GB1436475A - Process for catalytic ammoxidation of olefins to nitriles - Google Patents
Process for catalytic ammoxidation of olefins to nitrilesInfo
- Publication number
- GB1436475A GB1436475A GB4304174A GB4304174A GB1436475A GB 1436475 A GB1436475 A GB 1436475A GB 4304174 A GB4304174 A GB 4304174A GB 4304174 A GB4304174 A GB 4304174A GB 1436475 A GB1436475 A GB 1436475A
- Authority
- GB
- United Kingdom
- Prior art keywords
- propylene
- isobutylene
- metal
- methacrylonitrile
- moles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 150000002825 nitriles Chemical class 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 7
- 239000002184 metal Substances 0.000 abstract 7
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 4
- 229910052791 calcium Inorganic materials 0.000 abstract 4
- 239000011575 calcium Substances 0.000 abstract 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- 150000002739 metals Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 229910052721 tungsten Inorganic materials 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052738 indium Inorganic materials 0.000 abstract 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP48115351A JPS5245692B2 (ko) | 1973-10-16 | 1973-10-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1436475A true GB1436475A (en) | 1976-05-19 |
Family
ID=14660361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4304174A Expired GB1436475A (en) | 1973-10-16 | 1974-10-04 | Process for catalytic ammoxidation of olefins to nitriles |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5245692B2 (ko) |
| BE (1) | BE821098A (ko) |
| DE (1) | DE2447952A1 (ko) |
| FR (1) | FR2247454B1 (ko) |
| GB (1) | GB1436475A (ko) |
| NL (1) | NL7413543A (ko) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2436135A1 (fr) * | 1978-09-13 | 1980-04-11 | Ube Industries | Procede pour la preparation catalytique de l'acrylonitrile |
| EP1321188A1 (en) | 1997-09-02 | 2003-06-25 | The Standard Oil Company | Catalytic process for the manufacture of acrylonitrile and hydrogen cyanide |
| WO2011119208A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | Improved mixed metal oxide ammoxidation catalysts |
| WO2011119207A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
| WO2011119203A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
| WO2011119206A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
| WO2013043371A1 (en) | 2011-09-21 | 2013-03-28 | Ineos Usa Llc | Mixed metal oxide catalysts |
| US8420566B2 (en) | 2010-03-23 | 2013-04-16 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
| WO2015183283A1 (en) | 2014-05-29 | 2015-12-03 | Ineos Usa, Llc | Improved selective ammoxidation catalysts |
| WO2015183284A1 (en) | 2014-05-29 | 2015-12-03 | Ineos Usa, Llc | Improved selective ammoxidation catalysts |
| WO2016100023A1 (en) | 2014-12-17 | 2016-06-23 | Ineos Europe Ag | Improved mixed metal oxide ammoxidation catalysts |
| WO2018071166A1 (en) | 2016-10-11 | 2018-04-19 | Ineos Europe Ag | Ammoxidation catalyst with selective co-product hcn production |
| RU2709012C1 (ru) * | 2016-08-31 | 2019-12-13 | Асахи Касеи Кабусики Кайся | Способ получения катализатора и способ получения акрилонитрила |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1523772A (en) * | 1974-07-22 | 1978-09-06 | Standard Oil Co | Oxidation catalysts |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2249922C2 (de) * | 1972-10-12 | 1982-05-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur katalytischen Oxidation von Propylen oder Isobutylen zu Acrolein oder Methacrolein in der Gasphase mit molekularem Sauerstoff |
| DE2424934A1 (de) * | 1973-06-04 | 1975-01-02 | Standard Oil Co Ohio | Verfahren zur katalytischen herstellung ungesaettigter nitrile |
-
1973
- 1973-10-16 JP JP48115351A patent/JPS5245692B2/ja not_active Expired
-
1974
- 1974-10-04 GB GB4304174A patent/GB1436475A/en not_active Expired
- 1974-10-08 DE DE19742447952 patent/DE2447952A1/de active Pending
- 1974-10-15 NL NL7413543A patent/NL7413543A/xx not_active Application Discontinuation
- 1974-10-15 BE BE149557A patent/BE821098A/xx unknown
- 1974-10-16 FR FR7434840A patent/FR2247454B1/fr not_active Expired
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2436135A1 (fr) * | 1978-09-13 | 1980-04-11 | Ube Industries | Procede pour la preparation catalytique de l'acrylonitrile |
| EP1321188A1 (en) | 1997-09-02 | 2003-06-25 | The Standard Oil Company | Catalytic process for the manufacture of acrylonitrile and hydrogen cyanide |
| BG64461B1 (bg) * | 1997-09-02 | 2005-03-31 | The Standard Oil Co. | Катализатор за получаване на акрилонитрил и циановодород |
| US8350075B2 (en) | 2010-03-23 | 2013-01-08 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
| US8420566B2 (en) | 2010-03-23 | 2013-04-16 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
| WO2011119203A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
| WO2011119206A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
| US8258073B2 (en) | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
| WO2011119208A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | Improved mixed metal oxide ammoxidation catalysts |
| US8455388B2 (en) | 2010-03-23 | 2013-06-04 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
| WO2011119207A1 (en) | 2010-03-23 | 2011-09-29 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
| WO2013043371A1 (en) | 2011-09-21 | 2013-03-28 | Ineos Usa Llc | Mixed metal oxide catalysts |
| US9433929B2 (en) | 2011-09-21 | 2016-09-06 | Ineos Europe Ag | Mixed metal oxide catalysts |
| WO2015183283A1 (en) | 2014-05-29 | 2015-12-03 | Ineos Usa, Llc | Improved selective ammoxidation catalysts |
| WO2015183284A1 (en) | 2014-05-29 | 2015-12-03 | Ineos Usa, Llc | Improved selective ammoxidation catalysts |
| US9211527B1 (en) | 2014-05-29 | 2015-12-15 | Ineos Europe Ag | Selective ammoxidation catalysts |
| WO2016100023A1 (en) | 2014-12-17 | 2016-06-23 | Ineos Europe Ag | Improved mixed metal oxide ammoxidation catalysts |
| RU2709012C1 (ru) * | 2016-08-31 | 2019-12-13 | Асахи Касеи Кабусики Кайся | Способ получения катализатора и способ получения акрилонитрила |
| WO2018071166A1 (en) | 2016-10-11 | 2018-04-19 | Ineos Europe Ag | Ammoxidation catalyst with selective co-product hcn production |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5064218A (ko) | 1975-05-31 |
| NL7413543A (nl) | 1975-04-18 |
| FR2247454A1 (ko) | 1975-05-09 |
| BE821098A (fr) | 1975-04-15 |
| FR2247454B1 (ko) | 1976-10-22 |
| DE2447952A1 (de) | 1975-04-17 |
| JPS5245692B2 (ko) | 1977-11-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |