GB1340873A - Carbonylation of olefins and acetylenes - Google Patents

Carbonylation of olefins and acetylenes

Info

Publication number
GB1340873A
GB1340873A GB1441570A GB1340873DA GB1340873A GB 1340873 A GB1340873 A GB 1340873A GB 1441570 A GB1441570 A GB 1441570A GB 1340873D A GB1340873D A GB 1340873DA GB 1340873 A GB1340873 A GB 1340873A
Authority
GB
United Kingdom
Prior art keywords
ethyl
carboxylate
iiib
ene
oct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1441570A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of GB1340873A publication Critical patent/GB1340873A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0219—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/57—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
GB1441570A 1970-03-25 1971-03-25 Carbonylation of olefins and acetylenes Expired GB1340873A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1441570 1970-03-25
GB4253270 1970-09-04

Publications (1)

Publication Number Publication Date
GB1340873A true GB1340873A (en) 1973-12-19

Family

ID=26250545

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1441570A Expired GB1340873A (en) 1970-03-25 1971-03-25 Carbonylation of olefins and acetylenes

Country Status (6)

Country Link
US (1) US3952034A (cg-RX-API-DMAC7.html)
BE (1) BE764787A (cg-RX-API-DMAC7.html)
DE (1) DE2114544B2 (cg-RX-API-DMAC7.html)
FR (1) FR2085113A5 (cg-RX-API-DMAC7.html)
GB (1) GB1340873A (cg-RX-API-DMAC7.html)
NL (1) NL7103977A (cg-RX-API-DMAC7.html)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932484A (en) * 1974-04-22 1976-01-13 Texaco Inc. Preparation of monocarboxylated cyclododeca derivatives
DE2646792C2 (de) * 1975-10-23 1985-05-09 Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben
US4171450A (en) * 1977-06-22 1979-10-16 Atlantic Richfield Company Preparation of unsaturated diesters by catalytic oxidative carbonylation of diolefins
US4093647A (en) * 1977-08-22 1978-06-06 Suntech, Inc. Process for oxycarbonylation of aromatic hydrocarbons
IE53193B1 (en) * 1981-07-14 1988-08-17 Smithkline Beckman Corp Preparation of lower alkyl 2-formyl-3-(6-methyl-3-pyridinyl)-propionates
FR2512813A1 (fr) * 1981-09-16 1983-03-18 Rhone Poulenc Chim Base Procede de carbonylation des dienes conjugues en presence d'un catalyseur au palladium avec recyclage dudit catalyseur
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
GB8432376D0 (en) * 1984-12-21 1985-02-06 Shell Int Research Carbonylation of acetylenically unsaturated compounds
GB8501919D0 (en) * 1985-01-25 1985-02-27 Shell Int Research Carbonylation of allenically unsaturated compounds
DE3917329A1 (de) * 1989-05-27 1990-11-29 Huels Chemische Werke Ag Verfahren zur herstellung von cyclooctandicarbonsaeurediestern
US5254720A (en) * 1992-12-28 1993-10-19 Ethyl Corporation Process for preparing aryl-substituted aliphatic carboxylic acids and their alkyl esters
US6331502B1 (en) * 1998-12-09 2001-12-18 Council Of Scientific And Industrial Research Catalyst system containing a semilabile anionic ligand and a use of such catalyst system to produce α, β, -unsaturated carboxylic acids and their esters
WO2019219227A1 (en) * 2018-05-15 2019-11-21 Givaudan Sa Organic compounds
CN117004663A (zh) * 2022-04-27 2023-11-07 上海颐碳化学科技有限公司 合成(r)-4-丙基二氢呋喃-2(3氢)-酮的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3043872A (en) * 1958-11-07 1962-07-10 Union Carbide Corp Decolorization method for pimelic acid
US3468927A (en) * 1965-03-15 1969-09-23 Eastman Kodak Co Process for preparing pimelic acid and a 2,2-dialkyl-1,3-propanediol
US3453299A (en) * 1965-08-13 1969-07-01 Ici Ltd Dinuclear bridged copper and palladium complexes
GB1182932A (en) * 1967-04-17 1970-03-04 Ici Ltd Transition Metal Complexes
US3717670A (en) * 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3579552A (en) * 1968-08-15 1971-05-18 Monsanto Co Production of carboxylic acids
US3661949A (en) * 1969-06-11 1972-05-09 Union Oil Co Hydrocarboxylation process utilizing an iron salt cocatalyst
US3622607A (en) * 1969-11-03 1971-11-23 Union Oil Co Palladium chelates having a palladium-carbon bond

Also Published As

Publication number Publication date
US3952034A (en) 1976-04-20
FR2085113A5 (en) 1971-12-17
BE764787A (fr) 1971-09-24
DE2114544B2 (de) 1975-02-06
DE2114544A1 (de) 1971-10-14
NL7103977A (cg-RX-API-DMAC7.html) 1971-09-28

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee