GB1390497A - Copolymerisation process and product - Google Patents

Copolymerisation process and product

Info

Publication number
GB1390497A
GB1390497A GB685171A GB685171A GB1390497A GB 1390497 A GB1390497 A GB 1390497A GB 685171 A GB685171 A GB 685171A GB 685171 A GB685171 A GB 685171A GB 1390497 A GB1390497 A GB 1390497A
Authority
GB
United Kingdom
Prior art keywords
heat reaction
styrene
acrylic
copolymers
butyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB685171A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Berger Jenson and Nicholson Ltd
Original Assignee
Berger Jenson and Nicholson Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Berger Jenson and Nicholson Ltd filed Critical Berger Jenson and Nicholson Ltd
Priority to GB685171A priority Critical patent/GB1390497A/en
Priority to ZA721296A priority patent/ZA721296B/en
Priority to CA135,686A priority patent/CA979020A/en
Priority to IT21437/72A priority patent/IT961148B/en
Priority to FR7208754A priority patent/FR2130192A1/en
Priority to DE19722212504 priority patent/DE2212504A1/en
Priority to AT218972A priority patent/AT315489B/en
Priority to US05/458,454 priority patent/US3954720A/en
Publication of GB1390497A publication Critical patent/GB1390497A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Paints Or Removers (AREA)

Abstract

1390497 Copolymers of 1-olefin heat reaction products; enamels BERGER JENSON & NICHOLSON Ltd 8 March 1972 [15 March 1971 (2)] 6851/71 and 6852/71 Headings C3P and C3R Copolymers of (A) a heat reaction product of one or more normally liquid 1-olefins of 6-22 C atoms having a non-volatile content, determined at the mid-distillation point of the normally liquid 1-olefine or at 250‹ C., whichever is lower, of 1-60% by wt., and containing up to 10% by wt. of one or more free-radical-generating polymerization initiators, and (B) at least one other ethylenically unsaturated copolymerizable monomer, are claimed per se. (B) may be a vinyl aromatic, vinyl, vinylidene or allyl compound, a conjugated diene or an acrylic compound, Preferred copolymers are derived from 1-25% by wt. of (i) the heat reaction product (A), (ii) 5-25% of acrylamide, methacrylamide or hydroxyethyl or -propyl acrylates or methacrylates, (iii) 0-8% of ethylenically unsaturated mono- or dicarboxylic acid, and (iv) the balance of styrene, vinyl toluene or C 1 -C 10 aliphatic or cycloaliphatic monohydric alcohol esters of acrylic or methacrylic acid. The copolymers may be prepared by reacting the monomers in the presence of a free radical polymerization initiator added gradually during the course of the reaction. Specified acids are acrylic, methacrylic, itaconic, maleic and fumaric acids. Specified esters are methyl, butyl and 2-ethylhexyl acrylates. The initiator may be di-t.-butyl peroxide, cumene hydroperoxide or t. -butyl perbenzoate; and chain transfer agent, e.g. t.-dodecyl and lauryl mercaptans, may be present. The reaction may be effected in a solvent, e.g. xylene. The products may be mixed with crosslinking agents, e.g. urea, melamine- and phenol-formaldehyde condensates, alkylol alkyl melamines, polyepoxy compounds and polyisocyanate condensates, and pigments to give coating compositions. In examples 1- decene heat reaction products are copolymerized with hydroxypropyl methacrylate, styrene and (1 and 2) butyl acrylate and acrylic acid, and (3)2-ethylhexyl acrylate and methacrylic acid; 1-octene heat reaction product with (6) ethyl acrylate, acrylamide, maleic anhydride and styrene; and 1-hexene heat reaction product with (7) butyl acrylate, hydroxypropyl methacrylate, acrylic acid and styrene; and enamels are prepared by mixing products 1, 2 and 7 with butylated melamine-formaldehyde resin, epoxide resin, titanium dioxide, ethylene glycol monoethyl ether acetate, butanol and xylene; and product 6 with epoxy resin, titanium dioxide, butanol and xylene.
GB685171A 1971-03-15 1971-03-15 Copolymerisation process and product Expired GB1390497A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
GB685171A GB1390497A (en) 1971-03-15 1971-03-15 Copolymerisation process and product
ZA721296A ZA721296B (en) 1971-03-15 1972-02-28 Heat reaction process and product
CA135,686A CA979020A (en) 1971-03-15 1972-02-28 Copolymers and method of making them
IT21437/72A IT961148B (en) 1971-03-15 1972-03-04 PROCEDURE AND PRODUCT OF THERMAL REACTION OF ONE OR MORE OLEFINS
FR7208754A FR2130192A1 (en) 1971-03-15 1972-03-14 Catalytic heat-treatment of higher 1-olefines - to improve their copolymerisability
DE19722212504 DE2212504A1 (en) 1971-03-15 1972-03-15 HEAT ACTION PRODUCT OF 1-OLEFINS AND THE PROCESS FOR ITS MANUFACTURING
AT218972A AT315489B (en) 1971-03-15 1972-03-15 Process for the preparation of a 1-olefin heat conversion product or a copolymer containing this
US05/458,454 US3954720A (en) 1971-03-15 1974-04-05 Copolymerisation process and product

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB685171A GB1390497A (en) 1971-03-15 1971-03-15 Copolymerisation process and product
GB685271 1971-03-15

Publications (1)

Publication Number Publication Date
GB1390497A true GB1390497A (en) 1975-04-16

Family

ID=26240984

Family Applications (1)

Application Number Title Priority Date Filing Date
GB685171A Expired GB1390497A (en) 1971-03-15 1971-03-15 Copolymerisation process and product

Country Status (1)

Country Link
GB (1) GB1390497A (en)

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee