GB1560132A - Process for the production of ferrocyanide blue - Google Patents
Process for the production of ferrocyanide blue Download PDFInfo
- Publication number
- GB1560132A GB1560132A GB3450777A GB3450777A GB1560132A GB 1560132 A GB1560132 A GB 1560132A GB 3450777 A GB3450777 A GB 3450777A GB 3450777 A GB3450777 A GB 3450777A GB 1560132 A GB1560132 A GB 1560132A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ferrocyanide
- temperature
- precipitation
- blue
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910001868 water Inorganic materials 0.000 claims description 18
- 238000001556 precipitation Methods 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000002244 precipitate Substances 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 229960002089 ferrous chloride Drugs 0.000 claims description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 6
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 6
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 6
- 235000012247 sodium ferrocyanide Nutrition 0.000 claims description 6
- GTSHREYGKSITGK-UHFFFAOYSA-N sodium ferrocyanide Chemical compound [Na+].[Na+].[Na+].[Na+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] GTSHREYGKSITGK-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 235000012251 calcium ferrocyanide Nutrition 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 4
- 239000012429 reaction media Substances 0.000 claims description 4
- 239000012266 salt solution Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 230000032683 aging Effects 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000000279 calcium ferrocyanide Substances 0.000 claims description 3
- 239000000264 sodium ferrocyanide Substances 0.000 claims description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- 159000000001 potassium salts Chemical class 0.000 description 3
- -1 ammonium ions Chemical class 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/26—Iron blues
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762638228 DE2638228A1 (de) | 1976-08-25 | 1976-08-25 | Verfahren zur herstellung von ferrocyanblau |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1560132A true GB1560132A (en) | 1980-01-30 |
Family
ID=5986327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3450777A Expired GB1560132A (en) | 1976-08-25 | 1977-08-17 | Process for the production of ferrocyanide blue |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5326800A (cs) |
| BE (1) | BE858075A (cs) |
| DE (1) | DE2638228A1 (cs) |
| ES (1) | ES460529A1 (cs) |
| FR (1) | FR2362903A2 (cs) |
| GB (1) | GB1560132A (cs) |
| NL (1) | NL183408C (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113479911A (zh) * | 2021-06-21 | 2021-10-08 | 华中科技大学 | 一种铁基普鲁士蓝、制备方法及其应用 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3038328A1 (de) * | 1980-10-10 | 1982-05-06 | Degussa Ag, 6000 Frankfurt | Eisenblau-pigment, verfahren zur herstellung desselben und verwendung |
| DE3038285A1 (de) * | 1980-10-10 | 1982-05-06 | Degussa Ag, 6000 Frankfurt | Eisenblau-pigment, verfahren zur herstellung desselben und verwendung |
| JPS60160354U (ja) * | 1984-03-30 | 1985-10-24 | 東陶機器株式会社 | 燃焼安全装置 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1258601A (fr) * | 1960-05-31 | 1961-04-14 | Montedison Spa | Procédé de préparation de bleu de prusse et pigments analogues à partir de l'acide cyanhydrique, du sulfate ferreux et de bases |
| DE2361354C3 (de) * | 1973-12-10 | 1978-08-03 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zur Herstellung von Berliner Blau (A) |
| DE2453014A1 (de) * | 1974-11-08 | 1976-05-13 | Degussa | Verfahren zur herstellung von ferrocyanblau |
| JPS5159099A (en) * | 1974-12-09 | 1976-05-22 | Degussa | Fueroshianburuuno seiho |
-
1976
- 1976-08-25 DE DE19762638228 patent/DE2638228A1/de active Granted
-
1977
- 1977-07-05 NL NL7707439A patent/NL183408C/xx active Search and Examination
- 1977-07-08 ES ES460529A patent/ES460529A1/es not_active Expired
- 1977-08-17 GB GB3450777A patent/GB1560132A/en not_active Expired
- 1977-08-19 FR FR7725442A patent/FR2362903A2/fr active Granted
- 1977-08-24 JP JP10149377A patent/JPS5326800A/ja active Granted
- 1977-08-24 BE BE6046121A patent/BE858075A/xx not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113479911A (zh) * | 2021-06-21 | 2021-10-08 | 华中科技大学 | 一种铁基普鲁士蓝、制备方法及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE858075A (fr) | 1978-02-24 |
| FR2362903A2 (fr) | 1978-03-24 |
| JPS5747128B2 (cs) | 1982-10-07 |
| NL183408C (nl) | 1988-10-17 |
| DE2638228A1 (de) | 1978-03-02 |
| NL183408B (nl) | 1988-05-16 |
| FR2362903B2 (cs) | 1980-06-06 |
| DE2638228C2 (cs) | 1989-01-12 |
| NL7707439A (nl) | 1978-02-28 |
| ES460529A1 (es) | 1978-05-16 |
| JPS5326800A (en) | 1978-03-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4046861A (en) | Process for the production of ferrocyanide blue | |
| US2388659A (en) | Manufacture of pigments | |
| CA1079489A (en) | Continuous production of iron oxide hydroxide | |
| NO138786B (no) | Anordning for vinkelmaaling. | |
| GB1560132A (en) | Process for the production of ferrocyanide blue | |
| EP0069961A1 (en) | Slaked lime, process for its production, and its use | |
| US6818052B1 (en) | Method for production of iron ioxide pigments | |
| DE69619958T2 (de) | Kobaltkatalysator | |
| CN108946693A (zh) | 机械活化连续反应制备高纯磷酸锌的方法 | |
| US3915733A (en) | Process for the production of Berlin blue | |
| JP5674083B2 (ja) | オキシ水酸化鉄ゾル及びその製造方法 | |
| Hirsch | The acid strength of glucuronic acid in comparison with that of oxycelluloses | |
| US2789033A (en) | Treatment of heavy metal ferrocyanides for the recovery of heavy metal sulfides | |
| Mills et al. | Corrosion of ruthenium dioxide hydrate by Ce IV ions and other oxidants | |
| CN108516573B (zh) | 一种高效制备微米级正六边形碳酸钙的方法 | |
| DE3907910A1 (de) | Verfahren zur herstellung von eisenoxidgelb-pigmenten | |
| CN103570571B (zh) | 一种dtpa五钠盐合成方法 | |
| US3499724A (en) | Method of brine treatment for removal of impurities | |
| JPS59102824A (ja) | 黒色酸化鉄粉の製造方法 | |
| JP3249589B2 (ja) | 高純度硫化亜鉛粉末の製造方法 | |
| Klein et al. | Precipitation of zinc sulphide from ammoniacal solutions by thioacetamide | |
| JPH0193414A (ja) | 微粒子紺青及びその製造方法 | |
| US5139767A (en) | Production method of goethite | |
| SU1175871A1 (ru) | Способ получени диоксида циркони | |
| DE2361354A1 (de) | Verfahren zur herstellung von berliner blau (a) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19941209 |