GB1312956A - Process for liberating free hydroxyl groups in steroid ethers - Google Patents
Process for liberating free hydroxyl groups in steroid ethersInfo
- Publication number
- GB1312956A GB1312956A GB2240470A GB2240470A GB1312956A GB 1312956 A GB1312956 A GB 1312956A GB 2240470 A GB2240470 A GB 2240470A GB 2240470 A GB2240470 A GB 2240470A GB 1312956 A GB1312956 A GB 1312956A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethers
- methyl
- steroid
- hydroxyl groups
- free hydroxyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 steroid ethers Chemical class 0.000 title abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 238000003776 cleavage reaction Methods 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 2
- 230000007017 scission Effects 0.000 abstract 2
- DNXHEGUUPJUMQT-UHFFFAOYSA-N (+)-estrone Natural products OC1=CC=C2C3CCC(C)(C(CC4)=O)C4C3CCC2=C1 DNXHEGUUPJUMQT-UHFFFAOYSA-N 0.000 abstract 1
- RAGXUPKKYSEPRH-BBCBXFPWSA-N (8R,9S,13S,14S)-13-ethyl-6,7,8,9,11,12,14,15,16,17-decahydrocyclopenta[a]phenanthrene-3,17-diol Chemical compound OC1=CC=C2[C@H]3CC[C@](CC)(C(CC4)O)[C@@H]4[C@@H]3CCC2=C1 RAGXUPKKYSEPRH-BBCBXFPWSA-N 0.000 abstract 1
- VOXZDWNPVJITMN-ZBRFXRBCSA-N 17β-estradiol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 VOXZDWNPVJITMN-ZBRFXRBCSA-N 0.000 abstract 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 150000005215 alkyl ethers Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- PDRGHUMCVRDZLQ-UHFFFAOYSA-N d-equilenin Natural products OC1=CC=C2C(CCC3(C4CCC3=O)C)=C4C=CC2=C1 PDRGHUMCVRDZLQ-UHFFFAOYSA-N 0.000 abstract 1
- PDRGHUMCVRDZLQ-WMZOPIPTSA-N equilenin Chemical compound OC1=CC=C2C(CC[C@]3([C@H]4CCC3=O)C)=C4C=CC2=C1 PDRGHUMCVRDZLQ-WMZOPIPTSA-N 0.000 abstract 1
- 229960005309 estradiol Drugs 0.000 abstract 1
- 229930182833 estradiol Natural products 0.000 abstract 1
- 229960003399 estrone Drugs 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 150000005217 methyl ethers Chemical class 0.000 abstract 1
- HJKVPZJVBHWFCQ-UHFFFAOYSA-N phenolic steroid Chemical compound C1CC2=CC(O)=CC=C2C2C1C1CCCC1(C)CC2 HJKVPZJVBHWFCQ-UHFFFAOYSA-N 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J1/00—Normal steroids containing carbon, hydrogen, halogen or oxygen, not substituted in position 17 beta by a carbon atom, e.g. estrane, androstane
- C07J1/0051—Estrane derivatives
- C07J1/0059—Estrane derivatives substituted in position 17 by a keto group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J1/00—Normal steroids containing carbon, hydrogen, halogen or oxygen, not substituted in position 17 beta by a carbon atom, e.g. estrane, androstane
- C07J1/0051—Estrane derivatives
- C07J1/0066—Estrane derivatives substituted in position 17 beta not substituted in position 17 alfa
- C07J1/007—Estrane derivatives substituted in position 17 beta not substituted in position 17 alfa the substituent being an OH group free esterified or etherified
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J7/00—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms
- C07J7/0005—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21
- C07J7/001—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group
- C07J7/0015—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group not substituted in position 17 alfa
- C07J7/002—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group not substituted in position 17 alfa not substituted in position 16
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691924222 DE1924222A1 (de) | 1969-05-08 | 1969-05-08 | Spaltung von aromatischen Steroidalkylaethern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1312956A true GB1312956A (en) | 1973-04-11 |
Family
ID=5733999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2240470A Expired GB1312956A (en) | 1969-05-08 | 1970-05-08 | Process for liberating free hydroxyl groups in steroid ethers |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5037662B1 (enrdf_load_stackoverflow) |
| BE (1) | BE750162A (enrdf_load_stackoverflow) |
| CH (1) | CH544079A (enrdf_load_stackoverflow) |
| DE (1) | DE1924222A1 (enrdf_load_stackoverflow) |
| DK (1) | DK126777B (enrdf_load_stackoverflow) |
| FR (1) | FR2047463A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1312956A (enrdf_load_stackoverflow) |
| NL (1) | NL7006657A (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52106359U (enrdf_load_stackoverflow) * | 1976-02-05 | 1977-08-12 | ||
| JPS5319477U (enrdf_load_stackoverflow) * | 1976-07-27 | 1978-02-18 | ||
| JPH06182007A (ja) * | 1992-12-15 | 1994-07-05 | Bridgestone Corp | ゴルフクラブシャフト |
-
1969
- 1969-05-08 DE DE19691924222 patent/DE1924222A1/de active Pending
-
1970
- 1970-04-23 CH CH611470A patent/CH544079A/de not_active IP Right Cessation
- 1970-04-28 DK DK214070A patent/DK126777B/da unknown
- 1970-05-06 NL NL7006657A patent/NL7006657A/xx unknown
- 1970-05-07 JP JP7038987A patent/JPS5037662B1/ja active Pending
- 1970-05-08 GB GB2240470A patent/GB1312956A/en not_active Expired
- 1970-05-08 FR FR7016741A patent/FR2047463A5/fr not_active Expired
- 1970-05-08 BE BE750162D patent/BE750162A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL7006657A (enrdf_load_stackoverflow) | 1970-11-10 |
| DE1924222A1 (de) | 1970-11-19 |
| DK126777B (da) | 1973-08-20 |
| CH544079A (de) | 1973-11-15 |
| BE750162A (fr) | 1970-11-09 |
| FR2047463A5 (enrdf_load_stackoverflow) | 1971-03-12 |
| JPS5037662B1 (enrdf_load_stackoverflow) | 1975-12-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |