GB1330208A - Oxidation of vicinal glycols in the presence of organic peroxides and cobaltous compounds - Google Patents
Oxidation of vicinal glycols in the presence of organic peroxides and cobaltous compoundsInfo
- Publication number
- GB1330208A GB1330208A GB4098371A GB4098371A GB1330208A GB 1330208 A GB1330208 A GB 1330208A GB 4098371 A GB4098371 A GB 4098371A GB 4098371 A GB4098371 A GB 4098371A GB 1330208 A GB1330208 A GB 1330208A
- Authority
- GB
- United Kingdom
- Prior art keywords
- organic
- acids
- aryl
- alkyl
- carboxylic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002334 glycols Chemical group 0.000 title abstract 3
- 150000001451 organic peroxides Chemical class 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical class [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 150000001735 carboxylic acids Chemical class 0.000 abstract 3
- -1 cobalt (II) compound Chemical class 0.000 abstract 3
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- VACHUYIREGFMSP-UHFFFAOYSA-N (+)-threo-9,10-Dihydroxy-octadecansaeure Natural products CCCCCCCCC(O)C(O)CCCCCCCC(O)=O VACHUYIREGFMSP-UHFFFAOYSA-N 0.000 abstract 1
- BTOOAFQCTJZDRC-UHFFFAOYSA-N 1,2-hexadecanediol Chemical compound CCCCCCCCCCCCCCC(O)CO BTOOAFQCTJZDRC-UHFFFAOYSA-N 0.000 abstract 1
- XWAMHGPDZOVVND-UHFFFAOYSA-N 1,2-octadecanediol Chemical compound CCCCCCCCCCCCCCCCC(O)CO XWAMHGPDZOVVND-UHFFFAOYSA-N 0.000 abstract 1
- DWANEFRJKWXRSG-UHFFFAOYSA-N 1,2-tetradecanediol Chemical compound CCCCCCCCCCCCC(O)CO DWANEFRJKWXRSG-UHFFFAOYSA-N 0.000 abstract 1
- JPFGKGZYCXLEGQ-UHFFFAOYSA-N 1-(4-methoxyphenyl)-5-methylpyrazole-4-carboxylic acid Chemical compound C1=CC(OC)=CC=C1N1C(C)=C(C(O)=O)C=N1 JPFGKGZYCXLEGQ-UHFFFAOYSA-N 0.000 abstract 1
- VACHUYIREGFMSP-SJORKVTESA-N 9,10-Dihydroxystearic acid Natural products CCCCCCCC[C@@H](O)[C@@H](O)CCCCCCCC(O)=O VACHUYIREGFMSP-SJORKVTESA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001869 cobalt compounds Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002285 corn oil Substances 0.000 abstract 1
- 235000005687 corn oil Nutrition 0.000 abstract 1
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- ZITKDVFRMRXIJQ-UHFFFAOYSA-N dodecane-1,2-diol Chemical compound CCCCCCCCCCC(O)CO ZITKDVFRMRXIJQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- IHPDTPWNFBQHEB-UHFFFAOYSA-N hydrobenzoin Chemical compound C=1C=CC=CC=1C(O)C(O)C1=CC=CC=C1 IHPDTPWNFBQHEB-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000010697 neat foot oil Substances 0.000 abstract 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 abstract 1
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical class CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 abstract 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 238000007248 oxidative elimination reaction Methods 0.000 abstract 1
- 150000004965 peroxy acids Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000003549 soybean oil Substances 0.000 abstract 1
- 235000012424 soybean oil Nutrition 0.000 abstract 1
- 125000001174 sulfone group Chemical group 0.000 abstract 1
- 239000003760 tallow Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6991270A | 1970-09-04 | 1970-09-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1330208A true GB1330208A (en) | 1973-09-12 |
Family
ID=22091978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4098371A Expired GB1330208A (en) | 1970-09-04 | 1971-09-02 | Oxidation of vicinal glycols in the presence of organic peroxides and cobaltous compounds |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3711523A (enExample) |
| BE (1) | BE772164A (enExample) |
| CA (1) | CA969970A (enExample) |
| DE (1) | DE2144015A1 (enExample) |
| FR (1) | FR2107184A5 (enExample) |
| GB (1) | GB1330208A (enExample) |
| NL (1) | NL7112126A (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3855257A (en) * | 1970-06-29 | 1974-12-17 | Procter & Gamble | Preparation of carboxylic acids by the oxidation of vicinal glycols |
| DE2038296A1 (de) * | 1970-08-01 | 1972-02-17 | Henkel & Cie Gmbh | Verfahren zur Herstellung von Carbonsaeuren |
| DE2256888C2 (de) * | 1972-11-20 | 1982-06-09 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur Herstellung von Alkancarbonsäuren |
| DE2314454C2 (de) * | 1973-03-23 | 1987-04-23 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur kontinuierlichen Herstellung von Carbonsäuren |
| DE2836327A1 (de) * | 1978-08-19 | 1980-02-28 | Bayer Ag | Verfahren zur herstellung von arylglyoxylsaeuren |
| US4606863A (en) * | 1983-06-02 | 1986-08-19 | New Japan Chemical Co., Ltd. | Process for preparing carboxylic acid |
| US5596111A (en) * | 1995-06-05 | 1997-01-21 | North Dakota State University | Method for preparation of carboxylic acids |
| WO2018104208A1 (en) * | 2016-12-07 | 2018-06-14 | Solvay Sa | Method of cleaving oleic acid and/or derivatives thereof |
| WO2019101856A1 (en) | 2017-11-22 | 2019-05-31 | Novamont S.P.A. | Production of carboxylic acids from vicinal diols |
-
1970
- 1970-09-04 US US00069912A patent/US3711523A/en not_active Expired - Lifetime
-
1971
- 1971-08-23 CA CA121,112A patent/CA969970A/en not_active Expired
- 1971-09-02 GB GB4098371A patent/GB1330208A/en not_active Expired
- 1971-09-02 FR FR7131785A patent/FR2107184A5/fr not_active Expired
- 1971-09-02 DE DE19712144015 patent/DE2144015A1/de active Pending
- 1971-09-03 BE BE772164A patent/BE772164A/xx unknown
- 1971-09-03 NL NL7112126A patent/NL7112126A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE772164A (fr) | 1972-03-03 |
| DE2144015A1 (de) | 1972-03-09 |
| NL7112126A (enExample) | 1972-03-07 |
| US3711523A (en) | 1973-01-16 |
| FR2107184A5 (enExample) | 1972-05-05 |
| CA969970A (en) | 1975-06-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |