GB1347186A - Sizing composition and glass fibres sized therewith - Google Patents
Sizing composition and glass fibres sized therewithInfo
- Publication number
- GB1347186A GB1347186A GB3850172A GB3850172A GB1347186A GB 1347186 A GB1347186 A GB 1347186A GB 3850172 A GB3850172 A GB 3850172A GB 3850172 A GB3850172 A GB 3850172A GB 1347186 A GB1347186 A GB 1347186A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- sized
- fibres
- glass
- glass fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/64—Amino alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
1347186 Sizing glass fibres OWENS-CORNING FIBERGLAS CORP 17 Aug 1972 [29 Nov 1971] 38501/72 Heading D1P [Also in Division C3] Linear glass fibres are sized using a composition comprises: (I) 1.5-2.5% by wt. of a water emulsifiable resin comprising at least one film former containing a solubilizing group wherein Y is H or a C 1-7 alkyl radical or is the same'as X where X is an aliphatic hydrocarbon radical having at least one OH group, OH or -(OR") n OH (R" is a C 1-6 aliphatic hydrocarbon radical and n=1-25), R is a long chain organic radical having a M.W. up to 10,000; (II) 1.9 to 3.0% by wt. of an emulsifiable lubricant; (III) 0.06-0.40% by wt. of a volatile organic acid which forms an azetrope with water; and/or (IV) a non-volatile C 2-9 polyfunctional organic acid or a blend of such acids. A typical I has the formula: Other examples are derived from the same epoxy resin and contain either the original glycidyl group or two dihydroxyethyl amine groups. II may be a polyethylene glycol fatty acid ester, a silicone emulsion or a polyethylene emulsion. III may be formic acid, propionic acid, butyric acid, valeric acid or ethyl hexanoic acid. IV may be citric, oxalic, itaconic, succinic, lactic or azelaic acid. The composition may additionally comprise up to 1.2% by wt. of an organosilane (V), e.g. gamma-glycidoxypropyltrimethoxysilane and/or gamma - aminopropyltrimethoxysilane. The fibres may be sized immediately after formation from molten glass, the sized fibres gathered into a strand and the sized strands collected on a rotating cylinder to form a wound package having multiple layers of the sized glass strand; the product may be dried in a conventional oven.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20301271A | 1971-11-29 | 1971-11-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1347186A true GB1347186A (en) | 1974-02-27 |
Family
ID=22752091
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3850172A Expired GB1347186A (en) | 1971-11-29 | 1972-08-17 | Sizing composition and glass fibres sized therewith |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS5623931B2 (en) |
BE (1) | BE784261A (en) |
BR (1) | BR7203302D0 (en) |
CA (1) | CA979557A (en) |
DE (1) | DE2245835A1 (en) |
FI (1) | FI54592C (en) |
FR (1) | FR2161878B1 (en) |
GB (1) | GB1347186A (en) |
IT (1) | IT951490B (en) |
NL (1) | NL7213668A (en) |
NO (1) | NO135833C (en) |
SE (1) | SE380788B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2434128A1 (en) * | 1978-08-21 | 1980-03-21 | Ppg Industries Inc | GLASS FIBER YARNS, PRIMED, NON-CROSSLINKABLE, COMPATIBLE WITH POLYOLEFINS AND STABLE ON STORAGE |
US4358501A (en) | 1978-08-14 | 1982-11-09 | Ppg Industries, Inc. | Storage stable polyolefin compatible size for fiber glass strands |
US4413085A (en) | 1978-08-21 | 1983-11-01 | Ppg Industries, Inc. | Storage stable polyolefin compatible non-crosslinking size for fiber glass strands |
EP0224727A1 (en) * | 1985-11-13 | 1987-06-10 | International Business Machines Corporation | Process for preparing reinforced epoxy product and product |
US4749614A (en) * | 1986-04-10 | 1988-06-07 | International Business Machines Corporation | Process for coating fibers, use thereof, and product |
US5633075A (en) * | 1988-01-12 | 1997-05-27 | Raychem Limited | Composite material |
WO2001019713A1 (en) * | 1999-09-14 | 2001-03-22 | Ppg Industries Ohio, Inc. | Wound fiber strand package and process for winding fiber strand on a bobbin |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1565823A (en) * | 1976-11-11 | 1980-04-23 | Pilkington Brothers Ltd | Coating of glass fibres |
JPS55149147A (en) * | 1979-05-11 | 1980-11-20 | Fuji Fiber Glass Kk | Glass fiber sizing composition |
ATE244302T1 (en) * | 1993-04-05 | 2003-07-15 | Aveve Nv | PHYTATE HYDROLYSIS AND ENZYMATIC COMPOSITION FOR THE HYDROLYSIS OF PHYTATE |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3533768A (en) * | 1966-08-18 | 1970-10-13 | Owens Corning Fiberglass Corp | Method of coating fibers using shear thinning gel forming materials |
US3567570A (en) * | 1967-08-14 | 1971-03-02 | Owens Corning Fiberglass Corp | Glass fibers having reduced static electricity generating properties |
US3652326A (en) * | 1970-04-03 | 1972-03-28 | Owens Corning Fiberglass Corp | Sizing composition and glass fibers treated therewith |
-
1972
- 1972-04-17 IT IT2323672A patent/IT951490B/en active
- 1972-05-23 CA CA142,704A patent/CA979557A/en not_active Expired
- 1972-05-25 BR BR330272A patent/BR7203302D0/en unknown
- 1972-05-30 FR FR7219395A patent/FR2161878B1/fr not_active Expired
- 1972-06-01 BE BE784261A patent/BE784261A/en unknown
- 1972-08-17 GB GB3850172A patent/GB1347186A/en not_active Expired
- 1972-09-19 SE SE1207372A patent/SE380788B/en unknown
- 1972-09-19 DE DE19722245835 patent/DE2245835A1/en active Pending
- 1972-10-10 NL NL7213668A patent/NL7213668A/xx not_active Application Discontinuation
- 1972-11-27 NO NO434372A patent/NO135833C/no unknown
- 1972-11-29 JP JP12025572A patent/JPS5623931B2/ja not_active Expired
- 1972-11-29 FI FI337272A patent/FI54592C/en active
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4358501A (en) | 1978-08-14 | 1982-11-09 | Ppg Industries, Inc. | Storage stable polyolefin compatible size for fiber glass strands |
FR2434128A1 (en) * | 1978-08-21 | 1980-03-21 | Ppg Industries Inc | GLASS FIBER YARNS, PRIMED, NON-CROSSLINKABLE, COMPATIBLE WITH POLYOLEFINS AND STABLE ON STORAGE |
US4248935A (en) | 1978-08-21 | 1981-02-03 | Ppg Industries, Inc. | Storage stable polyolefin compatible non-crosslinking size for fiber glass strands |
US4413085A (en) | 1978-08-21 | 1983-11-01 | Ppg Industries, Inc. | Storage stable polyolefin compatible non-crosslinking size for fiber glass strands |
EP0224727A1 (en) * | 1985-11-13 | 1987-06-10 | International Business Machines Corporation | Process for preparing reinforced epoxy product and product |
US4749614A (en) * | 1986-04-10 | 1988-06-07 | International Business Machines Corporation | Process for coating fibers, use thereof, and product |
US5633075A (en) * | 1988-01-12 | 1997-05-27 | Raychem Limited | Composite material |
US5645906A (en) * | 1988-01-12 | 1997-07-08 | Raychem Limited | Radially-recoverable sleeve of composite |
WO2001019713A1 (en) * | 1999-09-14 | 2001-03-22 | Ppg Industries Ohio, Inc. | Wound fiber strand package and process for winding fiber strand on a bobbin |
Also Published As
Publication number | Publication date |
---|---|
FI54592B (en) | 1978-09-29 |
NO135833B (en) | 1977-02-28 |
JPS4863094A (en) | 1973-09-03 |
IT951490B (en) | 1973-06-30 |
SE380788B (en) | 1975-11-17 |
BR7203302D0 (en) | 1973-07-24 |
FR2161878B1 (en) | 1977-04-01 |
DE2245835A1 (en) | 1973-06-07 |
NO135833C (en) | 1977-06-08 |
BE784261A (en) | 1972-12-01 |
NL7213668A (en) | 1973-06-01 |
JPS5623931B2 (en) | 1981-06-03 |
FR2161878A1 (en) | 1973-07-13 |
FI54592C (en) | 1979-01-10 |
CA979557A (en) | 1975-12-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |