GB942664A - Improved methods of producing dimethyl ª -ketoadipate and dimethyl ª -methyl ª -ketoadipate - Google Patents
Improved methods of producing dimethyl ª -ketoadipate and dimethyl ª -methyl ª -ketoadipateInfo
- Publication number
- GB942664A GB942664A GB4137262A GB4137262A GB942664A GB 942664 A GB942664 A GB 942664A GB 4137262 A GB4137262 A GB 4137262A GB 4137262 A GB4137262 A GB 4137262A GB 942664 A GB942664 A GB 942664A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ketoadipate
- dimethyl
- methyl
- improved methods
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/716—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Dimethyl b -ketoadipate and dimethyl a -methyl-b -ketoadipate are prepared by a process consisting in treating the ethyl methyl ester of b -ketoadipic acid with sodium methoxide in methanol in the case of the former, and in the case of the latter further reacting the product with a methyl halide. Examples are furnished. The products are employed in the preparation intermediates for the preparation of oestrone according to the process of Specification 942,663.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4137262A GB942664A (en) | 1960-04-06 | 1960-04-06 | Improved methods of producing dimethyl ª -ketoadipate and dimethyl ª -methyl ª -ketoadipate |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1220360A GB942663A (en) | 1960-04-06 | 1960-04-06 | Phenyl cyclohexane and -cyclohexene derivatives, new intermediates for the synthesis of the female sex hormone estrone and other steroids |
GB4137262A GB942664A (en) | 1960-04-06 | 1960-04-06 | Improved methods of producing dimethyl ª -ketoadipate and dimethyl ª -methyl ª -ketoadipate |
Publications (1)
Publication Number | Publication Date |
---|---|
GB942664A true GB942664A (en) | 1963-11-27 |
Family
ID=10419382
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4137262A Expired GB942664A (en) | 1960-04-06 | 1960-04-06 | Improved methods of producing dimethyl ª -ketoadipate and dimethyl ª -methyl ª -ketoadipate |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB942664A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104478719A (en) * | 2015-01-23 | 2015-04-01 | 河南师范大学 | 4-methoxy methyl acetoacetate preparation method |
-
1960
- 1960-04-06 GB GB4137262A patent/GB942664A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104478719A (en) * | 2015-01-23 | 2015-04-01 | 河南师范大学 | 4-methoxy methyl acetoacetate preparation method |
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