GB1411137A - Process for the preparation of perfluoroalkyl iodides - Google Patents

Process for the preparation of perfluoroalkyl iodides

Info

Publication number
GB1411137A
GB1411137A GB5746672A GB5746672A GB1411137A GB 1411137 A GB1411137 A GB 1411137A GB 5746672 A GB5746672 A GB 5746672A GB 5746672 A GB5746672 A GB 5746672A GB 1411137 A GB1411137 A GB 1411137A
Authority
GB
United Kingdom
Prior art keywords
perfluoroalkyl iodides
integer
preparation
telogen
dec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5746672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of GB1411137A publication Critical patent/GB1411137A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/26Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/278Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of only halogenated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1411137 Perfluoroalkyl iodides HOECHST AG 13 Dec 1972 [24 Dec 1971] 57466/72 Heading C2C Perfluoroalkyl iodides of the general formula C 2 F 5 (CF 2 -F 2 ) n I in which n is an integer of 1 to 10 are obtained by reacting CF 2 = CF 2 with C 2 F 5 (CF 2 -CF 2 ) x I in which x is 0 or an integer of 1 to 9 in the presence of a catalyst of general formula (C m F 2m+1 COO) 2 in which m is an integer from 2 to 10. The reaction is preferably performed at 25-65‹ C. at a pressure of normal to 8 atmosphere gauge using 0.02-0.7% by weight of catalyst based on the weight of telogen dissolved in telogen for ease of addition to the reaction mixture.
GB5746672A 1971-12-24 1972-12-13 Process for the preparation of perfluoroalkyl iodides Expired GB1411137A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19712164567 DE2164567B2 (en) 1971-12-24 1971-12-24 Process for the preparation of perfluoroalkyl iodides

Publications (1)

Publication Number Publication Date
GB1411137A true GB1411137A (en) 1975-10-22

Family

ID=5829215

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5746672A Expired GB1411137A (en) 1971-12-24 1972-12-13 Process for the preparation of perfluoroalkyl iodides

Country Status (10)

Country Link
JP (1) JPS4868508A (en)
AT (1) AT321872B (en)
BE (1) BE793356A (en)
CA (1) CA989872A (en)
CH (1) CH574887A5 (en)
DE (1) DE2164567B2 (en)
FR (1) FR2164933B1 (en)
GB (1) GB1411137A (en)
IT (1) IT972869B (en)
NL (1) NL7217278A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7888538B1 (en) 2009-11-04 2011-02-15 E.I. Du Pont De Nemours And Company Catalyzed olefin insertion
US7951983B2 (en) 2009-11-04 2011-05-31 E.I. Du Pont De Nemours And Company Catalyzed olefin insertion
EP2578560B1 (en) 2010-06-04 2016-09-14 Asahi Glass Company, Limited Process for production of fluoroalkyl iodide

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2542496C3 (en) * 1975-09-24 1980-07-31 Hoechst Ag, 6000 Frankfurt Process for the preparation of perfluoroalkyl iodide telomers
DE4025154A1 (en) * 1990-08-08 1992-02-13 Max Planck Gesellschaft PHOTOCHEMICAL PREPARATION OF HALOGEN COMPOUNDS
WO2009035110A1 (en) * 2007-09-13 2009-03-19 Asahi Glass Company, Limited Process for producing fluoroalkyl iodide
JP5088254B2 (en) * 2008-07-09 2012-12-05 旭硝子株式会社 Method for producing fluoroalkyl halide
JP5088253B2 (en) * 2008-07-09 2012-12-05 旭硝子株式会社 Method for producing fluoroalkyl halide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559630A (en) * 1950-03-04 1951-07-10 Du Pont Fluorinated acyl peroxides
US3226449A (en) * 1962-06-06 1965-12-28 Du Pont Process for preparing perfluoroalkyl iodides

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7888538B1 (en) 2009-11-04 2011-02-15 E.I. Du Pont De Nemours And Company Catalyzed olefin insertion
US7951983B2 (en) 2009-11-04 2011-05-31 E.I. Du Pont De Nemours And Company Catalyzed olefin insertion
EP2578560B1 (en) 2010-06-04 2016-09-14 Asahi Glass Company, Limited Process for production of fluoroalkyl iodide

Also Published As

Publication number Publication date
CH574887A5 (en) 1976-04-30
FR2164933B1 (en) 1976-06-04
DE2164567B2 (en) 1974-03-21
AT321872B (en) 1975-04-25
CA989872A (en) 1976-05-25
IT972869B (en) 1974-05-31
FR2164933A1 (en) 1973-08-03
BE793356A (en) 1973-06-27
JPS4868508A (en) 1973-09-18
NL7217278A (en) 1973-06-26
DE2164567A1 (en) 1973-07-05

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee