GB2021589A - Process for Preparation of Compounds Containing Phosphorus-Carbon-Nitrogen Bond - Google Patents
Process for Preparation of Compounds Containing Phosphorus-Carbon-Nitrogen BondInfo
- Publication number
- GB2021589A GB2021589A GB7911510A GB7911510A GB2021589A GB 2021589 A GB2021589 A GB 2021589A GB 7911510 A GB7911510 A GB 7911510A GB 7911510 A GB7911510 A GB 7911510A GB 2021589 A GB2021589 A GB 2021589A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon
- preparation
- compounds containing
- nitrogen bond
- containing phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- -1 phosphorus halide Chemical class 0.000 abstract 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Luminescent Compositions (AREA)
Abstract
The invention relates to compounds containing phosphorus- carbon-nitrogen bond of the general formula I <IMAGE> wherein R1 and R2 are the same or different and stand for hydrogen or an organic radical, R3 and R4 are the same or different and stand for hydrogen, hydroxy or an organic radical. The compounds are prepared by reacting a phosphorus halide with ammonia, water soluble ammonium salts, primary or secondary amine in the presence of water and further with aldehyde or ketone. The product is recovered by reducing the reaction volume or by adding a water miscible organic solvent to the reaction mixture. The process is preferably suitable for the preparation of N-phosphono- methylglycine and derivatives thereof, which are significant in plant protection as herbicidally active compounds.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU78NI213A HU177486B (en) | 1978-04-11 | 1978-04-11 | Process for preparing phosphonic acid derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2021589A true GB2021589A (en) | 1979-12-05 |
| GB2021589B GB2021589B (en) | 1982-10-20 |
Family
ID=11000006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7911510A Expired GB2021589B (en) | 1978-04-11 | 1979-04-03 | Process for preparation of compounds containing phosphorous-carbonnitrogen bond |
Country Status (30)
| Country | Link |
|---|---|
| JP (1) | JPS554362A (en) |
| AR (1) | AR227625A1 (en) |
| AT (1) | AT373602B (en) |
| BE (1) | BE875501A (en) |
| BG (1) | BG34334A3 (en) |
| BR (1) | BR7900568A (en) |
| CA (1) | CA1135279A (en) |
| CH (1) | CH642666A5 (en) |
| CS (1) | CS239903B2 (en) |
| DD (1) | DD142888A5 (en) |
| DE (1) | DE2914294C2 (en) |
| DK (1) | DK149473C (en) |
| EG (1) | EG13622A (en) |
| ES (1) | ES471960A1 (en) |
| FR (1) | FR2422675B1 (en) |
| GB (1) | GB2021589B (en) |
| GR (1) | GR67713B (en) |
| HU (1) | HU177486B (en) |
| IL (1) | IL57008A0 (en) |
| IN (1) | IN149779B (en) |
| IT (1) | IT1118553B (en) |
| LU (1) | LU81126A1 (en) |
| NL (1) | NL7902854A (en) |
| NO (1) | NO160373C (en) |
| PL (1) | PL123998B1 (en) |
| PT (1) | PT69461A (en) |
| RO (1) | RO78631A (en) |
| SU (1) | SU776561A3 (en) |
| TR (1) | TR20811A (en) |
| YU (1) | YU41154B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2154588A (en) * | 1984-02-20 | 1985-09-11 | Sunlead Chemical Industry Co L | A process for preparation of N-phosphonomethyl glycine |
| GB2224506A (en) * | 1988-11-02 | 1990-05-09 | Albright & Wilson | Purification of amino organic phosphonic acids |
| US7084298B2 (en) | 2001-01-12 | 2006-08-01 | Basf Aktiengesellschaft | Method for producing n-phosphonomethyl iminodiacetic acid |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL72142A0 (en) * | 1983-08-17 | 1984-10-31 | Stauffer Chemical Co | Preparation of phosphonomethylated amino acids |
| JPS6134834U (en) * | 1985-07-24 | 1986-03-03 | 三菱農機株式会社 | Mounting device for fertilizer tank, etc. on riding paddy field work machine with fertilization device |
| HU205944B (en) * | 1988-02-08 | 1992-07-28 | Nitrokemia Ipartelepek | Process for producing n-phosphono-methyl-imino-diacetic acid |
| HU203360B (en) * | 1988-11-25 | 1991-07-29 | Monsanto Co | Process for producing n-acylamino methylphosphonates |
| JP2525977B2 (en) * | 1991-10-17 | 1996-08-21 | 昭和電工株式会社 | Process for producing N-acylaminomethylphosphonic acid |
| US5495042A (en) * | 1993-11-04 | 1996-02-27 | Cytogen Corporation | Non-alkaline purification of aminophosphonic acids |
| CN100400543C (en) * | 2006-09-08 | 2008-07-09 | 四川贝尔实业有限责任公司 | Method for preparing Phosphonomethyl iminodiacetic acid (PMIDA) through hydrolysis of imino diacetonitrile |
-
1978
- 1978-04-11 HU HU78NI213A patent/HU177486B/en not_active IP Right Cessation
- 1978-07-21 ES ES471960A patent/ES471960A1/en not_active Expired
- 1978-08-03 SU SU782643651A patent/SU776561A3/en active
-
1979
- 1979-01-30 BR BR7900568A patent/BR7900568A/en unknown
- 1979-03-30 CH CH296679A patent/CH642666A5/en not_active IP Right Cessation
- 1979-04-03 GR GR58770A patent/GR67713B/el unknown
- 1979-04-03 GB GB7911510A patent/GB2021589B/en not_active Expired
- 1979-04-03 FR FR7908315A patent/FR2422675B1/en not_active Expired
- 1979-04-03 IN IN332/CAL/79A patent/IN149779B/en unknown
- 1979-04-05 IL IL57008A patent/IL57008A0/en unknown
- 1979-04-06 CS CS792378A patent/CS239903B2/en unknown
- 1979-04-06 LU LU81126A patent/LU81126A1/en unknown
- 1979-04-07 EG EG208/79A patent/EG13622A/en active
- 1979-04-09 DE DE2914294A patent/DE2914294C2/en not_active Expired
- 1979-04-09 RO RO7997178A patent/RO78631A/en unknown
- 1979-04-09 AT AT0263179A patent/AT373602B/en not_active IP Right Cessation
- 1979-04-10 NO NO791217A patent/NO160373C/en unknown
- 1979-04-10 PL PL1979214793A patent/PL123998B1/en unknown
- 1979-04-10 YU YU850/79A patent/YU41154B/en unknown
- 1979-04-10 TR TR20811A patent/TR20811A/en unknown
- 1979-04-10 BG BG7943195A patent/BG34334A3/en unknown
- 1979-04-10 DK DK148679A patent/DK149473C/en not_active IP Right Cessation
- 1979-04-10 PT PT69461A patent/PT69461A/en unknown
- 1979-04-11 AR AR276155A patent/AR227625A1/en active
- 1979-04-11 JP JP4409879A patent/JPS554362A/en active Pending
- 1979-04-11 NL NL7902854A patent/NL7902854A/en not_active Application Discontinuation
- 1979-04-11 BE BE0/194546A patent/BE875501A/en not_active IP Right Cessation
- 1979-04-11 IT IT67767/79A patent/IT1118553B/en active
- 1979-04-11 CA CA000325294A patent/CA1135279A/en not_active Expired
- 1979-04-11 DD DD79212157A patent/DD142888A5/en not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2154588A (en) * | 1984-02-20 | 1985-09-11 | Sunlead Chemical Industry Co L | A process for preparation of N-phosphonomethyl glycine |
| GB2224506A (en) * | 1988-11-02 | 1990-05-09 | Albright & Wilson | Purification of amino organic phosphonic acids |
| US5008015A (en) * | 1988-11-02 | 1991-04-16 | Albright & Wilson Limited | Purification of phosphorus compounds |
| GB2224506B (en) * | 1988-11-02 | 1992-06-17 | Albright & Wilson | Purification of aminophosphonic acids |
| US7084298B2 (en) | 2001-01-12 | 2006-08-01 | Basf Aktiengesellschaft | Method for producing n-phosphonomethyl iminodiacetic acid |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |