GB1409729A - Hot melt backsize adhesive compositions - Google Patents
Hot melt backsize adhesive compositionsInfo
- Publication number
- GB1409729A GB1409729A GB4970772A GB4970772A GB1409729A GB 1409729 A GB1409729 A GB 1409729A GB 4970772 A GB4970772 A GB 4970772A GB 4970772 A GB4970772 A GB 4970772A GB 1409729 A GB1409729 A GB 1409729A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- weight per
- softening point
- wax
- hot melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000000853 adhesive Substances 0.000 title abstract 2
- 230000001070 adhesive effect Effects 0.000 title abstract 2
- 239000012943 hotmelt Substances 0.000 title 1
- 239000000463 material Substances 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 239000001993 wax Substances 0.000 abstract 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 240000000491 Corchorus aestuans Species 0.000 abstract 1
- 235000011777 Corchorus aestuans Nutrition 0.000 abstract 1
- 235000010862 Corchorus capsularis Nutrition 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000004831 Hot glue Substances 0.000 abstract 1
- 239000013032 Hydrocarbon resin Substances 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229910052570 clay Inorganic materials 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 235000013312 flour Nutrition 0.000 abstract 1
- 229920006270 hydrocarbon resin Polymers 0.000 abstract 1
- 238000010030 laminating Methods 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 1
- 235000019792 magnesium silicate Nutrition 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 239000012169 petroleum derived wax Substances 0.000 abstract 1
- 235000019381 petroleum wax Nutrition 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2471/00—Floor coverings
- B32B2471/02—Carpets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23993—Composition of pile or adhesive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31801—Of wax or waxy material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Carpets (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US19402571A | 1971-10-29 | 1971-10-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1409729A true GB1409729A (en) | 1975-10-15 |
Family
ID=22715998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4970772A Expired GB1409729A (en) | 1971-10-29 | 1972-10-27 | Hot melt backsize adhesive compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3745054A (enExample) |
| JP (1) | JPS56467B2 (enExample) |
| BE (1) | BE790696A (enExample) |
| CA (1) | CA987811A (enExample) |
| DE (1) | DE2252799C2 (enExample) |
| FR (1) | FR2158028B1 (enExample) |
| GB (1) | GB1409729A (enExample) |
| IT (1) | IT970047B (enExample) |
| NL (1) | NL174478C (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0046536A1 (en) * | 1980-08-11 | 1982-03-03 | E.I. Du Pont De Nemours And Company | Filled and plasticized blends of linear low density polyethylene and a carpet having a backside coating of the same |
| EP0045968A3 (en) * | 1980-08-11 | 1982-03-03 | E.I. Du Pont De Nemours And Company | Filled thermoplastic compositions based on ethylene interpolymers and polyester, polyether and polyether ester plasticizers |
| EP0045967A3 (en) * | 1980-08-11 | 1982-03-03 | E.I. Du Pont De Nemours And Company | Filled thermoplastic compositions based on mixtures of ethylene interpolymers |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3887738A (en) * | 1971-03-04 | 1975-06-03 | Ashland Oil Inc | Carpet backsized with hot melt adhesive and method |
| US3878011A (en) * | 1973-01-05 | 1975-04-15 | Bond Worth Ltd | Pile fabrics and methods and apparatus for the production thereof |
| JPS5810437B2 (ja) * | 1974-12-20 | 1983-02-25 | ジェイエスアール株式会社 | ネツユウチヤクホウホウ |
| US3940525A (en) * | 1974-12-30 | 1976-02-24 | E. I. Du Pont De Nemours And Company | Tufted carpet having a polyolefin film as the secondary backing |
| JPS5825705B2 (ja) * | 1975-10-09 | 1983-05-28 | 日石三菱株式会社 | ネツヨウユウセイセツチヤクザイソセイブツ |
| US4175977A (en) * | 1977-09-19 | 1979-11-27 | International Paper Company | Process for producing a flowable, highly pigmented, low viscosity, hot-melt coating compound |
| US4500661A (en) * | 1977-11-03 | 1985-02-19 | Gulf Oil Corporation | Adhesive composition |
| US4247584A (en) * | 1979-05-22 | 1981-01-27 | American Can Company | Composition comprising a blend of EVA polymers having differing VA contents; films and laminates made therefrom by extrusion; and heat-sealed food bags made from the laminates |
| NL7905548A (nl) * | 1979-07-17 | 1981-01-20 | Unilever Nv | Vaste koolwaterstofharsen. |
| US4456649A (en) * | 1979-10-02 | 1984-06-26 | Manville Service Corporation | Low-cost, highly filled, wax-based hot melt adhesives and coatings |
| JPS56501285A (enExample) * | 1979-10-02 | 1981-09-10 | ||
| US4508771A (en) * | 1979-11-19 | 1985-04-02 | Exxon Research & Engineering Co. | Extruded carpet backing with resin and elastomer components |
| GR77638B (enExample) * | 1981-09-22 | 1984-09-25 | Milliken Res Corp | |
| US4435469A (en) | 1982-04-28 | 1984-03-06 | Manville Service Corporation | Hot melt adhesive for bonding paper to glass fiber |
| US4552794A (en) * | 1983-06-30 | 1985-11-12 | Hercules Incorporated | Composition for tufted carpets containing azidosulfonyl silane crosslinker |
| US4501846A (en) * | 1983-06-30 | 1985-02-26 | Hercules Incorporated | Composition for tufted carpets |
| US4844765A (en) * | 1987-10-14 | 1989-07-04 | Amoco Corporation | Method for preparing tufted pile carpet and adhesive therefor |
| US5560972A (en) * | 1988-07-25 | 1996-10-01 | Interface, Inc. | Latex fusion bonded pile carpets and carpet tile |
| US6133355A (en) * | 1995-09-27 | 2000-10-17 | 3D Systems, Inc. | Selective deposition modeling materials and method |
| US7338698B1 (en) | 1997-02-28 | 2008-03-04 | Columbia Insurance Company | Homogeneously branched ethylene polymer carpet, carpet backing and method for making same |
| US20030211280A1 (en) | 1997-02-28 | 2003-11-13 | Shaw Industries, Inc. | Carpet, carpet backings and methods |
| WO1998038375A2 (en) | 1997-02-28 | 1998-09-03 | Shaw Industries, Inc. | Carpet, carpet backings and methods |
| US7018492B1 (en) * | 1999-10-29 | 2006-03-28 | Propex Fabrics, Inc. | Carpets with improved fuzz-resistance |
| US20050281977A1 (en) * | 2004-01-23 | 2005-12-22 | Mashburn Larry E | Method of carpet construction |
| DE102004016790A1 (de) * | 2004-04-06 | 2005-11-17 | Clariant Gmbh | Verwendung von Wachsen als Modifizierungsmittel für gefüllte Kunststoffe |
| US20050260380A1 (en) * | 2004-05-20 | 2005-11-24 | Moon Richard C | Tuftable carpet backings and carpets with enhanced tuft holding properties |
| EP1879745B1 (en) * | 2005-02-28 | 2017-04-12 | Propex Operating Company, LLC | Composite secondary carpet backing, method of manufacture thereof, and carpet made therefrom |
| US8043713B2 (en) * | 2005-12-15 | 2011-10-25 | Dow Global Technologies Llc | Compositions and aqueous dispersions |
| US20070178790A1 (en) * | 2006-01-31 | 2007-08-02 | Propex Fabrics Inc. | Secondary carpet backing and buckling resistant carpet made therefrom |
| US7820728B2 (en) | 2006-11-13 | 2010-10-26 | Columbia Insurance Company | Methods and systems for recycling carpet and carpets manufactured from recycled material |
| CN101945756B (zh) * | 2007-12-21 | 2014-09-17 | 陶氏环球技术有限责任公司 | 地毯,地毯衬垫和使用烯烃嵌段共聚物制备它们的方法 |
| US9885149B2 (en) | 2009-07-08 | 2018-02-06 | Dow Global Technologies Llc | Carpet and carpet backing |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3390035A (en) * | 1966-05-12 | 1968-06-25 | Du Pont | Method for manufacturing tufted carpets |
| US3551231A (en) * | 1968-05-01 | 1970-12-29 | Du Pont | Process for preparing a tufted carpet using a hot melt backsizing composition |
-
0
- BE BE790696D patent/BE790696A/xx not_active IP Right Cessation
-
1971
- 1971-10-29 US US00194025A patent/US3745054A/en not_active Expired - Lifetime
-
1972
- 1972-10-23 CA CA154,476A patent/CA987811A/en not_active Expired
- 1972-10-27 FR FR7238262A patent/FR2158028B1/fr not_active Expired
- 1972-10-27 GB GB4970772A patent/GB1409729A/en not_active Expired
- 1972-10-27 IT IT31084/72A patent/IT970047B/it active
- 1972-10-27 NL NLAANVRAGE7214610,A patent/NL174478C/xx not_active IP Right Cessation
- 1972-10-27 JP JP10726072A patent/JPS56467B2/ja not_active Expired
- 1972-10-27 DE DE2252799A patent/DE2252799C2/de not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0046536A1 (en) * | 1980-08-11 | 1982-03-03 | E.I. Du Pont De Nemours And Company | Filled and plasticized blends of linear low density polyethylene and a carpet having a backside coating of the same |
| EP0045968A3 (en) * | 1980-08-11 | 1982-03-03 | E.I. Du Pont De Nemours And Company | Filled thermoplastic compositions based on ethylene interpolymers and polyester, polyether and polyether ester plasticizers |
| EP0045967A3 (en) * | 1980-08-11 | 1982-03-03 | E.I. Du Pont De Nemours And Company | Filled thermoplastic compositions based on mixtures of ethylene interpolymers |
Also Published As
| Publication number | Publication date |
|---|---|
| NL174478B (nl) | 1984-01-16 |
| DE2252799A1 (de) | 1973-05-03 |
| DE2252799C2 (de) | 1982-07-01 |
| JPS56467B2 (enExample) | 1981-01-08 |
| FR2158028A1 (enExample) | 1973-06-08 |
| IT970047B (it) | 1974-04-10 |
| NL174478C (nl) | 1984-06-18 |
| BE790696A (fr) | 1973-02-15 |
| US3745054A (en) | 1973-07-10 |
| FR2158028B1 (enExample) | 1977-08-26 |
| JPS4851939A (enExample) | 1973-07-21 |
| NL7214610A (enExample) | 1973-05-02 |
| CA987811A (en) | 1976-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |