ES329470A1 - A procedure for preparing linear alfaolephins. (Machine-translation by Google Translate, not legally binding) - Google Patents

A procedure for preparing linear alfaolephins. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES329470A1
ES329470A1 ES0329470A ES329470A ES329470A1 ES 329470 A1 ES329470 A1 ES 329470A1 ES 0329470 A ES0329470 A ES 0329470A ES 329470 A ES329470 A ES 329470A ES 329470 A1 ES329470 A1 ES 329470A1
Authority
ES
Spain
Prior art keywords
group
compound
translation
machine
legally binding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0329470A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Esso Research and Engineering Co filed Critical Esso Research and Engineering Co
Publication of ES329470A1 publication Critical patent/ES329470A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/135—Compounds comprising a halogen and titanum, zirconium, hafnium, germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for preparing linear alpha-olefins having an average molecular weight of about 70 to 300, by polymerization of a gas containing ethylene in the presence of a catalyst comprising the reaction product of a transition metal halide selected from the group consists of TiX4, TiX3OR ', TiX3OOCR', where X is selected from the group consisting of chlorine and bromine and R 'is selected from the group consisting of alkyl, aryl, aralkyl, and cycloalkyl; and an aluminum alkyl compound such that the final formula of the aluminum alkyl compound is AlRnX3, where R is selected from the group consisting of alkyl, aralkyl, and cycloalkyl, X is selected from the group consisting of chlorine, bromine, and iodine, and is less than 2, in the presence of a polar diluent at a tempera ture of less than 75º C and a pressure above 3.5 kg/cm2 absolute, characterized by the addition, to the reaction mixture of a caustic compound and if Desires a catalyst-destroying compound selected from the group consisting of water, acids and alcohols. (Machine-translation by Google Translate, not legally binding)
ES0329470A 1966-07-01 1966-07-23 A procedure for preparing linear alfaolephins. (Machine-translation by Google Translate, not legally binding) Expired ES329470A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US56208966A 1966-07-01 1966-07-01

Publications (1)

Publication Number Publication Date
ES329470A1 true ES329470A1 (en) 1967-05-16

Family

ID=24244750

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0329470A Expired ES329470A1 (en) 1966-07-01 1966-07-23 A procedure for preparing linear alfaolephins. (Machine-translation by Google Translate, not legally binding)

Country Status (4)

Country Link
BE (1) BE684587A (en)
DE (1) DE1568461A1 (en)
ES (1) ES329470A1 (en)
NL (1) NL6610457A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1754694A1 (en) * 2005-08-10 2007-02-21 Linde AG Method for deactivation and removal of catalytic components in the oligomerisation of ethylene
EP1752433B1 (en) * 2005-08-10 2012-10-03 Linde AG Improved drying process for linear alpha-olefins
KR101679515B1 (en) 2015-02-12 2016-11-24 주식회사 엘지화학 Method of preparing catalyst system for oligomerization and catalyst sysyem for oligomerization prepared thereby

Also Published As

Publication number Publication date
BE684587A (en) 1967-01-25
NL6610457A (en) 1968-01-02
DE1568461A1 (en) 1970-03-19

Similar Documents

Publication Publication Date Title
ATE2082T1 (en) OLEFIN POLYMERIZATION CATALYST AND ITS PRODUCTION AND USE.
ES432605A1 (en) Olefine polymerisation process and catalyst
GB907386A (en) Production of polymerisation catalysts
ES392021A2 (en) Catalysts and process for the polymerization and copolymerization of olefins
ES431126A1 (en) Process for the polymerisation of copolymerisation of olefins
ES8202841A1 (en) Components of catalysts for the polymerization of olefines.
ES375278A1 (en) Olefin polymerization
ES329470A1 (en) A procedure for preparing linear alfaolephins. (Machine-translation by Google Translate, not legally binding)
GB836633A (en) Polymerization of olefins
ES382882A1 (en) Procedure for the polymerization of alpha-olefins. (Machine-translation by Google Translate, not legally binding)
ES334581A2 (en) Procedure for preparing linear olefins. (Machine-translation by Google Translate, not legally binding)
ES386497A1 (en) Process for polymerizing alpha-olefins
ES432671A1 (en) Process for the production of polyethylene
ES386684A1 (en) Catalysts for the polymerization of olefins
ES323599A1 (en) A procedure for preparing linear alpine-olefin polymers. (Machine-translation by Google Translate, not legally binding)
GB1187245A (en) Improved Process for Low Pressure Polymerisation of alpha-olefines
ES329469A1 (en) Procedure for preparing linear olefins. (Machine-translation by Google Translate, not legally binding)
GB1194079A (en) Improved Process for Producing Linear Alpha Olefins
Failes et al. 121. Catalysis by hydrogen halides in the gas phase. Part VI. Butan-2-ol and hydrogen bromide
GB1018328A (en) Process for purifying polyolefins
GB1115317A (en) Process for preparing linear alpha olefins
ES375277A1 (en) Procedure for the polymerization of ethylene and its mixtures with superior alpha-olefins and/or diolephins. (Machine-translation by Google Translate, not legally binding)
ES486116A1 (en) Preparation of low density ethylene copolymers in fluid bed reactor.
GB875073A (en) Process for the polymerisation of olefins
ES236885A1 (en) Procedure for the graduation of the molecular weight of olefines polymerized. (Machine-translation by Google Translate, not legally binding)