GB1574188A - Production of esters of carbonic acid - Google Patents
Production of esters of carbonic acid Download PDFInfo
- Publication number
- GB1574188A GB1574188A GB35784/77A GB3578477A GB1574188A GB 1574188 A GB1574188 A GB 1574188A GB 35784/77 A GB35784/77 A GB 35784/77A GB 3578477 A GB3578477 A GB 3578477A GB 1574188 A GB1574188 A GB 1574188A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- methanol
- salt
- carbonic acid
- atmospheres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 title description 8
- 150000002148 esters Chemical class 0.000 title description 7
- 238000004519 manufacturing process Methods 0.000 title description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 48
- 238000006243 chemical reaction Methods 0.000 description 32
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 17
- 238000000034 method Methods 0.000 description 16
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 10
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 229940108928 copper Drugs 0.000 description 8
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 description 4
- 229960003280 cupric chloride Drugs 0.000 description 4
- 229940045803 cuprous chloride Drugs 0.000 description 4
- 150000001449 anionic compounds Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910001412 inorganic anion Inorganic materials 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 2
- 229910021590 Copper(II) bromide Inorganic materials 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- -1 carbonate ester Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 235000014987 copper Nutrition 0.000 description 1
- 150000001880 copper compounds Chemical group 0.000 description 1
- 229910000336 copper(I) sulfate Inorganic materials 0.000 description 1
- NKNDPYCGAZPOFS-UHFFFAOYSA-M copper(i) bromide Chemical compound Br[Cu] NKNDPYCGAZPOFS-UHFFFAOYSA-M 0.000 description 1
- WIVXEZIMDUGYRW-UHFFFAOYSA-L copper(i) sulfate Chemical compound [Cu+].[Cu+].[O-]S([O-])(=O)=O WIVXEZIMDUGYRW-UHFFFAOYSA-L 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JILPJDVXYVTZDQ-UHFFFAOYSA-N lithium methoxide Chemical compound [Li+].[O-]C JILPJDVXYVTZDQ-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/01—Preparation of esters of carbonic or haloformic acids from carbon monoxide and oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT27825/76A IT1070574B (it) | 1976-09-30 | 1976-09-30 | Procedimento per la preparazione di esteri dell acido carbonico |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1574188A true GB1574188A (en) | 1980-09-03 |
Family
ID=11222406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB35784/77A Expired GB1574188A (en) | 1976-09-30 | 1977-08-25 | Production of esters of carbonic acid |
Country Status (12)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5461028A (en) * | 1990-06-07 | 1995-10-24 | Henkel Kommanditgesellschaft Auf Aktien | Fluid-drill-hole treatment agents based on carbonic acid diesters |
| US5599965A (en) * | 1993-07-30 | 1997-02-04 | Bayer Aktiengesellschaft | Process for the preparation of dialky carbonates |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0071286B1 (en) * | 1981-07-30 | 1985-08-28 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of carbonate esters |
| DE3926709A1 (de) * | 1989-08-12 | 1991-02-14 | Basf Ag | Verfahren zur herstellung von dialkylcarbonaten |
| DE3926710A1 (de) * | 1989-08-12 | 1991-02-14 | Basf Ag | Verfahren zur herstellung von dialkylcarbonaten |
| DE4138755A1 (de) * | 1991-11-26 | 1993-05-27 | Bayer Ag | Verfahren zur herstellung von dialkylcarbonaten |
| DE4140259A1 (de) * | 1991-12-06 | 1993-06-09 | Basf Ag, 6700 Ludwigshafen, De | Verfahren zur herstellung tertiaerer aminoxide |
| DE4203796A1 (de) * | 1992-02-10 | 1993-08-12 | Bayer Ag | Verfahren zur herstellung von dialkylcarbonaten |
| DE4339977A1 (de) * | 1993-11-24 | 1995-06-01 | Bayer Ag | Verfahren zur Aufarbeitung der flüssigen Reaktionsprodukte aus der Cu-katalysierten Dimethylcarbonatherstellung |
| DE4344159A1 (de) * | 1993-12-23 | 1995-06-29 | Bayer Ag | Verfahren zur Herstellung von Dimethylcarbonat |
| US6258923B1 (en) * | 1999-06-11 | 2001-07-10 | General Electric Company | Method for manufacturing dialkyl carbonate |
-
1976
- 1976-09-30 IT IT27825/76A patent/IT1070574B/it active
-
1977
- 1977-08-25 GB GB35784/77A patent/GB1574188A/en not_active Expired
- 1977-09-12 CA CA286,560A patent/CA1098535A/en not_active Expired
- 1977-09-16 JP JP52110621A patent/JPS6058739B2/ja not_active Expired
- 1977-09-27 SU SU772524854A patent/SU1115667A3/ru active
- 1977-09-27 FR FR7729068A patent/FR2366254A1/fr active Granted
- 1977-09-28 DE DE2743690A patent/DE2743690C3/de not_active Expired
- 1977-09-28 LU LU78193A patent/LU78193A1/xx unknown
- 1977-09-29 NL NL7710689A patent/NL7710689A/xx not_active Application Discontinuation
- 1977-09-29 DK DK432077A patent/DK157674C/da not_active IP Right Cessation
- 1977-09-29 AT AT0696277A patent/AT368123B/de not_active IP Right Cessation
- 1977-09-30 BE BE181370A patent/BE859272A/xx not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5461028A (en) * | 1990-06-07 | 1995-10-24 | Henkel Kommanditgesellschaft Auf Aktien | Fluid-drill-hole treatment agents based on carbonic acid diesters |
| US5599965A (en) * | 1993-07-30 | 1997-02-04 | Bayer Aktiengesellschaft | Process for the preparation of dialky carbonates |
Also Published As
| Publication number | Publication date |
|---|---|
| AT368123B (de) | 1982-09-10 |
| FR2366254B1 (enrdf_load_stackoverflow) | 1980-10-17 |
| IT1070574B (it) | 1985-03-29 |
| LU78193A1 (enrdf_load_stackoverflow) | 1978-01-23 |
| CA1098535A (en) | 1981-03-31 |
| DE2743690B2 (enrdf_load_stackoverflow) | 1979-05-03 |
| BE859272A (fr) | 1978-03-30 |
| ATA696277A (de) | 1982-01-15 |
| JPS6058739B2 (ja) | 1985-12-21 |
| DE2743690A1 (de) | 1978-04-06 |
| DE2743690C3 (de) | 1980-01-10 |
| DK157674B (da) | 1990-02-05 |
| SU1115667A3 (ru) | 1984-09-23 |
| JPS5344523A (en) | 1978-04-21 |
| NL7710689A (nl) | 1978-04-03 |
| FR2366254A1 (fr) | 1978-04-28 |
| DK432077A (da) | 1978-03-31 |
| DK157674C (da) | 1990-07-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19970824 |