GB1378063A - Battery electrolyte composition containing the reaction product of an amine and an epichlorohydrin - Google Patents
Battery electrolyte composition containing the reaction product of an amine and an epichlorohydrinInfo
- Publication number
- GB1378063A GB1378063A GB5261372A GB5261372A GB1378063A GB 1378063 A GB1378063 A GB 1378063A GB 5261372 A GB5261372 A GB 5261372A GB 5261372 A GB5261372 A GB 5261372A GB 1378063 A GB1378063 A GB 1378063A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epichlorohydrin
- reaction product
- electrolyte
- suggested
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003792 electrolyte Substances 0.000 title abstract 6
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 title abstract 5
- 239000007795 chemical reaction product Substances 0.000 title abstract 4
- 150000001412 amines Chemical class 0.000 title abstract 3
- 210000004027 cell Anatomy 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- ICGLOTCMOYCOTB-UHFFFAOYSA-N [Cl].[Zn] Chemical compound [Cl].[Zn] ICGLOTCMOYCOTB-UHFFFAOYSA-N 0.000 abstract 1
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 210000001787 dendrite Anatomy 0.000 abstract 1
- 238000004146 energy storage Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 abstract 1
- 239000004312 hexamethylene tetramine Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910001507 metal halide Inorganic materials 0.000 abstract 1
- 150000005309 metal halides Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- ACXCKRZOISAYHH-UHFFFAOYSA-N molecular chlorine hydrate Chemical compound O.ClCl ACXCKRZOISAYHH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 235000005074 zinc chloride Nutrition 0.000 abstract 1
- 239000011592 zinc chloride Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
- H01M12/085—Zinc-halogen cells or batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/365—Zinc-halogen accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Secondary Cells (AREA)
Abstract
1378063 Battery electrolytes OMF CALIFORNIA Inc 14 Nov 1972 [18 Nov 1971] 52613/72 Heading H1B An electrolyte for an electric energy storage device comprises an aqueous solution containing a metal halide and the (unidentified) reaction product of ammonia or an amine and an epichlorohydrin. Virtually all metals are suggested for the halide with the exception of the alkali and alkaline earth metals. Zinc or iron cobalt or nickel is preferred. Chlorine and bromine are the suggested halogens. The particular application is to zinc-chlorine cells involving the use of chlorine hydrate. The epichlorohydrin reaction product in the electrolyte acts to prevent dendrite formation during charging of the cell. It may be necessary to add a concentrate of the reaction product to the electrolyte immediately prior to each recharging of the cell. A great variety of amines are suggested. They may be reacted with epichlorohydrin in water. In the only specific example, hexamethylenetetramine and epichlorohydrin are reacted in water at 100 C. and the product steam distilled out. The distillate is brought to pH 5-6 and added to aqueous zinc chloride to produce the electrolyte.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20023071A | 1971-11-18 | 1971-11-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1378063A true GB1378063A (en) | 1974-12-18 |
Family
ID=22740845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5261372A Expired GB1378063A (en) | 1971-11-18 | 1972-11-14 | Battery electrolyte composition containing the reaction product of an amine and an epichlorohydrin |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS4863240A (en) |
| AU (1) | AU4792272A (en) |
| BR (1) | BR7208090D0 (en) |
| CA (1) | CA982213A (en) |
| DE (1) | DE2254404A1 (en) |
| FR (1) | FR2160622A1 (en) |
| GB (1) | GB1378063A (en) |
| IT (1) | IT988074B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0109223B1 (en) * | 1982-11-02 | 1987-07-22 | Kabushiki Kaisha Meidensha Meidensha Electric Mfg. Co., Ltd. | Electrolyte for zinc-bromine storage batteries |
-
1972
- 1972-10-18 CA CA154,532A patent/CA982213A/en not_active Expired
- 1972-10-19 AU AU47922/72A patent/AU4792272A/en not_active Expired
- 1972-11-07 DE DE2254404A patent/DE2254404A1/en active Pending
- 1972-11-14 GB GB5261372A patent/GB1378063A/en not_active Expired
- 1972-11-16 IT IT54066/72A patent/IT988074B/en active
- 1972-11-17 BR BR008090/72A patent/BR7208090D0/en unknown
- 1972-11-17 FR FR7240953A patent/FR2160622A1/fr not_active Withdrawn
- 1972-11-18 JP JP47116089A patent/JPS4863240A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU4792272A (en) | 1974-04-26 |
| IT988074B (en) | 1975-04-10 |
| DE2254404A1 (en) | 1973-05-24 |
| BR7208090D0 (en) | 1973-08-30 |
| JPS4863240A (en) | 1973-09-03 |
| CA982213A (en) | 1976-01-20 |
| FR2160622A1 (en) | 1973-06-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |