GB1592271A - Overtreated higher dialkyl dimethyl ammonium clay gellants and their use in greases - Google Patents
Overtreated higher dialkyl dimethyl ammonium clay gellants and their use in greases Download PDFInfo
- Publication number
- GB1592271A GB1592271A GB36559/77A GB3655977A GB1592271A GB 1592271 A GB1592271 A GB 1592271A GB 36559/77 A GB36559/77 A GB 36559/77A GB 3655977 A GB3655977 A GB 3655977A GB 1592271 A GB1592271 A GB 1592271A
- Authority
- GB
- United Kingdom
- Prior art keywords
- clay
- ammonium
- quaternary
- gellant
- dimethyl ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004927 clay Substances 0.000 title claims description 146
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 title claims description 85
- 239000003349 gelling agent Substances 0.000 title claims description 66
- 239000000203 mixture Substances 0.000 claims description 74
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 37
- 238000005342 ion exchange Methods 0.000 claims description 35
- 229920000098 polyolefin Polymers 0.000 claims description 31
- 229920000180 alkyd Polymers 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 22
- -1 ammonium ions Chemical class 0.000 claims description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 19
- 239000000376 reactant Substances 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 17
- 230000009974 thixotropic effect Effects 0.000 claims description 16
- 239000004519 grease Substances 0.000 claims description 15
- 239000012530 fluid Substances 0.000 claims description 14
- 229920000728 polyester Polymers 0.000 claims description 12
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims description 11
- 239000005695 Ammonium acetate Substances 0.000 claims description 11
- 235000019257 ammonium acetate Nutrition 0.000 claims description 11
- 229940043376 ammonium acetate Drugs 0.000 claims description 11
- 239000000314 lubricant Substances 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 8
- 239000011707 mineral Substances 0.000 claims description 8
- 229920006305 unsaturated polyester Polymers 0.000 claims description 8
- 150000003863 ammonium salts Chemical class 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003495 polar organic solvent Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000012429 reaction media Substances 0.000 claims description 4
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 125000001174 sulfone group Chemical group 0.000 claims 1
- 239000000047 product Substances 0.000 description 40
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 36
- 229910052901 montmorillonite Inorganic materials 0.000 description 33
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 24
- 239000000499 gel Substances 0.000 description 20
- 238000003756 stirring Methods 0.000 description 20
- 150000003839 salts Chemical group 0.000 description 18
- 230000000694 effects Effects 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- 239000002585 base Substances 0.000 description 16
- 239000007788 liquid Substances 0.000 description 16
- 239000003921 oil Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 12
- XRHCAGNSDHCHFJ-UHFFFAOYSA-N Ethylene brassylate Chemical compound O=C1CCCCCCCCCCCC(=O)OCCO1 XRHCAGNSDHCHFJ-UHFFFAOYSA-N 0.000 description 10
- 150000002430 hydrocarbons Chemical class 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 125000001453 quaternary ammonium group Chemical group 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 229910000323 aluminium silicate Inorganic materials 0.000 description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- NSXJEEMTGWMJPY-UHFFFAOYSA-N 9-[3-(3-carbazol-9-ylphenyl)phenyl]carbazole Chemical compound C12=CC=CC=C2C2=CC=CC=C2N1C1=CC(C=2C=CC=C(C=2)N2C3=CC=CC=C3C3=CC=CC=C32)=CC=C1 NSXJEEMTGWMJPY-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
- 230000002411 adverse Effects 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 5
- 235000012216 bentonite Nutrition 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 5
- 150000001805 chlorine compounds Chemical group 0.000 description 5
- 230000001419 dependent effect Effects 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 150000002500 ions Chemical group 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- 239000000440 bentonite Substances 0.000 description 3
- 229910000278 bentonite Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 2
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
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- 238000010438 heat treatment Methods 0.000 description 2
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 2
- 229910000271 hectorite Inorganic materials 0.000 description 2
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
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- JZXZMBFPQJNGJF-UHFFFAOYSA-N CC#N.C=1C=COC=1 Chemical compound CC#N.C=1C=COC=1 JZXZMBFPQJNGJF-UHFFFAOYSA-N 0.000 description 1
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- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
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Classifications
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/044—Polyamides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/780,451 US4317737A (en) | 1977-03-23 | 1977-03-23 | Polyolefin based greases gelled by clays overtreated by higher dialkyl dimethyl ammonium salts |
| US05/780,450 US4365030A (en) | 1974-09-27 | 1977-03-23 | Overtreated higher dialkyl dimethyl ammonium clay gellants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1592271A true GB1592271A (en) | 1981-07-01 |
Family
ID=27119704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB36559/77A Expired GB1592271A (en) | 1977-03-23 | 1977-09-01 | Overtreated higher dialkyl dimethyl ammonium clay gellants and their use in greases |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS53118282A (enrdf_load_stackoverflow) |
| DE (1) | DE2739504A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1592271A (enrdf_load_stackoverflow) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4391637A (en) | 1981-10-19 | 1983-07-05 | Nl Industries, Inc. | Rheological additive for non-aqueous fluid systems |
| US4434075A (en) | 1981-10-19 | 1984-02-28 | Nl Industries, Inc. | Anionically modified organophilic clays and their preparation |
| US4434076A (en) | 1981-10-19 | 1984-02-28 | Nl Industries, Inc. | Clay cation complexes and their use to increase viscosity of liquid organic systems |
| US4450095A (en) * | 1980-11-17 | 1984-05-22 | Nl Industries, Inc. | Organophilic clay gellant having enhanced dispersibility |
| US4517112A (en) * | 1982-02-18 | 1985-05-14 | Nl Industries, Inc. | Modified organophilic clay complexes, their preparation and non-aqueous systems containing them |
| GB2175291A (en) * | 1985-05-04 | 1986-11-26 | Perchem Ltd | Organoclays |
| US4664820A (en) * | 1985-10-28 | 1987-05-12 | Nl Industries, Inc. | Preactivated organophilic clay gellant lubricating grease thickened with preactivated organophilic clay gellant and process for preparing preactivated organophilic clay gellants |
| US4695402A (en) * | 1985-08-20 | 1987-09-22 | Nl Chemicals, Inc. | Organophilic clay gellants and process for preparation |
| US4742098A (en) * | 1985-08-20 | 1988-05-03 | Nl Chemicals, Inc. | Organophilic clay gellants and process for preparation |
| US4929644A (en) * | 1986-10-24 | 1990-05-29 | Rheox, Inc. | Thickened organic composition having biocidal activity and an additive for thickening and imparting biocidal activity to an organic composition |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4081496A (en) * | 1977-06-27 | 1978-03-28 | N L Industries, Inc. | Thixotropic polyester compositions containing an organophilic clay gellant |
| DE3145449C2 (de) * | 1980-11-17 | 1995-05-24 | Rheox Int | Organophiles Tongelbildungsmittel und dessen Verwendung zur Steigerung der Viskosität |
| US4412018A (en) * | 1980-11-17 | 1983-10-25 | Nl Industries, Inc. | Organophilic clay complexes, their preparation and compositions comprising said complexes |
| DE3145423A1 (de) * | 1980-11-17 | 1982-07-29 | NL Industries, Inc., 10020 New York, N.Y. | Nicht-waessriges fluides system und dieses enthaltendeanstrichmittelzusammensetzung |
| DE3149131A1 (de) * | 1981-12-11 | 1983-06-23 | Henkel KGaA, 4000 Düsseldorf | Synthetische schichtsilikate modifiziert mit quartaeren ammoniumverbindungen |
| GB8407531D0 (en) * | 1984-03-22 | 1984-05-02 | Laporte Industries Ltd | Organophilic clay gellants |
| US4582866A (en) * | 1984-04-30 | 1986-04-15 | E. I. Du Pont De Nemours And Company | Flame retardant thermoplastic multi-block copolyester elastomers |
| JPS6474294A (en) * | 1987-09-17 | 1989-03-20 | Nippon Steel Corp | Production of lubricating grease |
| JP2605373B2 (ja) * | 1988-08-23 | 1997-04-30 | エヌオーケー株式会社 | 機能性流体の製造法 |
| DE10343130A1 (de) * | 2003-09-18 | 2005-04-28 | Karlsruhe Forschzent | Modifizierte Zweischicht-Tonminerale, Verfahren zu deren Herstellung und ihre Verwendung |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE929791C (de) * | 1948-10-19 | 1955-07-04 | Nat Lead Co | Verfahren zum Herstellen von gelbildenden organophilen Tonen |
| US3755166A (en) * | 1972-06-28 | 1973-08-28 | Witco Corp | Grease sealant |
| GB1439828A (en) * | 1973-04-17 | 1976-06-16 | Laporte Industries Ltd | Organophilic clay mineral derivatives |
| US3974125A (en) * | 1974-09-27 | 1976-08-10 | Exxon Research And Engineering Company | Higher dialkyl dimethyl ammonium clay gelling agents for unsaturated polyester compositions |
-
1977
- 1977-09-01 GB GB36559/77A patent/GB1592271A/en not_active Expired
- 1977-09-02 JP JP10574777A patent/JPS53118282A/ja active Granted
- 1977-09-02 DE DE19772739504 patent/DE2739504A1/de not_active Ceased
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4450095A (en) * | 1980-11-17 | 1984-05-22 | Nl Industries, Inc. | Organophilic clay gellant having enhanced dispersibility |
| US4391637A (en) | 1981-10-19 | 1983-07-05 | Nl Industries, Inc. | Rheological additive for non-aqueous fluid systems |
| US4434075A (en) | 1981-10-19 | 1984-02-28 | Nl Industries, Inc. | Anionically modified organophilic clays and their preparation |
| US4434076A (en) | 1981-10-19 | 1984-02-28 | Nl Industries, Inc. | Clay cation complexes and their use to increase viscosity of liquid organic systems |
| US4517112A (en) * | 1982-02-18 | 1985-05-14 | Nl Industries, Inc. | Modified organophilic clay complexes, their preparation and non-aqueous systems containing them |
| GB2175291A (en) * | 1985-05-04 | 1986-11-26 | Perchem Ltd | Organoclays |
| GB2175291B (en) * | 1985-05-04 | 1989-07-12 | Perchem Ltd | Organoclays |
| US4695402A (en) * | 1985-08-20 | 1987-09-22 | Nl Chemicals, Inc. | Organophilic clay gellants and process for preparation |
| US4742098A (en) * | 1985-08-20 | 1988-05-03 | Nl Chemicals, Inc. | Organophilic clay gellants and process for preparation |
| US4664820A (en) * | 1985-10-28 | 1987-05-12 | Nl Industries, Inc. | Preactivated organophilic clay gellant lubricating grease thickened with preactivated organophilic clay gellant and process for preparing preactivated organophilic clay gellants |
| US4929644A (en) * | 1986-10-24 | 1990-05-29 | Rheox, Inc. | Thickened organic composition having biocidal activity and an additive for thickening and imparting biocidal activity to an organic composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6111273B2 (enrdf_load_stackoverflow) | 1986-04-02 |
| DE2739504A1 (de) | 1978-09-28 |
| JPS53118282A (en) | 1978-10-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |