GB1323301A - Continuous production of water-soluble phenol formaldehyde resins - Google Patents

Continuous production of water-soluble phenol formaldehyde resins

Info

Publication number
GB1323301A
GB1323301A GB3178970A GB3178970A GB1323301A GB 1323301 A GB1323301 A GB 1323301A GB 3178970 A GB3178970 A GB 3178970A GB 3178970 A GB3178970 A GB 3178970A GB 1323301 A GB1323301 A GB 1323301A
Authority
GB
United Kingdom
Prior art keywords
reactor
phenol
water
coil
formaldehyde resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3178970A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie de Saint Gobain SA
Original Assignee
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie de Saint Gobain SA filed Critical Compagnie de Saint Gobain SA
Publication of GB1323301A publication Critical patent/GB1323301A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen

Abstract

1323301 Polymerisation apparatus SAINTGOBAIN 1 July 1970 [3 July 1969] 31789/70 Heading B1X [Also in Division C3] An apparatus for the continuous production of water-soluble phenol-formaldehyde resin comprises storage vessels 1, 2, 3 for phenol, HCHO and an alkaline catalyst respectively, a mixing device 4 for homogeneously mixing the components at a temperature not above 45‹C, which components are continuously supplied from the storage vessels, a reactor 7 which comprises a coil 9 through which the reaction mixture flows, the coil being immersed in a fluid, such as water, at a temperature of 80‹-90‹C, the rate of flow of the reaction mixture and the temperature through the coil being controllable such that the reaction proceeds with the liquid mixture remaining homogeneous. In the embodiment shown in Fig. 1 for the production of unmodified phenol-formaldehyde resin, the mixture leaving reactor 7 passes through cooling apparatus 11 and then into a neutralisation vat 12. In other embodiments the phenol-formaldehyde resin leaving reactor 7 is condensed with urea, dicyandiamide or melamine in a second reactor of the same construction as reactor 7, the homogeneity of the product being preserved. Suitable catalysts include barium hydroxide monohydrate, pentahydrate or octahydrate, or NaOH.
GB3178970A 1969-07-03 1970-07-01 Continuous production of water-soluble phenol formaldehyde resins Expired GB1323301A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR6922509A FR2051990A5 (en) 1969-07-03 1969-07-03

Publications (1)

Publication Number Publication Date
GB1323301A true GB1323301A (en) 1973-07-11

Family

ID=9036852

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3178970A Expired GB1323301A (en) 1969-07-03 1970-07-01 Continuous production of water-soluble phenol formaldehyde resins

Country Status (16)

Country Link
AT (1) AT319599B (en)
BE (1) BE753006A (en)
CA (1) CA921635A (en)
CH (1) CH519539A (en)
DE (1) DE2029934C3 (en)
DK (1) DK133901B (en)
ES (1) ES381377A1 (en)
FI (1) FI51942C (en)
FR (1) FR2051990A5 (en)
GB (1) GB1323301A (en)
HU (1) HU164823B (en)
NL (1) NL170543C (en)
RO (1) RO57610A (en)
SE (1) SE389124B (en)
YU (1) YU33448B (en)
ZA (1) ZA704542B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0062757A1 (en) * 1981-04-03 1982-10-20 Formica Limited Continuous production of phenolformaldehyde resin and laminates produced therefrom
WO2010149632A1 (en) 2009-06-22 2010-12-29 Dynea Oy A process for the continuous production of an aqueous hydroxy-aryl formaldehyde resin solution
US10450400B1 (en) 2014-01-15 2019-10-22 Arclin Usa, Llc Extruded resorcinol-formaldehyde, phenol-formaldehyde and phenol-resorcinol-formaldehyde gel resins
CN112321780A (en) * 2021-01-04 2021-02-05 山东友泉新材料有限公司 Continuous production method of thermosetting phenolic resin
CN112321779A (en) * 2021-01-04 2021-02-05 山东友泉新材料有限公司 Continuous production method of water-soluble phenolic resin
CN112552472A (en) * 2020-11-13 2021-03-26 山东京博木基材料有限公司 Preparation method of water-soluble toughened modified phenolic resin

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1562211A (en) * 1975-08-04 1980-03-05 Matsushita Electric Works Ltd Phenol-formaldehyde composition useful as a raw material for the preparation of phenolic resins
FR2766201A1 (en) * 1997-07-15 1999-01-22 Saint Gobain Isover PHENOLIC RESIN FOR SIZING COMPOSITION, PROCESS FOR PREPARATION AND SIZING COMPOSITION CONTAINING THE SAME

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0062757A1 (en) * 1981-04-03 1982-10-20 Formica Limited Continuous production of phenolformaldehyde resin and laminates produced therefrom
WO2010149632A1 (en) 2009-06-22 2010-12-29 Dynea Oy A process for the continuous production of an aqueous hydroxy-aryl formaldehyde resin solution
US10450400B1 (en) 2014-01-15 2019-10-22 Arclin Usa, Llc Extruded resorcinol-formaldehyde, phenol-formaldehyde and phenol-resorcinol-formaldehyde gel resins
CN112552472A (en) * 2020-11-13 2021-03-26 山东京博木基材料有限公司 Preparation method of water-soluble toughened modified phenolic resin
CN112552472B (en) * 2020-11-13 2022-08-16 山东京博木基材料有限公司 Preparation method of water-soluble toughened modified phenolic resin
CN112321780A (en) * 2021-01-04 2021-02-05 山东友泉新材料有限公司 Continuous production method of thermosetting phenolic resin
CN112321779A (en) * 2021-01-04 2021-02-05 山东友泉新材料有限公司 Continuous production method of water-soluble phenolic resin
CN112321779B (en) * 2021-01-04 2021-04-06 山东友泉新材料有限公司 Continuous production method of water-soluble phenolic resin
CN112321780B (en) * 2021-01-04 2021-04-09 山东友泉新材料有限公司 Continuous production method of thermosetting phenolic resin

Also Published As

Publication number Publication date
YU33448B (en) 1977-02-28
FI51942C (en) 1977-05-10
DE2029934B2 (en) 1973-12-20
NL170543C (en) 1982-11-16
DE2029934C3 (en) 1974-07-25
DK133901B (en) 1976-08-09
YU143570A (en) 1976-08-31
NL7009904A (en) 1971-01-05
DK133901C (en) 1977-01-17
AT319599B (en) 1974-12-27
SE389124B (en) 1976-10-25
DE2029934A1 (en) 1971-01-14
NL170543B (en) 1982-06-16
ES381377A1 (en) 1972-12-16
HU164823B (en) 1974-04-11
CH519539A (en) 1972-02-29
FI51942B (en) 1977-01-31
RO57610A (en) 1975-08-15
ZA704542B (en) 1971-05-27
CA921635A (en) 1973-02-20
BE753006A (en) 1971-01-04
FR2051990A5 (en) 1971-04-09

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee