GB1345081A - Process for the preparation of ypsilon-alkoxy-acetoacetic esters - Google Patents
Process for the preparation of ypsilon-alkoxy-acetoacetic estersInfo
- Publication number
- GB1345081A GB1345081A GB3097072A GB3097072A GB1345081A GB 1345081 A GB1345081 A GB 1345081A GB 3097072 A GB3097072 A GB 3097072A GB 3097072 A GB3097072 A GB 3097072A GB 1345081 A GB1345081 A GB 1345081A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ester
- alkoxy
- acetoacetic
- acetoacetic acid
- formamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/716—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
1345081 Alkoxy-acetoacetic esters LONZA Ltd 25 Aug 1972 [10 Sept 1971] 30970/72 Heading C2C #-Alkoxy-acetoacetic acid esters are prepared by reacting a #-haloacetoacetic ester with an alkali metal alcoholate dissolved in an alcohol. A further aprotic solvent, e.g. dimethyl sulphoxide, dimethyl formamide, formamide, N- methyl formamide and N-methyl propionamide may be present. Methanol, ethanol, n-propanol, isopropanol, n-butanol and sec-butanol may be the alcohols. Examples describe the preparation of #-ethoxy-acetoacetic acid ethyl ester, #-methoxy-acetoacetic acid methyl ester, γ-isopropoxy - acetoacetic acid isopropyl ester and #-octyloxyacetoacetic acid octyl ester.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1327773A CH572104A5 (en) | 1972-11-18 | 1973-09-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1345081A true GB1345081A (en) | 1974-01-30 |
Family
ID=4390994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3097072A Expired GB1345081A (en) | 1973-09-14 | 1972-05-25 | Process for the preparation of ypsilon-alkoxy-acetoacetic esters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1345081A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0067410A1 (en) * | 1981-06-17 | 1982-12-22 | Lonza Ag | Alkyl esters of 4-hydroxy-acetoacetic acid and process of their preparation |
EP0102893A1 (en) * | 1982-08-24 | 1984-03-14 | Shionogi & Co., Ltd. | A novel production of 1-oxacephams |
EP0520290A2 (en) * | 1991-06-28 | 1992-12-30 | Haarmann & Reimer Gmbh | Ethers of 1-hydroxy-hex-5-en-2-on, process for their preparation and their use in perfumery |
-
1972
- 1972-05-25 GB GB3097072A patent/GB1345081A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0067410A1 (en) * | 1981-06-17 | 1982-12-22 | Lonza Ag | Alkyl esters of 4-hydroxy-acetoacetic acid and process of their preparation |
EP0102893A1 (en) * | 1982-08-24 | 1984-03-14 | Shionogi & Co., Ltd. | A novel production of 1-oxacephams |
EP0520290A2 (en) * | 1991-06-28 | 1992-12-30 | Haarmann & Reimer Gmbh | Ethers of 1-hydroxy-hex-5-en-2-on, process for their preparation and their use in perfumery |
EP0520290A3 (en) * | 1991-06-28 | 1993-03-24 | Haarmann & Reimer Gmbh | Ethers of 1-hydroxy-hex-5-en-2-on, process for their preparation and their use in perfumery |
US5248831A (en) * | 1991-06-28 | 1993-09-28 | Haarmann & Reimer Gmbh | Ethers of 1-hydroxy-hex-5-en-2-one, processes for their preparation and their use as odoriferous substances |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |