GB1420892A - Racemic 13beta-ethyl-3-methoxy-8,14-socogona-1,3,5-10,8- tetraen-17beta-ol-14-one and a process for the preparation thereof - Google Patents
Racemic 13beta-ethyl-3-methoxy-8,14-socogona-1,3,5-10,8- tetraen-17beta-ol-14-one and a process for the preparation thereofInfo
- Publication number
- GB1420892A GB1420892A GB162874A GB162874A GB1420892A GB 1420892 A GB1420892 A GB 1420892A GB 162874 A GB162874 A GB 162874A GB 162874 A GB162874 A GB 162874A GB 1420892 A GB1420892 A GB 1420892A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methoxy
- ethyl
- tetraen
- secogona
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J1/00—Normal steroids containing carbon, hydrogen, halogen or oxygen, not substituted in position 17 beta by a carbon atom, e.g. estrane, androstane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1420892 Secosteroids; steroids RICHTER GEDEON VEGYESZETI GYAR RT 14 Jan 1974 [31 Jan 1973] 01628/74 Headings C2C and C2U The invention comprises dl-3-methoxy-13#- ethyl - 17# - hydroxy - 8,14 - secogona- 1,3,5(10),8-tetraen-14-one (I). It is prepared in admixture with dl-3-methoxy-13#-ethyl-9#,14α- epoxy - 8,14 - secogona - 1,3,5(10) - trien - 17 - one (II) by selective reduction of 3-methoxy-13- ethyl - 8,14 - secogona - 1,3,5(10), 9(11) - tetraene-14,17-dione with a metal hydride in alkaline conditions to give dl-3-methoxy-13#-ethyl-17#- hydroxy - 8,14 - secogona - 1,3,5(10), 9(11) - tetraen-14-one (III) in admixture with its 17α- hydroxy epimer (IV). Upon acidification III converts to I, and IV converts to II, and the mixture of I and II is separated chromatographically. dl - 3 - Methoxy - 13# - ethylgona - 1,3,5(10),- 8,14-pentaen-17#-ol acetate is prepared from I by treatment with Ac 2 O/py/benzene then p-toluene sulphonic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HUGO1230A HU170147B (en) | 1973-01-31 | 1973-01-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1420892A true GB1420892A (en) | 1976-01-14 |
Family
ID=10996741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB162874A Expired GB1420892A (en) | 1973-01-31 | 1974-01-14 | Racemic 13beta-ethyl-3-methoxy-8,14-socogona-1,3,5-10,8- tetraen-17beta-ol-14-one and a process for the preparation thereof |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS5641610B2 (en) |
| AT (1) | AT346505B (en) |
| BE (1) | BE810381A (en) |
| BG (1) | BG23904A3 (en) |
| CS (1) | CS165309B2 (en) |
| DE (1) | DE2403985C2 (en) |
| DK (1) | DK138314B (en) |
| ES (1) | ES422607A1 (en) |
| FR (1) | FR2216275B1 (en) |
| GB (1) | GB1420892A (en) |
| HU (1) | HU170147B (en) |
| IL (1) | IL43992A (en) |
| IT (1) | IT1043869B (en) |
| NL (1) | NL7401256A (en) |
| RO (1) | RO67880A (en) |
| SE (1) | SE400977B (en) |
| SU (1) | SU561515A3 (en) |
| YU (1) | YU35750B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE541389C2 (en) * | 2017-12-20 | 2019-09-10 | Scania Cv Ab | System and Method for Controlling a Motor Vehicle to Drive Autonomously |
| SE541390C2 (en) * | 2017-12-20 | 2019-09-10 | Scania Cv Ab | System and Method for Controlling a Motor Vehicle to Drive Autonomously |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3549673A (en) * | 1967-03-09 | 1970-12-22 | Takeda Chemical Industries Ltd | Total synthesis of 13beta-substituted gonapolyen-17alpha-ols |
-
1973
- 1973-01-31 HU HUGO1230A patent/HU170147B/hu unknown
-
1974
- 1974-01-10 IL IL43992A patent/IL43992A/en unknown
- 1974-01-14 GB GB162874A patent/GB1420892A/en not_active Expired
- 1974-01-14 YU YU103/74A patent/YU35750B/en unknown
- 1974-01-17 AT AT38374A patent/AT346505B/en not_active IP Right Cessation
- 1974-01-19 RO RO7477336A patent/RO67880A/en unknown
- 1974-01-22 BG BG025563A patent/BG23904A3/en unknown
- 1974-01-25 CS CS491A patent/CS165309B2/cs unknown
- 1974-01-25 IT IT19776/74A patent/IT1043869B/en active
- 1974-01-25 ES ES422607A patent/ES422607A1/en not_active Expired
- 1974-01-28 FR FR7402683A patent/FR2216275B1/fr not_active Expired
- 1974-01-29 SE SE7401140A patent/SE400977B/en not_active IP Right Cessation
- 1974-01-29 DE DE2403985A patent/DE2403985C2/en not_active Expired
- 1974-01-29 JP JP1154774A patent/JPS5641610B2/ja not_active Expired
- 1974-01-30 DK DK48374AA patent/DK138314B/en not_active IP Right Cessation
- 1974-01-30 BE BE140361A patent/BE810381A/xx not_active IP Right Cessation
- 1974-01-30 SU SU1991803A patent/SU561515A3/en active
- 1974-01-30 NL NL7401256A patent/NL7401256A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| IL43992A (en) | 1977-07-31 |
| IL43992A0 (en) | 1974-05-16 |
| ATA38374A (en) | 1978-03-15 |
| YU10374A (en) | 1980-10-31 |
| CS165309B2 (en) | 1975-12-22 |
| DE2403985C2 (en) | 1984-03-01 |
| DE2403985A1 (en) | 1974-08-08 |
| SU561515A3 (en) | 1977-06-05 |
| HU170147B (en) | 1977-04-28 |
| AT346505B (en) | 1978-11-10 |
| DK138314B (en) | 1978-08-14 |
| BE810381A (en) | 1974-05-16 |
| IT1043869B (en) | 1980-02-29 |
| YU35750B (en) | 1981-06-30 |
| JPS5641610B2 (en) | 1981-09-29 |
| FR2216275A1 (en) | 1974-08-30 |
| FR2216275B1 (en) | 1977-09-23 |
| DK138314C (en) | 1979-02-05 |
| ES422607A1 (en) | 1977-04-16 |
| NL7401256A (en) | 1974-08-02 |
| BG23904A3 (en) | 1977-11-10 |
| RO67880A (en) | 1980-12-30 |
| SE400977B (en) | 1978-04-17 |
| JPS5046653A (en) | 1975-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |