GB2018774A - Process of preparation of 2- mercaptobenzthiazole - Google Patents
Process of preparation of 2- mercaptobenzthiazoleInfo
- Publication number
- GB2018774A GB2018774A GB7913139A GB7913139A GB2018774A GB 2018774 A GB2018774 A GB 2018774A GB 7913139 A GB7913139 A GB 7913139A GB 7913139 A GB7913139 A GB 7913139A GB 2018774 A GB2018774 A GB 2018774A
- Authority
- GB
- United Kingdom
- Prior art keywords
- molar ratio
- nitrosobenzene
- reacted
- nitrobenzene
- specified molar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 8
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract 5
- NLRKCXQQSUWLCH-UHFFFAOYSA-N nitrosobenzene Chemical compound O=NC1=CC=CC=C1 NLRKCXQQSUWLCH-UHFFFAOYSA-N 0.000 abstract 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/70—Sulfur atoms
- C07D277/72—2-Mercaptobenzothiazole
Abstract
A process for the preparation of 2- mercaptobenzthiazole which comprises reacting nitrobenzene or nitrosobenzene, hydrogen sulphide and carbon disulphide, the molar ratio of nitrobenzene or nitrosobenzene: hydrogen sulphide being from 1:3 to 1:6 or from 1:1.5 to 1:4, the molar ratio of nitrobenzene or nitrosobenzene: carbon disulphide being from 1:1 to 1:3 and the final reaction temperature being from 200 to 300 DEG C, is disclosed. Embodiments are disclosed wherein (a) nitrobenzene and H25 are reacted in a specified molar ratio under elevated temperature and pressure and the resulting reaction mixture is reacted with CS2 in a specified molar ratio at 200 to 300 DEG C; (b) nitrosobenzene, H25 and C52 are reacted in a specified molar ratio at 200 to 300 DEG C; and (c) nitrosobenzene and H25 are reacted in a specified molar ratio at 20 to 100 DEG C and the resulting reaction mixture is reacted with C52 in a specified molar ratio at 200 to 300 DEG C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782816503 DE2816503C3 (en) | 1978-04-15 | 1978-04-15 | Process for the preparation of 2-mercaptobenzothiazole |
DE2816407A DE2816407C3 (en) | 1978-04-15 | 1978-04-15 | Process for the preparation of 2-mercaptobenzothiazole |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2018774A true GB2018774A (en) | 1979-10-24 |
GB2018774B GB2018774B (en) | 1982-12-01 |
Family
ID=25774251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7913139A Expired GB2018774B (en) | 1978-04-15 | 1979-04-12 | Process for the preparation of 2-mercaptobenzthiazole |
Country Status (13)
Country | Link |
---|---|
JP (1) | JPS54138555A (en) |
BR (1) | BR7902252A (en) |
CS (1) | CS209920B2 (en) |
DD (1) | DD142879A5 (en) |
ES (1) | ES479380A1 (en) |
FR (1) | FR2432514A1 (en) |
GB (1) | GB2018774B (en) |
HU (1) | HU179918B (en) |
IT (1) | IT1117172B (en) |
NL (1) | NL7902705A (en) |
PL (1) | PL119658B1 (en) |
RO (1) | RO77250A (en) |
SU (1) | SU1005661A3 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997046544A1 (en) * | 1996-06-03 | 1997-12-11 | Akzo Nobel N.V. | Acid catalysed process for preparing 2-mercaptobenzothiazole and derivatives thereof |
US6222041B1 (en) | 2000-02-24 | 2001-04-24 | Uniroyal Chemical Company, Inc. | Method for the production of 2-mercaptobenzothiazole |
-
1979
- 1979-04-06 ES ES479380A patent/ES479380A1/en not_active Expired
- 1979-04-06 NL NL7902705A patent/NL7902705A/en not_active Application Discontinuation
- 1979-04-11 CS CS792479A patent/CS209920B2/en unknown
- 1979-04-11 PL PL1979214829A patent/PL119658B1/en unknown
- 1979-04-11 BR BR7902252A patent/BR7902252A/en unknown
- 1979-04-11 IT IT48697/79A patent/IT1117172B/en active
- 1979-04-12 GB GB7913139A patent/GB2018774B/en not_active Expired
- 1979-04-12 DD DD79212194A patent/DD142879A5/en unknown
- 1979-04-12 FR FR7909358A patent/FR2432514A1/en active Granted
- 1979-04-13 JP JP4441279A patent/JPS54138555A/en active Pending
- 1979-04-13 RO RO7997222A patent/RO77250A/en unknown
- 1979-04-13 HU HU79AO478A patent/HU179918B/en unknown
- 1979-04-13 SU SU792753405A patent/SU1005661A3/en active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997046544A1 (en) * | 1996-06-03 | 1997-12-11 | Akzo Nobel N.V. | Acid catalysed process for preparing 2-mercaptobenzothiazole and derivatives thereof |
US6222041B1 (en) | 2000-02-24 | 2001-04-24 | Uniroyal Chemical Company, Inc. | Method for the production of 2-mercaptobenzothiazole |
WO2001062748A1 (en) * | 2000-02-24 | 2001-08-30 | Uniroyal Chemical Company, Inc. | Method for the production of 2-mercaptobenzothiazole |
Also Published As
Publication number | Publication date |
---|---|
GB2018774B (en) | 1982-12-01 |
CS209920B2 (en) | 1981-12-31 |
BR7902252A (en) | 1979-12-04 |
FR2432514B1 (en) | 1983-07-29 |
HU179918B (en) | 1983-01-28 |
IT1117172B (en) | 1986-02-17 |
DD142879A5 (en) | 1980-07-16 |
ES479380A1 (en) | 1979-07-16 |
NL7902705A (en) | 1979-10-17 |
SU1005661A3 (en) | 1983-03-15 |
IT7948697A0 (en) | 1979-04-11 |
FR2432514A1 (en) | 1980-02-29 |
RO77250A (en) | 1981-08-17 |
JPS54138555A (en) | 1979-10-27 |
PL119658B1 (en) | 1982-01-30 |
PL214829A1 (en) | 1980-01-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |