GB1571210A - Cerium compounds method of obtaining said compounds and applications thereof - Google Patents
Cerium compounds method of obtaining said compounds and applications thereof Download PDFInfo
- Publication number
- GB1571210A GB1571210A GB2643577A GB2643577A GB1571210A GB 1571210 A GB1571210 A GB 1571210A GB 2643577 A GB2643577 A GB 2643577A GB 2643577 A GB2643577 A GB 2643577A GB 1571210 A GB1571210 A GB 1571210A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cerium
- salt
- mixture
- organic acid
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 20
- 150000001785 cerium compounds Chemical class 0.000 title description 7
- 150000001875 compounds Chemical class 0.000 title description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 48
- 150000003839 salts Chemical class 0.000 claims description 46
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 34
- -1 alkyl hydrogen sulphate Chemical compound 0.000 claims description 31
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 239000000446 fuel Substances 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 16
- 239000003973 paint Substances 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000007524 organic acids Chemical class 0.000 claims description 11
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 10
- 239000002966 varnish Substances 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 9
- 239000011833 salt mixture Substances 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000005642 Oleic acid Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 5
- 244000060011 Cocos nucifera Species 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- UNJPQTDTZAKTFK-UHFFFAOYSA-K cerium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ce+3] UNJPQTDTZAKTFK-UHFFFAOYSA-K 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- DPUCLPLBKVSJIB-UHFFFAOYSA-N cerium;tetrahydrate Chemical compound O.O.O.O.[Ce] DPUCLPLBKVSJIB-UHFFFAOYSA-N 0.000 claims description 2
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 150000002910 rare earth metals Chemical group 0.000 claims description 2
- 239000012429 reaction media Substances 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 150000000703 Cerium Chemical class 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000002816 fuel additive Substances 0.000 description 2
- 125000005609 naphthenate group Chemical group 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/12—Straight chain carboxylic acids containing eighteen carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
- C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Paints Or Removers (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7622426A FR2359192A1 (fr) | 1976-07-22 | 1976-07-22 | Composes oleosolubles du cerium, leur procede de preparation et leur application en tant qu'agents siccatifs ou adjuvants de combustion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1571210A true GB1571210A (en) | 1980-07-09 |
Family
ID=9176026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2643577A Expired GB1571210A (en) | 1976-07-22 | 1977-06-23 | Cerium compounds method of obtaining said compounds and applications thereof |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5312907A (ja) |
| AU (1) | AU518590B2 (ja) |
| BE (1) | BE856974A (ja) |
| DE (1) | DE2729365A1 (ja) |
| FR (1) | FR2359192A1 (ja) |
| GB (1) | GB1571210A (ja) |
| IT (1) | IT1202371B (ja) |
| NL (1) | NL7707497A (ja) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2160527A (en) * | 1984-05-25 | 1985-12-24 | Kao Corp | Metal salts of phoshate monoesters |
| US4836830A (en) * | 1986-09-19 | 1989-06-06 | Rhone-Poulenc Inc. | Rare earth compositions for diesel fuel stabilization |
| FR2911607A1 (fr) * | 2007-01-23 | 2008-07-25 | Rhodia Recherches & Tech | Procede de preparation d'une solution d'un organophosphate de terre rare. |
| US9669375B2 (en) | 2012-01-30 | 2017-06-06 | Cerion, Llc | Method for production of stable cerium oxide organic colloids |
| US10544376B2 (en) | 2012-01-30 | 2020-01-28 | Cerion, Llc | Rapid method for production of cerium-containing oxide organic colloids |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2486083B1 (fr) * | 1980-07-01 | 1986-03-07 | Gamlen Europ Sa | Sels organosolubles de manganese, procede de preparation de ceux-ci, compositions organiques, combustibles liquides, peintures et vernis contenant lesdits sels |
| EP0093627B1 (fr) * | 1982-04-12 | 1985-07-10 | Rhone-Poulenc Specialites Chimiques | Procédé pour la préparation de carboxylates cériques |
| US4545923A (en) * | 1982-06-11 | 1985-10-08 | Rhone-Poulenc Inc. | Process for preparing colloidal ceric oxide and complexes thereof with free organic acids |
| US4464227A (en) * | 1982-09-16 | 1984-08-07 | At&T Technologies, Inc. | Methods and apparatus for distilling a contaminated solvent |
| FR2537593B1 (fr) * | 1982-12-10 | 1986-04-11 | Raffinage Cie Francaise | Compositions organometalliques mixtes comprenant des elements des groupes du fer et des lanthanides, procede de preparation et application desdites compositions comme additifs pour combustibles ou carburants |
| DE3245882A1 (de) * | 1982-12-11 | 1984-06-14 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur verbesserung der verbrennung fluessiger brennstoffe |
| US4462810A (en) * | 1983-08-17 | 1984-07-31 | Exxon Research & Engineering Co. | Zirconium-cerium additives for residual fuel oil |
| US4522631A (en) * | 1983-11-18 | 1985-06-11 | Texaco Inc. | Diesel fuel containing rare earth metal and oxygenated compounds |
| US4670020A (en) * | 1984-12-24 | 1987-06-02 | Ford Motor Company | Carbon ignition temperature depressing agent and method of regenerating an automotive particulate trap utilizing said agent |
| FR2583761B1 (fr) * | 1985-06-20 | 1987-08-14 | Rhone Poulenc Spec Chim | Procede de preparation d'une dispersion colloidale d'un compose de cation metallique en milieu organique et les sols obtenus |
| JPH02182783A (ja) * | 1989-01-09 | 1990-07-17 | Nippon Mining Co Ltd | 高残炭燃料の燃焼方法 |
| WO2024003254A1 (en) * | 2022-06-30 | 2024-01-04 | Umicore Specialty Materials Brugge | Fuel borne catalyst composition for oxidative soot removal |
-
1976
- 1976-07-22 FR FR7622426A patent/FR2359192A1/fr active Granted
-
1977
- 1977-06-23 GB GB2643577A patent/GB1571210A/en not_active Expired
- 1977-06-29 DE DE19772729365 patent/DE2729365A1/de not_active Ceased
- 1977-06-30 IT IT2522577A patent/IT1202371B/it active
- 1977-07-06 NL NL7707497A patent/NL7707497A/xx not_active Application Discontinuation
- 1977-07-12 AU AU26951/77A patent/AU518590B2/en not_active Expired
- 1977-07-20 BE BE179482A patent/BE856974A/xx not_active IP Right Cessation
- 1977-07-20 JP JP8615377A patent/JPS5312907A/ja active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2160527A (en) * | 1984-05-25 | 1985-12-24 | Kao Corp | Metal salts of phoshate monoesters |
| US4836830A (en) * | 1986-09-19 | 1989-06-06 | Rhone-Poulenc Inc. | Rare earth compositions for diesel fuel stabilization |
| FR2911607A1 (fr) * | 2007-01-23 | 2008-07-25 | Rhodia Recherches & Tech | Procede de preparation d'une solution d'un organophosphate de terre rare. |
| WO2008090141A1 (fr) * | 2007-01-23 | 2008-07-31 | Rhodia Operations | Procede de preparation d'une solution d'un organophosphate de terre rare |
| US9669375B2 (en) | 2012-01-30 | 2017-06-06 | Cerion, Llc | Method for production of stable cerium oxide organic colloids |
| US10544376B2 (en) | 2012-01-30 | 2020-01-28 | Cerion, Llc | Rapid method for production of cerium-containing oxide organic colloids |
Also Published As
| Publication number | Publication date |
|---|---|
| AU518590B2 (en) | 1981-10-08 |
| FR2359192B1 (ja) | 1981-10-30 |
| BE856974A (fr) | 1977-11-14 |
| NL7707497A (nl) | 1978-01-24 |
| IT1202371B (it) | 1989-02-09 |
| DE2729365A1 (de) | 1978-03-09 |
| FR2359192A1 (fr) | 1978-02-17 |
| AU2695177A (en) | 1979-01-18 |
| JPS5312907A (en) | 1978-02-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19960623 |