ES392021A2 - Catalysts and process for the polymerization and copolymerization of olefins - Google Patents
Catalysts and process for the polymerization and copolymerization of olefinsInfo
- Publication number
- ES392021A2 ES392021A2 ES392021A ES392021A ES392021A2 ES 392021 A2 ES392021 A2 ES 392021A2 ES 392021 A ES392021 A ES 392021A ES 392021 A ES392021 A ES 392021A ES 392021 A2 ES392021 A2 ES 392021A2
- Authority
- ES
- Spain
- Prior art keywords
- compound
- solid
- monovalent
- bivalent metal
- organometallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000007787 solid Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- 239000012265 solid product Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- -1 aluminum alcohol halide Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/064—Aluminium compounds with C-aluminium linkage compounds with an Al-Halogen linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Improvements introduced in the object of the main Patent No. 374,898, applied for on December 24, 1969 for: "Procedure for the polymerization and copolymerization of olefins at low pressure", according to which the catalysts are made up: a) of a compound organometallic and b) by a solid obtained by reacting a support consisting of a solid compound of a bivalent metal with an organometallic compound identical or different from the previous one, separating the solid product from the reaction, reacting this product with a halogenated derivative of a metal of transition in the absence of liquid diluent and separating the solid product from the reaction, according to claim 1 of the main patent, characterized in that the solid compound of a bivalent metal is made up of a compound of formula X2-nM (OR) n where M is a bivalent metal, X is a monovalent inorganic radical, R is a hydrocarbon radical C monovalent containing from 1 to 20 carbon atoms and n a number such that 0 or 2 and the organometallic compound reacted with it is an aluminum alcohol halide of formula AlR'Y3-p where Y is a halide radical, R' a monovalent hydrocarbon radical containing 1 to 20 carbon atoms and p is such that 1 or 3. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7021221A FR2093306A6 (en) | 1970-06-09 | 1970-06-09 | ADVANCED CATALYSTS AND PROCESS FOR THE POLYMERIZATION AND COPOLYMERIZATION OF OLEFINS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES392021A2 true ES392021A2 (en) | 1973-11-01 |
Family
ID=9056930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES392021A Expired ES392021A2 (en) | 1970-06-09 | 1971-06-08 | Catalysts and process for the polymerization and copolymerization of olefins |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS51149193A (en) |
| AT (1) | AT312284B (en) |
| BE (1) | BE767586R (en) |
| CA (1) | CA942734A (en) |
| CS (1) | CS169821B2 (en) |
| DE (1) | DE2123356C2 (en) |
| ES (1) | ES392021A2 (en) |
| FR (1) | FR2093306A6 (en) |
| GB (1) | GB1309987A (en) |
| IT (1) | IT983140B (en) |
| NL (1) | NL145562B (en) |
| RO (1) | RO62183A (en) |
| SU (1) | SU407435A3 (en) |
| ZA (1) | ZA712721B (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE791676A (en) * | 1971-12-08 | 1973-05-21 | Solvay | Process for the polymerization of olefins |
| FI57264C (en) * | 1972-09-14 | 1980-07-10 | Mitsui Petrochemical Ind | SAETT ATT HOMOPOLYMERISERA ELLER COPOLYMERISERA ETHYL PROPYLEN ELLER ETHLEN OCH ALPHA-OLEFIN OCH / ELLER EN DIOLEFIN SAMT EN CATALYST COMPOSITION FOR ANALYZING VID SAETTET |
| JPS5146387A (en) * | 1974-10-18 | 1976-04-20 | Yozo Kondo | Horiorefuinno seizohoho |
| US4192772A (en) | 1975-04-14 | 1980-03-11 | Solvay & Cie | Solid catalyst and process for the preparation thereof |
| LU72278A1 (en) | 1975-04-14 | 1977-02-03 | ||
| IT1038179B (en) * | 1975-05-16 | 1979-11-20 | Montedison Spa | PROCEDURE FOR POLYMERIZATION OF ALPHA OLEFINS WITH AT LEAST THREEATONS OF CARBON |
| LU77489A1 (en) * | 1977-06-06 | 1979-01-19 | ||
| US4105846A (en) * | 1977-08-25 | 1978-08-08 | Standard Oil Company (Indiana) | Increasing the particle size of as formed polyethylene or ethylene copolymer |
| US4233182A (en) | 1978-12-26 | 1980-11-11 | Standard Oil Company (Indiana) | High activity catalyst for the polymerization of alpha-olefins |
| US4277370A (en) * | 1979-02-15 | 1981-07-07 | Standard Oil Company (Indiana) | Alpha-olefin polymerization catalyst |
| US4246383A (en) | 1979-06-25 | 1981-01-20 | The Dow Chemical Company | Process for polymerizing olefins in the presence of a catalyst prepared from an organomagnesium component which does not reduce TiCl4 |
| JPS5641207A (en) * | 1979-09-14 | 1981-04-17 | Idemitsu Kosan Co Ltd | Preparation of polyethylene |
| US4496660A (en) * | 1980-10-01 | 1985-01-29 | The Dow Chemical Company | Catalyst prepared from organo-magnesium compound; oxygen- or nitrogen-containing compound; halide source; transition metal compound and reducing agent |
| JPS58189206A (en) * | 1982-04-30 | 1983-11-04 | Chisso Corp | Catalytic component for alpha-olefin polymerization |
| US4544647A (en) * | 1982-07-29 | 1985-10-01 | The Dow Chemical Company | Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound |
| US4426316A (en) | 1982-09-10 | 1984-01-17 | The Dow Chemical Company | Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound |
| US4434282A (en) | 1982-10-04 | 1984-02-28 | The Dow Chemical Company | Process for polymerizing olefins |
| US4661465A (en) * | 1985-10-31 | 1987-04-28 | The Dow Chemical Company | Method for preparing transition metal component of Ziegler-Natta catalysts |
| US4870039A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from mixed magnesium alkyls and aryls |
| US4870040A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from alkyl or aryl magnesium mixed with a branched or aromatic aldehyde |
| FR2624122B1 (en) * | 1987-12-03 | 1991-11-08 | Solvay | PROCESS FOR THE POLYMERIZATION OF ALPHA-OLEFINS, SOLID CATALYTIC COMPLEXES FOR USE IN THIS POLYMERIZATION AND PROCESS FOR THEIR PREPARATION |
| US5045612A (en) * | 1990-04-18 | 1991-09-03 | The Dow Chemical Company | Catalyst and process for polymerizing olefins |
| US5114897A (en) * | 1990-04-18 | 1992-05-19 | The Dow Chemical Company | Catalyst and process for polymerizing olefins |
| FR2802833B1 (en) * | 1999-12-24 | 2002-05-10 | Inst Francais Du Petrole | CATALYTIC COMPOSITION AND PROCESS FOR THE OLIGOMERIZATION OF ETHYLENE, PARTICULARLY HEXENE-1 |
| US9382347B2 (en) * | 2011-02-16 | 2016-07-05 | Fina Technology Inc | Ziegler-Natta catalysts doped with non-group IV metal chlorides |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE608977A (en) * | 1960-10-10 | |||
| US3644318A (en) * | 1968-08-21 | 1972-02-22 | Hoechst Ag | Process for the polymerization of olefins |
-
1970
- 1970-06-09 FR FR7021221A patent/FR2093306A6/en not_active Expired
-
1971
- 1971-04-27 ZA ZA712721A patent/ZA712721B/en unknown
- 1971-05-11 DE DE2123356A patent/DE2123356C2/en not_active Expired
- 1971-05-17 SU SU1658576A patent/SU407435A3/ru active
- 1971-05-18 CA CA113,322A patent/CA942734A/en not_active Expired
- 1971-05-25 BE BE767586A patent/BE767586R/en active
- 1971-06-05 IT IT25478/71A patent/IT983140B/en active
- 1971-06-07 CS CS4147A patent/CS169821B2/cs unknown
- 1971-06-08 ES ES392021A patent/ES392021A2/en not_active Expired
- 1971-06-08 AT AT04966/71A patent/AT312284B/en active
- 1971-06-09 GB GB1964571*[A patent/GB1309987A/en not_active Expired
- 1971-06-09 RO RO67237A patent/RO62183A/ro unknown
- 1971-06-09 NL NL717107896A patent/NL145562B/en unknown
-
1976
- 1976-06-07 JP JP51065715A patent/JPS51149193A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CS169821B2 (en) | 1976-07-29 |
| JPS5650888B2 (en) | 1981-12-02 |
| RO62183A (en) | 1977-06-15 |
| FR2093306A6 (en) | 1972-01-28 |
| SU407435A3 (en) | 1973-11-21 |
| CA942734A (en) | 1974-02-26 |
| DE2123356C2 (en) | 1983-12-29 |
| BE767586R (en) | 1971-11-25 |
| NL7107896A (en) | 1971-12-13 |
| JPS51149193A (en) | 1976-12-21 |
| ZA712721B (en) | 1972-01-26 |
| IT983140B (en) | 1974-10-31 |
| AT312284B (en) | 1973-11-15 |
| GB1309987A (en) | 1973-03-14 |
| NL145562B (en) | 1975-04-15 |
| DE2123356A1 (en) | 1971-12-16 |
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