GB1439638A - Photographic silver halide emulsions - Google Patents

Photographic silver halide emulsions

Info

Publication number
GB1439638A
GB1439638A GB4604773A GB4604773A GB1439638A GB 1439638 A GB1439638 A GB 1439638A GB 4604773 A GB4604773 A GB 4604773A GB 4604773 A GB4604773 A GB 4604773A GB 1439638 A GB1439638 A GB 1439638A
Authority
GB
United Kingdom
Prior art keywords
silver halide
dye
halide emulsion
photographic silver
azaindene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4604773A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1439638A publication Critical patent/GB1439638A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/28Sensitivity-increasing substances together with supersensitising substances
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/10Organic substances
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/34Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression

Landscapes

  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

Abstract

1439638 Infrared sensitized photographic silver halide emulsion EASTMAN KODAK CO 2 Oct 1973 [2 Oct 1972] 46047/73 Heading G2C A photographic silver halide emulsion having a pAg of 6À0 to 8À5 contains at least an infrared spectral sensitizing dye which has a cathodic polarographic halfwave potential more positive than -1À20 volts, the dye being present in an amount which results in at least 0À3 log E desensitization of a portion of the same emulsion (when coated on a support, sensitometrically exposed to light to which the silver halide emulsion is intrinsically sensitive and developed for 6 minutes at 20‹C in Kodak (R.T.M.) D-19 developer) and a silver complexing azaindene in an amount which will reduce the desensitization caused by the dye. These dyes may be used at 50 to 1000mg per mole of silver halide. The dye may have one of the Formulae: where R<SP>1</SP>, R<SP>2</SP>, R<SP>3</SP> and R<SP>4</SP> are each alkyl, substituted alkyl or aryl or R<SP>3</SP> and R<SP>4</SP> together with the N atom to which they are attached form a 5- or 6-membered heterocyclic ring, Z<SP>1</SP> and Z<SP>2</SP> each complete a heterocyclic nucleus containing 5 or 6 atoms in the ring containing the N atom shown; Q is an ethylene group which may be substituted; each L is optionally substituted methine; n and p are each 0 or 1; m is 1-5, q is 1 or 2, and X# is an anion e.g. 3, 3' -diethylselenadicarbocyanine iodide. The azaindene may be a triazaindene, tetraazaindene or pentaazaindene. Sensitizing dye combinations are used in Examples 1, 3 and 4. Bis-(vinylsulphonyl-methyl) ether is used as a hardener in Example 1. The emulsions have higher speeds in the spectrally sensitized region and are sensitive to longer wavelengths than similar emulsions having lower dye concentrations.
GB4604773A 1972-10-02 1973-10-02 Photographic silver halide emulsions Expired GB1439638A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US29396372A 1972-10-02 1972-10-02

Publications (1)

Publication Number Publication Date
GB1439638A true GB1439638A (en) 1976-06-16

Family

ID=23131303

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4604773A Expired GB1439638A (en) 1972-10-02 1973-10-02 Photographic silver halide emulsions

Country Status (5)

Country Link
JP (1) JPS4974018A (en)
BE (1) BE805583A (en)
DE (1) DE2349504A1 (en)
FR (1) FR2201485B1 (en)
GB (1) GB1439638A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1016909A1 (en) * 1998-12-29 2000-07-05 Konica Corporation Silver halide emulsion and photographic material by use thereof

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1194827B (en) * 1979-10-12 1988-09-28 Minnesota Mining & Mfg PHOTOGRAPHIC EMULSIONS FOR SILVER HALIDES INCLUDING SENSITIZING DYES AND SUPER SENSITIZING OR STABILIZING QUANTITIES OF A POLYMERIC COMPOUND AND PHOTOGRAPHIC ELEMENTS IN PARTICULAR X-RAY ELEMENTS THAT INCLUDE EMULSIONS
JPS62148942A (en) * 1985-12-23 1987-07-02 Konishiroku Photo Ind Co Ltd Silver halide photographic sensitive material
JPH06105340B2 (en) * 1986-09-29 1994-12-21 富士写真フイルム株式会社 Silver halide photographic light-sensitive material
JPH01102534A (en) * 1987-10-16 1989-04-20 Fuji Photo Film Co Ltd Image forming method
DE3901268A1 (en) * 1989-01-18 1990-07-19 Du Pont Deutschland PHOTOGRAPHIC SILVER HALOGEN EMULSION
JP2967879B2 (en) * 1989-06-07 1999-10-25 富士写真フイルム株式会社 Silver halide photographic material
JP2632052B2 (en) * 1989-10-06 1997-07-16 富士写真フイルム株式会社 Silver halide photographic material
JP2782138B2 (en) * 1992-03-18 1998-07-30 富士写真フイルム株式会社 Silver halide photographic material

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3563754A (en) * 1966-11-23 1971-02-16 Eastman Kodak Co Photographic process
BE756536A (en) * 1969-09-23 1971-03-01 Eastman Kodak Co NEW CYANINE DYE AND ITS APPLICATIONS IN PHOTOGRAPHY
BE756535A (en) * 1969-09-23 1971-03-01 Eastman Kodak Co OVERSENSITIZED SILVER HALIDE PHOTOGRAPHIC EMULSION
US3706569A (en) * 1970-12-04 1972-12-19 Eastman Kodak Co Silver halide emulsion containing silver ethynylcyclopentanol complex to reduce desensitization of optical sensitizing dye incorporated therein

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1016909A1 (en) * 1998-12-29 2000-07-05 Konica Corporation Silver halide emulsion and photographic material by use thereof

Also Published As

Publication number Publication date
DE2349504A1 (en) 1974-04-11
BE805583A (en) 1974-04-02
FR2201485B1 (en) 1977-05-27
JPS4974018A (en) 1974-07-17
FR2201485A1 (en) 1974-04-26

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee