GB1332829A - Process for the production of hydrogen - Google Patents

Process for the production of hydrogen

Info

Publication number
GB1332829A
GB1332829A GB6097570A GB6097570A GB1332829A GB 1332829 A GB1332829 A GB 1332829A GB 6097570 A GB6097570 A GB 6097570A GB 6097570 A GB6097570 A GB 6097570A GB 1332829 A GB1332829 A GB 1332829A
Authority
GB
United Kingdom
Prior art keywords
bricks
catalyst
catalysts
dec
reacted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6097570A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of GB1332829A publication Critical patent/GB1332829A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0294—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing three or more CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0877—Methods of cooling by direct injection of fluid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1332829 Combustible gas SIEMENS AG 22 Dec 1970 [24 Dec 1969] 60975/70 Heading C5E A gaseous or liquid hydrocarbon, e.g. benzene, is reacted with air or oxygen over a Ni or Pt catalyst to produce H 2 and CO which are reacted with water vapour over a catalyst which promotes the conversion of CO to CO 2 , both reactions being conducted on a porous surface, e.g. in sintered bricks which support the catalysts. The preheated reactants traverse a plurality of spaced bricks, having a pore volume of 50 to 65%, through parallel passages in the bricks, water being delivered to the spaces between the downstream bricks which contain the conversion catalyst, e.g. a mixture of Zn, Cu, Cr, Fe or their oxides. The Ni- or Pt-containing brick may be bounded on each side by a catalystfree brick, and the Ni catalyst may incorporate UO 2 or one or more uranium compounds convertible during the reaction to UO 2 . The Ni and Pt catalysts may be introduced into the bricks in the form of aqueous solutions of e.g. Ni acetate, carbonate or formate, or chloroplatinic acid.
GB6097570A 1969-12-24 1970-12-22 Process for the production of hydrogen Expired GB1332829A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1964810A DE1964810C3 (en) 1969-12-24 1969-12-24 Device for the production of hydrogen

Publications (1)

Publication Number Publication Date
GB1332829A true GB1332829A (en) 1973-10-03

Family

ID=5754928

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6097570A Expired GB1332829A (en) 1969-12-24 1970-12-22 Process for the production of hydrogen

Country Status (12)

Country Link
US (1) US3798005A (en)
JP (1) JPS5023675B1 (en)
AT (1) AT311920B (en)
BE (1) BE760829A (en)
CA (1) CA924079A (en)
CH (1) CH555294A (en)
DE (1) DE1964810C3 (en)
FR (1) FR2074176A5 (en)
GB (1) GB1332829A (en)
NL (1) NL7017470A (en)
SE (1) SE362861B (en)
ZA (1) ZA708583B (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2232506C2 (en) * 1972-07-03 1982-03-25 Siemens AG, 1000 Berlin und 8000 München Method and device for generating a gas mixture to be formed by the catalytic conversion of fuel and a gas serving as an oxygen carrier
DE2306025C3 (en) * 1973-02-07 1978-11-02 Siemens Ag, 1000 Berlin Und 8000 Muenchen Quick start device especially for gap gas generators used on internal combustion engines
NL175835B (en) * 1973-04-17 1984-08-01 Shell Int Research Process for preparing a hydrogen-rich gas from a carbon monoxide-containing gas using a nickel and / or cobalt and molybdenum-containing catalyst.
JPS5228447B2 (en) * 1974-03-06 1977-07-27
US4131086A (en) * 1974-07-20 1978-12-26 Nippon Soken, Inc. Fuel reforming apparatus for use with internal combustion engine
US4270896A (en) * 1975-08-26 1981-06-02 Engelhard Minerals & Chemicals Corporation Catalyst system
US4138220A (en) * 1978-02-13 1979-02-06 Colonial Metals, Inc. Apparatus for catalytic oxidation of grease and fats in low temperature fumes
DE2809126C2 (en) * 1978-03-03 1986-07-17 GHT Gesellschaft für Hochtemperaturreaktor-Technik mbH, 5060 Bergisch Gladbach Cracking furnace
US4371500A (en) * 1979-06-30 1983-02-01 Unique Energy Systems, Inc. Apparatus for generating hydrogen
US4419329A (en) * 1980-07-09 1983-12-06 Heller Charles H Device for producing hydrogen and oxygen gases
AU1334383A (en) * 1983-01-26 1984-08-15 Unique Energy Systems, Inc. Method and apparatus for generating hydrogen
DE19544895C1 (en) * 1995-12-01 1997-02-27 Daimler Benz Ag Oxidising carbon mon:oxide in gas mixt. from hydrocarbon reforming plant
DE19719997A1 (en) * 1997-05-13 1998-05-28 Daimler Benz Ag Reformer for stream reforming methanol
DE19720294C1 (en) * 1997-05-15 1998-12-10 Dbb Fuel Cell Engines Gmbh Reforming reactor and operating procedures therefor
DE19836289A1 (en) * 1998-08-11 2000-02-17 Opel Adam Ag Reformer for endothermally and chemically converting a reactant to a reformate gas in fuel cells has a catalyst bed and a burner formed by a catalytically active layer
JP4810749B2 (en) * 2000-06-08 2011-11-09 トヨタ自動車株式会社 Fuel reformer
JP4356198B2 (en) * 2000-06-14 2009-11-04 トヨタ自動車株式会社 Fuel reformer
AT412845B (en) * 2003-07-14 2005-08-25 Alpps Fuel Cell Systems Gmbh EXHAUST GAS TREATMENT SYSTEM FOR REDUCING NOX EMISSIONS FROM HEATING POWER MACHINES USING FUEL PRODUCED REDUCTIVE MEANS
DE102005048385A1 (en) * 2005-10-10 2007-04-19 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for the evaporation and reforming of liquid fuels
AU2010224845B2 (en) * 2009-03-19 2013-08-22 Air Products And Chemicals, Inc. Process to prepare a hydrogen rich gas mixture
DE102009051938A1 (en) * 2009-11-04 2011-05-26 Siemens Aktiengesellschaft Chemical reactor with heat extraction
JP2016103366A (en) * 2014-11-27 2016-06-02 アイシン精機株式会社 Fuel cell system

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2465235A (en) * 1949-03-22 Production of hydrogen
GB265989A (en) * 1926-02-11 1927-09-22 Ig Farbenindustrie Ag Improvements in the decomposition of gaseous or vapourous hydrocarbons by means of water vapour
US1967665A (en) * 1930-06-17 1934-07-24 Ig Farbenindustrie Ag Conversion of hydrocarbons
US1904908A (en) * 1930-08-07 1933-04-18 Standard Oil Co Hydrogen preparation
US2482866A (en) * 1944-11-01 1949-09-27 Stanolind Oil & Gas Co Production of carbon monoxide and hydrogen
GB775334A (en) * 1954-06-22 1957-05-22 Basf Ag Improvements in the reaction of gaseous hydrocarbons with oxygen
US2956864A (en) * 1955-01-10 1960-10-18 Wulff Process Company Furnace assemblies and combination of such furnaces
CH354060A (en) * 1955-12-27 1961-05-15 Simonek Jiri Process for recovering the heat and the water vapor from the reaction gases in the reaction of water vapor with gas
US3010807A (en) * 1958-09-10 1961-11-28 Chemical Construction Corp Multi-stage catalytic conversion
US3172251A (en) * 1963-01-14 1965-03-09 Minnesota Mining & Mfg Afterburner system
US3441359A (en) * 1967-04-26 1969-04-29 Engelhard Ind Inc Catalytic radiant heater
GB1193202A (en) * 1967-05-02 1970-05-28 Texaco Development Corp Process for the Production of Synthesis Gas.
US3679372A (en) * 1969-04-09 1972-07-25 Gen Electric Off-gas burner system

Also Published As

Publication number Publication date
BE760829A (en) 1971-06-24
DE1964810A1 (en) 1971-07-15
DE1964810C3 (en) 1979-04-05
CH555294A (en) 1974-10-31
FR2074176A5 (en) 1971-10-01
ZA708583B (en) 1971-09-29
DE1964810B2 (en) 1978-07-20
US3798005A (en) 1974-03-19
CA924079A (en) 1973-04-10
AT311920B (en) 1973-12-10
JPS5023675B1 (en) 1975-08-09
SE362861B (en) 1973-12-27
NL7017470A (en) 1971-06-28

Similar Documents

Publication Publication Date Title
GB1332829A (en) Process for the production of hydrogen
US5525322A (en) Method for simultaneous recovery of hydrogen from water and from hydrocarbons
US6409940B1 (en) Nickel-rhodium based catalysts and process for preparing synthesis gas
US2601221A (en) Dissociation of ammonia
GB1330841A (en) Catalytic reactions
GB1375791A (en)
GB1415847A (en) Oxidation of pollutants of an exhaust gas
ES489081A1 (en) Process for preparing urethanes.
GB1472595A (en) Process for the preparation of a hydrogenrich gas
EP0147569A1 (en) Process for the production of hydrogen
GB1289375A (en)
GB1440149A (en) Catalysts comprising phosphorus vanadium and oxygen
GB1206729A (en) Improvements in or relating to nitric acid tail gas purification
GB1491499A (en) Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide
GB1440413A (en) Process for producing butyraldehydes
GB319396A (en) Improvements relating to the purification of gas containing sulphuretted hydrogen
US3705231A (en) Selective removal of nitrogen dioxide from gases
JPH0218282B2 (en)
GB1357502A (en) Process for producing a reducing gas
ES395092A1 (en) Method and apparatus for reacting sulfur dioxide and natural gas
US11390522B2 (en) Process for conversion of sulfur trioxide and hydrogen production
GB1481017A (en) Process and device for the recovery of noble metals
GB1475090A (en) Process for the conversion of water into hydrogen and oxygen
JP3051564B2 (en) Steam reforming reactor
GB1411106A (en) Process for reducing the nitrogen oxide-s- content of a gas comprising oxygen and one or more nitrogen oxides

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee