GB1068809A - Production of hydrogen - Google Patents

Production of hydrogen

Info

Publication number
GB1068809A
GB1068809A GB30510/64A GB3051064A GB1068809A GB 1068809 A GB1068809 A GB 1068809A GB 30510/64 A GB30510/64 A GB 30510/64A GB 3051064 A GB3051064 A GB 3051064A GB 1068809 A GB1068809 A GB 1068809A
Authority
GB
United Kingdom
Prior art keywords
carbon monoxide
silicates
carbonates
catalysts
mentioned
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30510/64A
Inventor
Karl-Geert Malle
Guenther Zirker
Gerhard Schulze
Franz Ludwig Ebenhoech
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1068809A publication Critical patent/GB1068809A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

Catalysts for use in the production of hydrogen by reaction of carbon monoxide or gases containing carbon monoxide with steam are obtained by precipitation of copper oxides, hydroxides, and/or carbonates from solutions of copper salts by means of alkali metal hydroxides or carbonates on to natural or synthetic silicates having an average particle size of less than 100 m , in aqueous suspension at 10 DEG to 90 DEG C., followed by filtration, drying and subsequent reduction at 150 DEG to 250 DEG C. Gases containing carbon monoxide mentioned are cracking gas, coke oven gas, gas from pressure gasification of mineral coal, producer gas. Natural silicates mentioned are clay, kaolin, bleaching earths, bentonite, bolus alba, asbestos, meerschaum; synthetic silicates mentioned are magnesium, calcium, zinc, aluminium silicates. The catalyst may be shaped, e.g. pelleted and may be reduced with gases containing 1 to 20% carbon monoxide and/or hydrogen, which may be the gases to be converted. Chromium, molybdenum, tungsten, vanadium, silver, barium, zinc compounds may be added to the catalyst during the production of the catalysts or subsequently. The reaction may be carried out at atmospheric or superatmospheric presure, e.g. up to 40 atmospheres, and at 110 DEG to 200 DEG C.ALSO:Shift reaction catalysts are obtained by precipitation of copper oxides, hydroxides, and/or carbonates from solutions of copper salts by means of alkali metal hydroxides or carbonates on to natural or synthetic silicates having an average particle size of less than 100m , in aqueous suspension at 10 to 90 DEG C., followed by filtration, drying and subsequent reduction at 150 to 250 DEG C. Natural silicates mentioned are clay, kaolin, bleaching earths, bentonite, bolus alba, asbestos, meerschaum; synthetic silicates mentioned are magnesium, calcium, zinc, aluminium silicates. The catalyst may be shaped e.g. pelleted and may be reduced with gases containing 1 to 20% carbon monoxide and/or hydrogen, which may be the gases to be converted. Chromium, molybdenum, tungsten, vanadium, silver, barium, zinc compounds may be added to the catalyst during the production of the catalysts or subsequently.
GB30510/64A 1963-07-30 1964-08-04 Production of hydrogen Expired GB1068809A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB0072918 1963-07-30

Publications (1)

Publication Number Publication Date
GB1068809A true GB1068809A (en) 1967-05-17

Family

ID=6977639

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30510/64A Expired GB1068809A (en) 1963-07-30 1964-08-04 Production of hydrogen

Country Status (8)

Country Link
AT (1) AT249003B (en)
BE (1) BE651047A (en)
CH (1) CH438234A (en)
DE (1) DE1442981A1 (en)
FI (1) FI41541B (en)
FR (1) FR1402614A (en)
GB (1) GB1068809A (en)
NL (1) NL6408438A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2139520A (en) * 1983-05-12 1984-11-14 British Gas Corp Clay-containing catalysts for methanation, methanol synthesis and steam-cracking
EP0147569A1 (en) * 1983-11-04 1985-07-10 Veg-Gasinstituut N.V. Process for the production of hydrogen

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1148864B (en) * 1980-05-16 1986-12-03 Snam Progetti PROCESS FOR THE PRODUCTION OF A MIXTURE OF METHANOL AND HIGHER ALCOHOLS FUEL DEGREE
IT1140947B (en) * 1980-05-16 1986-10-10 Snam Progetti PROCESS FOR THE PRODUCTION OF A MIXTURE OF METHANOL AND HIGHER ALCOHOL "FUEL DEGREE"
CN114314793A (en) * 2022-01-06 2022-04-12 青岛诺康新氢源研究院有限公司 Hydrogen production particle capable of generating porous structure on site and preparation method and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2139520A (en) * 1983-05-12 1984-11-14 British Gas Corp Clay-containing catalysts for methanation, methanol synthesis and steam-cracking
US4546091A (en) * 1983-05-12 1985-10-08 British Gas Corporation Catalysts
EP0147569A1 (en) * 1983-11-04 1985-07-10 Veg-Gasinstituut N.V. Process for the production of hydrogen
US4711773A (en) * 1983-11-04 1987-12-08 Veg-Gasinstituut N.V. Process for the production of hydrogen

Also Published As

Publication number Publication date
CH438234A (en) 1967-06-30
BE651047A (en) 1965-01-27
FI41541B (en) 1969-09-01
DE1442981A1 (en) 1969-01-02
FR1402614A (en) 1965-06-11
AT249003B (en) 1966-08-25
NL6408438A (en) 1965-02-01

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