 of insulating material, such as a field oxide, is deposited over the gate conductor 104. The transistor 90 operates utilizing the oppositely biased P-N junctions formed between layers 94 and 96 and between 96 and 98.
The transistor 90 is similar to the transistor 70 as shown in Fig. 5 except that the source region 98 and drain region 94 is made of a semiconductor alloy, such as a-Si:F:H. The V- MOS like construction of the invention illustrated by transistors 70 and 90 is advantageously utilized with any deposited semiconductor material, such as but not only a silicon alloy containing at least hydrogen as deposi- ted from silane.
A conventional schematic circuit diagram of the transistor 90 is illustrated in Fig. 8.
Referring now to Fig. 9, there is illustrated therein another field effect transistor 110 made in accordance with the teachings of the present invention. The transistor 110 is formed on a metal substrate 111 which has deposited thereon a thin layer of insulating material 112 which separates the active com- ponents of the transistor 110 from the metal substrate 111 and yet is thin enough so that heat generated in the transistor 110 can flow to the metal substrate which forms a heat sink therefor.
The thin film, field effect transistor 110 is formed by depositing a source conductor layer 114 made of metal or N or P type semiconductor alloy. A drain conductor 116 is deposited on the insulating layer 112 and also is made of a metal or a P or N type semiconductor alloy. On top of the conductors 114 and 116 is deposited an intrinsic or lightly doped alloy layer 118, such as the a-Si: F: H alloy previously described.
On top of the alloy layer 118 is deposited a gate insulator 120 which can be a silicon oxide or a silicon nitride. On top of the gate insulator 120 is deposited a gate conductor layer 122 which can be a metal or semiconductor material. A passivating layer 124 is deposited over the gate conductor 122.
The various transistors 10, 40, 70, 90, and 110 can be formed in a matrix so that either the source or drain region extends as a Y axis conductor across the deposited substrate 112. Then, the drain or source region is deposited to form a segregated drain or source region which is then connected to an X axis conductor. Then the gate electrode is deposited so as to extend parallel to the Y axis to form a Y axis gate conductor. In this way, the field effect transistors 10, 50, 70, 90, and 110 can be utilized in conjunction with PROM devices to form the isolating device in a memory circuit therefor which comprises a memory region and the isolating device..
The thin film, field effect transistor of the present invention and the various specific embodiments thereof described herein provide a transistor which is very small and yet has very good operating characteristics as enumerated above. The top insulating layer of the transistors, such as 124 in Fig. 9, can be utilized to form the insulating layer for another transistor to be formed thereon to provide a stacked 6 GB 2 131 605A 6 transistor configuration and hence further increase the packing density of the devices. This is possible because the layers are deposited and because of the low operating and leakage 5 current of the devices.
9. A transistor device according to any one of the preceding claims, wherein the drain, and the source regions are deposited materials. 10. A transistor device according to any From the foregoing description it
will be one of the preceding claims, wherein the apparent that a thin film, field effect transistor drain region is a p- type semiconductor.
incorporating an alloy layer of a-Si:F:H 11. A transistor device according to any therein according to the teachings of the pre- one of the preceding claims, wherein the sent invention has a number of advantages. 75 drain region is a metal or an amorphous alloy.
The planar structures of Figs. 1, 3 and 9 12. A transistor device according to any also can be formed in inverse order to that one of the preceding claims, wherein the shown with the gate on the bottom. The source region is a p-type semiconductor.
Schottky barriers also can be an MIS (metal 13. A transistor device according to any insulator semiconductor) contact. Also, the 80 one of the preceding claims, wherein the gate conductor in a device can be metal, source region is a metal or an amorphous polysilicon or doped semiconductor material alloy.
with a different metal or semiconductor drain 14. A transistor device according to any material, instead of both being of the same one of the preceding claims, wherein the metal or semiconductor material. 85 deposited semiconductor has a thickness of between 100 and 5000 angstroms.
15. A transistor device according to any one of the preceding claims, wherein the drain region has a thickness of between 500 and 20,000 angstroms.
16. A transistor device according to any one of the preceding claims, wherein the source region has a thickness of between 500 and 20,000 angstroms.
17. A transistor device according to any one of the preceding claims, wherein the gate insulator comprises an oxide layer.
18. A transistor device according to claim 17, wherein the gate insulator is a deposited layer.
19. A transistor device according to any one of the preceding claims, wherein the drain region is deposited on the substrate, and extends as a y-axis conductor across the substrate to an adjacent thin film, field effect transistor device; an x-axis conductor extends from another adjacent thin film, vertical field effect transistor device to the source; and the gate electrode extends horizontally parallel to the y-axis to an adjacent, thin film, vertical field effect transistor.
20. A transistor device according to any one of the preceding claims, comprising a covering insulating layer and a further thin film, vertical field effect transistor device stacked on top of the first transistor device.
21. A method of forming a thin film, field effect transistor device that has a source re gion, a drain region, a gate insulator, a thin film deposited semiconductor alloy coupled to the source region, the drain region and the gate insulator, and a gate electrode in contact with the gate insulator, the device having a V MOS like construction, the method including the steps of depositing the drain region on a substrate; depositing the semiconductor alloy on top of the drain region; depositing the source region on top of the semiconductor alloy whereby to form a vertical array with respect to the substrate; removing a portion of
Claims (1)
1. A thin film, field effect transistor device including a source region, a drain region, a gate insulator, a thin-film deposited semiconductor alloy coupled to said source region, said drain region and said gate insulator, and a gate electrode in contact with said gate insulator having a V-MOS like construction.
2. A thin film, field effect transistor according to claim 1 wherein the transistor includes two adjacent surfaces that form a Vtype structure.
3. A transistor device according to claim 1 or claim 2, wherein the V-MOS like construction includes the source region and the drain region being positioned one above the other, and vertically arrayed with respect to a substrate, and the deposited semiconductor alloy extending between and in contact with the source region and the drain region, and wherein the gate insulator and the gate electrode are positioned to apply an electric field to the semiconductor alloy between the source region and the drain region to cause electrical conduction therebetween.
4. A transistor device according to any one of the preceding claims, wherein the deposited semiconductor is an n-type semi- conductor.
5. A transistor device according to any one of the preceding claims, wherein the deposited semiconductor is an amorphous al loy.
6. A transistor device according to claim 5, wherein the alloy includes fluorine.
7. A transistor device according to claim 5 or claim 6, wherein the alloy includes silicon and hydrogen.
8. A transistor device according to claim 7, wherein the alloy has the empirical formula Siz,FbHc where a is between 80 and 98 atomic percent, b is between 1 and 10 atomic per cent, and c is between 1 and 10 atomic percent.
ir z z 7 GB 2 131 605A 7 the deposits whereby to expose edges of the drain region, the semiconductor alloy and the source region; depositing the gate insulator over the exposed edges of the drain region, the semiconductor alloy, and the source region; and depositing the gate electrode over the gate insulator.
22. A method according to claim 21, wherein the drain region is an amorphous, p- -10 type semiconductor alloy.
23. A method according to claim 22, wherein the drain region alloy includes silicon.
24. A method according to claim 22 or claim 23, wherein the drain region alloy in15 cludes fluorine.
25. A method according to any one of claims 21 to 24, wherein the drain region is deposited by glow discharge.
26. A method according to any one of claims 21 to 25, wherein the semiconductor alloy includes fluorine.
27. A method according to claim 26, wherein the semiconductor alloy includes silicon and fluorine.
28. A method according to any one of claims 21 to 27, wherein the semiconductor alloy is deposited by glow discharge.
29. A method according to any one of claims 21 to 28, wherein the source region is an amorphous, p-type semiconductor alloy.
30. A method according to claim 29, wherein the source region alloy includes silicon.
31. A method according to claim 29 or claim 30, wherein the source region alloy include fluorine.
32. A method according to any one of claims 21 to 31, wherein the source region is deposited by glow discharge.
33. A method according to any oine of claims 21 to 32, wherein the drain region is deposited to a thickness of between 500 and 20,000 angstroms.
34. A method according to any one of claims 21 to 33, wherein the semiconductor alloy is deposited to a thickness of between 100 and 5000 angstroms.
35. A method according to any one of claims 21 to 34, wherein the source region is deposited to a thickness of between 500 and 20,000 angstroms.
36. A method according to any one of claim 21 to 35, including the steps of depositing the drain region on the substrate as a y- axis conductor to an adjacent, thin film, vertical, field effect transistor device; depositing the source region as an x-axis conductor to another adjacent, thin film, vertical, field effect transistor device; and depositing the gate electrode horizontally parallel to the y-axis conductor to an adjacent, thin film, vertical, field effect transistor device; whereby to form a filed effect transistor matrix.
37. A method according to any one of claims 21 to 36, further including the steps of depositing an insulating layer on top of the gate electrode and the source region; and forming another thin film, vertical, field effect transistor device on top of the first transistor 70 device, whereby to form a transistor stack.
Printed for Her Majesty's Stationery Office by Burgess & Son (Abingdon) Ltd-1 984. Published at The Patent Office, 25 Southampton Buildings, London, WC2A 1 AY, from which copies may be obtained.
Applications Claiming Priority (2)
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US10301179A | 1979-12-13 | 1979-12-13 | |
US20827880A | 1980-11-19 | 1980-11-19 |
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GB8326775D0 GB8326775D0 (en) | 1983-11-09 |
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GB2131605B GB2131605B (en) | 1985-02-13 |
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GB8039608A Expired GB2067353B (en) | 1979-12-13 | 1980-12-10 | Thin film transistor |
GB08326775A Expired GB2131605B (en) | 1979-12-13 | 1983-10-06 | Thin film transistor |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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GB8039608A Expired GB2067353B (en) | 1979-12-13 | 1980-12-10 | Thin film transistor |
Country Status (14)
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KR (2) | KR840001605B1 (en) |
AU (2) | AU538008B2 (en) |
BE (1) | BE886630A (en) |
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DE (2) | DE3051063C2 (en) |
FR (1) | FR2474763B1 (en) |
GB (2) | GB2067353B (en) |
IE (1) | IE51076B1 (en) |
IL (1) | IL61679A (en) |
IT (1) | IT1193999B (en) |
MX (1) | MX151189A (en) |
NL (2) | NL8006770A (en) |
SE (1) | SE8008738L (en) |
SG (1) | SG72684G (en) |
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US6294796B1 (en) | 1982-04-13 | 2001-09-25 | Seiko Epson Corporation | Thin film transistors and active matrices including same |
US5698864A (en) * | 1982-04-13 | 1997-12-16 | Seiko Epson Corporation | Method of manufacturing a liquid crystal device having field effect transistors |
US5736751A (en) * | 1982-04-13 | 1998-04-07 | Seiko Epson Corporation | Field effect transistor having thick source and drain regions |
FR2527385B1 (en) * | 1982-04-13 | 1987-05-22 | Suwa Seikosha Kk | THIN FILM TRANSISTOR AND LIQUID CRYSTAL DISPLAY PANEL USING THIS TYPE OF TRANSISTOR |
US5365079A (en) * | 1982-04-30 | 1994-11-15 | Seiko Epson Corporation | Thin film transistor and display device including same |
US5677547A (en) * | 1982-04-30 | 1997-10-14 | Seiko Epson Corporation | Thin film transistor and display device including same |
US5650637A (en) * | 1982-04-30 | 1997-07-22 | Seiko Epson Corporation | Active matrix assembly |
US4547789A (en) * | 1983-11-08 | 1985-10-15 | Energy Conversion Devices, Inc. | High current thin film transistor |
US4620208A (en) * | 1983-11-08 | 1986-10-28 | Energy Conversion Devices, Inc. | High performance, small area thin film transistor |
US4633284A (en) * | 1983-11-08 | 1986-12-30 | Energy Conversion Devices, Inc. | Thin film transistor having an annealed gate oxide and method of making same |
US4543320A (en) * | 1983-11-08 | 1985-09-24 | Energy Conversion Devices, Inc. | Method of making a high performance, small area thin film transistor |
US4752814A (en) * | 1984-03-12 | 1988-06-21 | Xerox Corporation | High voltage thin film transistor |
US4673957A (en) * | 1984-05-14 | 1987-06-16 | Energy Conversion Devices, Inc. | Integrated circuit compatible thin film field effect transistor and method of making same |
US4769338A (en) * | 1984-05-14 | 1988-09-06 | Energy Conversion Devices, Inc. | Thin film field effect transistor and method of making same |
US4670763A (en) * | 1984-05-14 | 1987-06-02 | Energy Conversion Devices, Inc. | Thin film field effect transistor |
US4668968A (en) * | 1984-05-14 | 1987-05-26 | Energy Conversion Devices, Inc. | Integrated circuit compatible thin film field effect transistor and method of making same |
KR100741798B1 (en) * | 2004-12-30 | 2007-07-25 | 엘지전자 주식회사 | Washing machine with a integrated drier |
CN112420821B (en) * | 2020-10-29 | 2021-11-19 | 北京元芯碳基集成电路研究院 | Y-shaped gate structure based on carbon-based material and preparation method thereof |
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US3384792A (en) * | 1965-06-01 | 1968-05-21 | Electro Optical Systems Inc | Stacked electrode field effect triode |
US4115799A (en) * | 1977-01-26 | 1978-09-19 | Westinghouse Electric Corp. | Thin film copper transition between aluminum and indium copper films |
US4217374A (en) * | 1978-03-08 | 1980-08-12 | Energy Conversion Devices, Inc. | Amorphous semiconductors equivalent to crystalline semiconductors |
DE2820331C3 (en) * | 1978-05-10 | 1982-03-18 | Lüder, Ernst, Prof. Dr.-Ing., 7000 Stuttgart | Thin film field effect transistor and process for its manufacture |
GB2052853A (en) * | 1979-06-29 | 1981-01-28 | Ibm | Vertical fet on an insulating substrate |
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1980
- 1980-12-09 DE DE3051063A patent/DE3051063C2/de not_active Expired - Fee Related
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- 1980-12-11 MX MX185169A patent/MX151189A/en unknown
- 1980-12-12 IT IT26642/80A patent/IT1193999B/en active
- 1980-12-12 KR KR1019800004728A patent/KR840001605B1/en active
- 1980-12-12 BE BE0/203147A patent/BE886630A/en not_active IP Right Cessation
- 1980-12-12 IE IE2615/80A patent/IE51076B1/en unknown
- 1980-12-12 SE SE8008738A patent/SE8008738L/en unknown
- 1980-12-12 AU AU65313/80A patent/AU538008B2/en not_active Ceased
- 1980-12-12 CA CA000366712A patent/CA1153480A/en not_active Expired
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- 1980-12-12 FR FR8026402A patent/FR2474763B1/en not_active Expired
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1983
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- 1983-10-06 GB GB08326775A patent/GB2131605B/en not_active Expired
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1984
- 1984-05-21 AU AU28451/84A patent/AU554058B2/en not_active Ceased
- 1984-06-18 NL NL8401928A patent/NL8401928A/en not_active Application Discontinuation
- 1984-07-14 KR KR1019840004146A patent/KR850000902B1/en not_active IP Right Cessation
- 1984-08-01 CA CA000460196A patent/CA1188008A/en not_active Expired
- 1984-10-17 SG SG726/84A patent/SG72684G/en unknown
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KR850000902B1 (en) | 1985-06-26 |
KR850001478A (en) | 1985-02-18 |
BE886630A (en) | 1981-04-01 |
GB2067353B (en) | 1984-07-04 |
AU554058B2 (en) | 1986-08-07 |
DE3051063C2 (en) | 1991-04-11 |
SE8008738L (en) | 1981-06-14 |
CA1163377A (en) | 1984-03-06 |
KR830004680A (en) | 1983-07-16 |
MX151189A (en) | 1984-10-09 |
CA1153480A (en) | 1983-09-06 |
GB2131605B (en) | 1985-02-13 |
CA1188008A (en) | 1985-05-28 |
DE3046358A1 (en) | 1981-09-17 |
FR2474763A1 (en) | 1981-07-31 |
IT8026642A0 (en) | 1980-12-12 |
IE51076B1 (en) | 1986-10-01 |
IL61679A0 (en) | 1981-01-30 |
KR840001605B1 (en) | 1984-10-11 |
GB8326775D0 (en) | 1983-11-09 |
IL61679A (en) | 1984-11-30 |
GB2067353A (en) | 1981-07-22 |
AU2845184A (en) | 1984-09-13 |
FR2474763B1 (en) | 1987-03-20 |
AU6531380A (en) | 1981-06-18 |
AU538008B2 (en) | 1984-07-26 |
NL8006770A (en) | 1981-07-16 |
IE802615L (en) | 1981-06-13 |
SG72684G (en) | 1985-03-29 |
IT1193999B (en) | 1988-08-31 |
DE3046358C2 (en) | 1987-02-26 |
NL8401928A (en) | 1984-10-01 |
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