GB1449894A - Method for treatment of heavy oils - Google Patents

Method for treatment of heavy oils

Info

Publication number
GB1449894A
GB1449894A GB5545173A GB5545173A GB1449894A GB 1449894 A GB1449894 A GB 1449894A GB 5545173 A GB5545173 A GB 5545173A GB 5545173 A GB5545173 A GB 5545173A GB 1449894 A GB1449894 A GB 1449894A
Authority
GB
United Kingdom
Prior art keywords
metal compound
furnace
alkali metal
gasification
coking furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5545173A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Engineering and Shipbuilding Co Ltd
Original Assignee
Mitsui Engineering and Shipbuilding Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Engineering and Shipbuilding Co Ltd filed Critical Mitsui Engineering and Shipbuilding Co Ltd
Publication of GB1449894A publication Critical patent/GB1449894A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
    • C10B55/02—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials
    • C10B55/04—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials
    • C10B55/08—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials in dispersed form
    • C10B55/10—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Coke Industry (AREA)

Abstract

1449894 Gasification of heavy oils MITSUI SHIPBUILDING & ENG CO Ltd 29 Nov 1973 [30 Nov 1972] 55451/73 Heading C5E Heavy oils are coked in a fluidized bed coking furnace and the coked product gasified in a fluidized bed gasification furnace by heating a particulate alkali metal compound to a temperature at least 100‹ C. higher than the temperature in the coking furnace, and adding the heated alkali metal compound to the coking furnace independently of the heavy oil thereby forming a coke, and treating the coke particles with steam and oxygen or air in a fluidized bed gasification furnace to cause a gasification reaction to occur. The alkali metal compound, e.g. the carbonate or hydroxide of sodium, lithium or potassium or an admixture thereof, in powder or granular form, or supported on an inorganic refractory or an alkaline earth metal compound, e.g. alumina, murite, zirconia, or chamotte, or calcium or magnesium oxide or carbonate, or dolomite, may be heated to a temperature of not more than 500‹ C. higher than that of the coking furnace. The alkali metal compound may be recovered from the gasification furnace and recycled to the coking furnace.
GB5545173A 1972-11-30 1973-11-29 Method for treatment of heavy oils Expired GB1449894A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP47119367A JPS5139644B2 (en) 1972-11-30 1972-11-30

Publications (1)

Publication Number Publication Date
GB1449894A true GB1449894A (en) 1976-09-15

Family

ID=14759730

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5545173A Expired GB1449894A (en) 1972-11-30 1973-11-29 Method for treatment of heavy oils

Country Status (3)

Country Link
US (1) US3915844A (en)
JP (1) JPS5139644B2 (en)
GB (1) GB1449894A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2560317A (en) * 2017-03-06 2018-09-12 Sibelco Nederland N V Bed materials for fluidised bed reaction methods and fluidised bed reaction methods

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003823A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Combined desulfurization and hydroconversion with alkali metal hydroxides
US4046670A (en) * 1975-04-30 1977-09-06 Kureha Kagaku Kogyo Kabushiki Kaisha Method for the treatment of heavy petroleum oil
US4220518A (en) * 1977-09-28 1980-09-02 Hitachi, Ltd. Method for preventing coking in fluidized bed reactor for cracking heavy hydrocarbon oil
CA1156952A (en) * 1979-06-08 1983-11-15 Zacharia M. George Formation of coke from heavy crude oils in the presence of calcium carbonate
US4305809A (en) * 1980-03-06 1981-12-15 Mobil Oil Corporation Fixed sulfur petroleum coke fuel and method for its production
US4479804A (en) * 1980-03-06 1984-10-30 Mobil Oil Corporation Fixed sulfur petroleum coke fuel and method for its production
JPS59106638U (en) * 1982-12-30 1984-07-18 橋本フオ−ミング工業株式会社 Composite processing equipment for forming materials such as satsushi
JPH0248090Y2 (en) * 1985-09-25 1990-12-18
JPH0385115U (en) * 1989-12-18 1991-08-28
JPH0412314U (en) * 1990-04-18 1992-01-31
US5284574A (en) * 1990-10-01 1994-02-08 Exxon Research And Engineering Company Improved integrated coking-gasification process with mitigation of slagging
US5466361A (en) * 1992-06-12 1995-11-14 Mobil Oil Corporation Process for the disposal of aqueous sulfur and caustic-containing wastes
IT1275410B (en) * 1995-06-01 1997-08-05 Eniricerche Spa PROCEDURE FOR THE COMPLETE CONVERSION OF HIGH MOLECULAR WEIGHT HYDROCARBON MATERIALS
EP2275513A3 (en) * 2000-09-18 2011-04-13 Ensyn Petroleum International Ltd. Products produced from rapid thermal processing of heavy hydrocarbon feedstocks
JP4395570B2 (en) * 2002-07-30 2010-01-13 独立行政法人産業技術総合研究所 Method for producing hydrogen by thermochemical decomposition of water
US7572365B2 (en) * 2002-10-11 2009-08-11 Ivanhoe Energy, Inc. Modified thermal processing of heavy hydrocarbon feedstocks
US7572362B2 (en) * 2002-10-11 2009-08-11 Ivanhoe Energy, Inc. Modified thermal processing of heavy hydrocarbon feedstocks
US8715616B2 (en) * 2011-02-11 2014-05-06 Phillips 66 Company Soak and coke
US9707532B1 (en) 2013-03-04 2017-07-18 Ivanhoe Htl Petroleum Ltd. HTL reactor geometry
CN103933995A (en) * 2014-04-12 2014-07-23 深圳市绿野清风环保工程有限公司 Rubbish gasification catalyst and preparation method thereof
MX2016013839A (en) * 2014-06-20 2017-03-09 Exxonmobil Res & Eng Co Fluidized bed coking with fuel gas production.
US20190352571A1 (en) * 2018-05-16 2019-11-21 Exxonmobil Research And Engineering Company Fluidized coking with catalytic gasification

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2320118A (en) * 1940-04-22 1943-05-25 Phillips Petroleum Co Hydrocarbon conversion and catalyst therefor
US2527575A (en) * 1945-12-04 1950-10-31 Standard Oil Dev Co Method for handling fuels
US2921017A (en) * 1957-02-13 1960-01-12 Socony Mobil Oil Co Inc Process of producing desulfurized coke from petroleum
US3009781A (en) * 1957-02-23 1961-11-21 Shawinigan Chem Ltd Process for preparation of carbon disulphide and for the desulphurization of coke
US3179584A (en) * 1962-02-23 1965-04-20 Exxon Research Engineering Co Oil coking with increased hydrogen production
GB1280375A (en) * 1970-01-27 1972-07-05 Exxon Research Engineering Co Conversion of heavy hydrocarbon feedstocks
US3803023A (en) * 1970-06-09 1974-04-09 Exxon Research Engineering Co Steam gasification of coke
US3723291A (en) * 1971-04-16 1973-03-27 Continental Oil Co Process for desulfurizing coke

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2560317A (en) * 2017-03-06 2018-09-12 Sibelco Nederland N V Bed materials for fluidised bed reaction methods and fluidised bed reaction methods

Also Published As

Publication number Publication date
US3915844A (en) 1975-10-28
DE2359571A1 (en) 1974-06-06
JPS5139644B2 (en) 1976-10-29
DE2359571B2 (en) 1976-12-02
JPS4980102A (en) 1974-08-02

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee