GB1496926A - Polyhydric alcohol production using ruthenium zeolite catalyst - Google Patents

Polyhydric alcohol production using ruthenium zeolite catalyst

Info

Publication number
GB1496926A
GB1496926A GB34429/75A GB3442975A GB1496926A GB 1496926 A GB1496926 A GB 1496926A GB 34429/75 A GB34429/75 A GB 34429/75A GB 3442975 A GB3442975 A GB 3442975A GB 1496926 A GB1496926 A GB 1496926A
Authority
GB
United Kingdom
Prior art keywords
polysaccharide
catalyst
metal
polyhydric alcohol
ruthenium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34429/75A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zeneca Inc
Original Assignee
ICI Americas Inc
ICI United States Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ICI Americas Inc, ICI United States Inc filed Critical ICI Americas Inc
Publication of GB1496926A publication Critical patent/GB1496926A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/26—Hexahydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00—Glucose; Glucose-containing syrups
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00—Glucose; Glucose-containing syrups
    • C13K1/06—Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
GB34429/75A 1974-08-20 1975-08-19 Polyhydric alcohol production using ruthenium zeolite catalyst Expired GB1496926A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US49896974A 1974-08-20 1974-08-20
US05/520,926 US3963788A (en) 1974-08-20 1974-11-05 Polyhydric alcohol production using ruthenium zeolite catalyst
BE163217A BE837201A (fr) 1974-08-20 1975-12-30 Procede de production de polyol
BE837201 1975-12-30

Publications (1)

Publication Number Publication Date
GB1496926A true GB1496926A (en) 1978-01-05

Family

ID=27424651

Family Applications (2)

Application Number Title Priority Date Filing Date
GB34429/75A Expired GB1496926A (en) 1974-08-20 1975-08-19 Polyhydric alcohol production using ruthenium zeolite catalyst
GB6452/77A Expired GB1496927A (en) 1974-08-20 1975-08-19 Regeneration of ruthenium catalyst

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB6452/77A Expired GB1496927A (en) 1974-08-20 1975-08-19 Regeneration of ruthenium catalyst

Country Status (10)

Country Link
US (1) US3963788A (enExample)
JP (1) JPS5143707A (enExample)
BE (1) BE837201A (enExample)
BR (1) BR7505206A (enExample)
CA (1) CA1054160A (enExample)
CH (1) CH614185A5 (enExample)
DE (1) DE2536416A1 (enExample)
FR (1) FR2282418A1 (enExample)
GB (2) GB1496926A (enExample)
NL (1) NL7509668A (enExample)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4177166A (en) * 1976-11-05 1979-12-04 Phillips Petroleum Company Hydroalkylation composition and process for producing said composition
US4118434A (en) * 1976-11-05 1978-10-03 Phillips Petroleum Company Hydroalkylation using multimetallic zeolite catalyst
US4173514A (en) * 1977-06-02 1979-11-06 Ici Americas Inc. High mannitol process (enzymatic isomerization)
DE2831659A1 (de) * 1978-07-19 1980-02-07 Bayer Ag Verfahren zur herstellung von polyalkoholen
JPS56141839A (en) * 1980-03-18 1981-11-05 Raffinerie Tirlemontoise Sa Regenerating method for catalyst for hydrogenating sugar by platinum group metal base
DE3144320A1 (de) * 1981-11-07 1983-05-19 Henkel KGaA, 4000 Düsseldorf "verfahren zur kontinuierlichen herstellung von mehrwertigen alkoholen"
US4430253A (en) 1982-02-11 1984-02-07 Ethyl Corporation Sulfide-modified ruthenium catalyst
US4380680A (en) * 1982-05-21 1983-04-19 Uop Inc. Method for hydrogenating aqueous solutions of carbohydrates
US4405499A (en) * 1982-08-23 1983-09-20 Shell Oil Company Zeolite-ruthenium-borane catalyst composition
US4466907A (en) * 1982-08-23 1984-08-21 Shell Oil Company Zeolite-ruthenium-borane catalyst composition
US4413152A (en) * 1982-08-25 1983-11-01 Uop Inc. Hydrogenation in aqueous solutions
US4459419A (en) * 1982-09-02 1984-07-10 Ethyl Corporation Hydrogenation process using cationic ruthenium-containing zeolite
US4510339A (en) * 1983-01-12 1985-04-09 Uop Inc. Increasing catalyst lifetime in hydrogenation of a carbohydrate in aqueous solution
US4503274A (en) * 1983-08-08 1985-03-05 Uop Inc. Ruthenium hydrogenation catalyst with increased activity
EP0137063B1 (en) * 1983-10-08 1987-07-22 Union Carbide Corporation Bulk separation of polyhydric alcohols by selective adsorption on zeolitic molecular sieves
EP0193566A1 (en) * 1984-09-12 1986-09-10 Commonwealth Scientific And Industrial Research Organisation Composite catalyst of ruthenium on zeolite and a group vi and/or group viii metal on refractory
ES2054877T3 (es) * 1988-02-22 1994-08-16 Fina Research Procedimiento catalitico de una etapa para la conversion directa de polisacaridos a alcoholes polihidricos.
US5026927A (en) * 1989-11-16 1991-06-25 The United States Of America As Represented By The United States Department Of Energy Hydrocracking of carbohydrates making glycerol, glycols and other polyols
DE4023255A1 (de) * 1990-07-21 1992-01-23 Basf Ag Verfahren zur herstellung von glykolen, insbesondere propylenglykol aus formaldehyd
FR2727980A1 (fr) * 1994-12-07 1996-06-14 Agrichimie Sa Procede de fabrication d'une solution pure de sucres simples par hydrolyse d'au moins un sucre compose en presence d'un adsorbant selectif
US5866101A (en) * 1997-07-22 1999-02-02 Colgate Palmolive Company Color stable anticalculus compostion
AU2326899A (en) * 1998-01-20 1999-08-02 Grain Processing Corporation Reduced malto-oligosaccharides
US6919446B1 (en) 1998-01-20 2005-07-19 Grain Processing Corp. Reduced malto-oligosaccharides
US6780990B1 (en) 1998-03-26 2004-08-24 Spi Polyols, Inc. Hydrogenated starch hydrolysate
US6380379B1 (en) 1999-08-20 2002-04-30 Grain Processing Corporation Derivatized reduced malto-oligosaccharides
BR0007202A (pt) 1999-10-20 2005-04-12 Grain Processing Corp Composições de limpeza de malto-oligosacarìdeos reduzidos
US6593469B1 (en) 1999-10-20 2003-07-15 Grain Processing Corporation Compositions including reduced malto-oligosaccharide preserving agents
DE10128205A1 (de) * 2001-06-11 2002-12-12 Basf Ag Ruthenium-Katalysatoren
DE10128203A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Herstellung von Sorbit
EP1572607A1 (de) * 2002-12-11 2005-09-14 Basf Aktiengesellschaft Kontinuierliches verfahren zur herstellung von zuckeralkoholen
WO2005021475A1 (en) * 2003-09-03 2005-03-10 Sk Corporation Method for preparing sugar alcohols by catalytic hydrogenation of sugars
US20050096212A1 (en) * 2003-10-31 2005-05-05 Hiroshi Takeda Catalyst for the conversion of carbon monoxide
US20050096211A1 (en) * 2003-10-31 2005-05-05 Hiroshi Takeda Catalyst for the conversion of carbon monoxide
JP4423432B2 (ja) 2006-03-01 2010-03-03 国立大学法人北海道大学 セルロースの加水分解および／または加水分解物の還元用触媒およびセルロースから糖アルコールの製造方法
GB2437517A (en) 2006-04-27 2007-10-31 Danisco Sweeteners Oy Catalytic hydrogenation of sugar to sugar alcohol, using increasing reaction temperature and/or addition of monocarboxylic acid to maintain catalyst activity
CN101121643B (zh) * 2007-08-09 2010-05-19 厦门大学 六元醇的制备方法
DE102008015406A1 (de) * 2008-03-22 2009-09-24 Bayer Materialscience Ag Verfahren zur Regeneration eines mit Schwefel in Form von Schwefelverbindungen vergifteten, Ruthenium oder Rutheniumverbindungen enthaltenden Katalysators
WO2010144558A2 (en) * 2009-06-09 2010-12-16 University Of Kansas Nano-metal catalysts for polyol hydrogenolysis
CN107048328B (zh) * 2009-12-23 2021-07-09 赢创运营有限公司 甜味剂及其制备方法
KR101332303B1 (ko) * 2011-04-19 2013-11-22 한국화학연구원 당류의 촉매 수소화에 의한 당알코올류의 제조방법
KR101359446B1 (ko) * 2011-04-19 2014-02-11 한국화학연구원 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매 및 이의 제조방법
WO2012141523A2 (ko) * 2011-04-14 2012-10-18 한국화학연구원 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매, 이의 제조방법 및 이를 이용한 당알코올류의 제조방법
CA2937511C (en) 2014-01-21 2022-07-05 Council Of Scientific & Industrial Research An improved process for the preparation of 2,5-dimethylfuran and furfuryl alcohol over ruthenium supported catalysts
IL281378B2 (en) 2018-09-11 2025-02-01 S?Dzucker Ag Improved production method for isomalt

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2868847A (en) * 1956-10-05 1959-01-13 Engelhard Ind Inc Hydrogenation of mono-and disaccharides to polyols
US3055840A (en) * 1958-01-13 1962-09-25 Engelhard Ind Inc Ruthenium-containing catalysts and methods of making said catalysts and increasing their activity

Also Published As

Publication number Publication date
FR2282418A1 (fr) 1976-03-19
GB1496927A (en) 1978-01-05
US3963788A (en) 1976-06-15
FR2282418B1 (enExample) 1980-04-25
JPS5143707A (enExample) 1976-04-14
BE837201A (fr) 1976-06-30
CA1054160A (en) 1979-05-08
NL7509668A (nl) 1976-02-24
AU8366975A (en) 1977-02-10
CH614185A5 (enExample) 1979-11-15
DE2536416A1 (de) 1976-03-04
BR7505206A (pt) 1976-08-03

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee