GB1312211A - Phosphorus-containing dibromoeopentyl glycol ester derivatives - Google Patents
Phosphorus-containing dibromoeopentyl glycol ester derivativesInfo
- Publication number
- GB1312211A GB1312211A GB1332771A GB1332771A GB1312211A GB 1312211 A GB1312211 A GB 1312211A GB 1332771 A GB1332771 A GB 1332771A GB 1332771 A GB1332771 A GB 1332771A GB 1312211 A GB1312211 A GB 1312211A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- phosphorus
- ester derivatives
- solvent
- dibromoeopentyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 2
- -1 glycol ester Chemical class 0.000 title abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 2
- 239000011574 phosphorus Substances 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- CHUGKEQJSLOLHL-UHFFFAOYSA-N 2,2-Bis(bromomethyl)propane-1,3-diol Chemical compound OCC(CO)(CBr)CBr CHUGKEQJSLOLHL-UHFFFAOYSA-N 0.000 abstract 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 abstract 1
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical group C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/564—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657109—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s)
- C07F9/657118—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s) non-condensed with carbocyclic rings or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657154—Cyclic esteramides of oxyacids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65742—Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
1312211 Phosphorus-containing dibromoneopentyl ester derivatives STAUFFER CHEMICAL CO 5 May 1971 [6 May 1970] 13327/71 Heading C2P [Also in Division C3] The invention comprises compounds of the general formulae in which X is O or S, Y is Cl or Br, R 1 and R 2 are H, phenyl, cyclohexyl, or the same or different C 1 to C 10 alkyl radicals or R 1 and R 2 together with the N atom to which they are attached form a ring containing 2, 4, 5 or 6 carbon atoms, e.g. an aziridine, piperidine, pyrrolidine or hexamethylenimine ring. The compounds I may be obtained by reacting dibromo-neopentyl glycol with a compound PXY 3 , e.g. POCl 3 , POBr 3 and PSCl 3 in the presence of a solvent, e.g. benzene, suitably at between 0‹ and 100‹ C., until evolution of hydrogen halide is essentially complete and the compounds II may be obtained by reacting compounds I with a secondary amine (R 1 )(R 2 )NH, the reaction being preferably effected in a solvent, e.g. chloroform, at below 10‹ C. The compounds have flameretardant properties.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3526970A | 1970-05-06 | 1970-05-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1312211A true GB1312211A (en) | 1973-04-04 |
Family
ID=21881630
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1332771A Expired GB1312211A (en) | 1970-05-06 | 1971-05-05 | Phosphorus-containing dibromoeopentyl glycol ester derivatives |
Country Status (7)
Country | Link |
---|---|
JP (2) | JPS538709B1 (en) |
BE (1) | BE766533A (en) |
CA (1) | CA988517A (en) |
DE (1) | DE2166942A1 (en) |
FR (1) | FR2093467A5 (en) |
GB (1) | GB1312211A (en) |
NL (1) | NL7105802A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4721583A (en) * | 1985-07-17 | 1988-01-26 | Atochem | Fire-resistant polycarbonates |
EP2481744A1 (en) | 2011-02-01 | 2012-08-01 | EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt | Aromatic bis-phosphoramidate additives as flame retardants for polymers |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4007236A (en) * | 1974-12-31 | 1977-02-08 | Hooker Chemicals & Plastics Corporation | Brominated phosphoramidates |
US6600007B2 (en) | 2001-03-27 | 2003-07-29 | Southwest Distributing Co. | Preparation of bromine-containing hydroxy-functional copolymers |
-
1971
- 1971-04-15 CA CA110,436A patent/CA988517A/en not_active Expired
- 1971-04-28 NL NL7105802A patent/NL7105802A/xx not_active Application Discontinuation
- 1971-04-30 BE BE766533A patent/BE766533A/en unknown
- 1971-05-04 DE DE19712166942 patent/DE2166942A1/en active Pending
- 1971-05-04 FR FR7116076A patent/FR2093467A5/fr not_active Expired
- 1971-05-04 JP JP2896471A patent/JPS538709B1/ja active Pending
- 1971-05-05 GB GB1332771A patent/GB1312211A/en not_active Expired
- 1971-08-03 JP JP5803571A patent/JPS511079B1/ja active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4721583A (en) * | 1985-07-17 | 1988-01-26 | Atochem | Fire-resistant polycarbonates |
EP2481744A1 (en) | 2011-02-01 | 2012-08-01 | EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt | Aromatic bis-phosphoramidate additives as flame retardants for polymers |
Also Published As
Publication number | Publication date |
---|---|
JPS538709B1 (en) | 1978-03-31 |
FR2093467A5 (en) | 1972-01-28 |
BE766533A (en) | 1971-11-03 |
DE2122037B2 (en) | 1977-05-12 |
JPS511079B1 (en) | 1976-01-13 |
NL7105802A (en) | 1971-11-09 |
DE2166942A1 (en) | 1976-12-30 |
DE2122037A1 (en) | 1971-11-18 |
CA988517A (en) | 1976-05-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MY100115A (en) | Nitrogen containing heterocyclic compounds, and their production and use. | |
GB1204447A (en) | 2,2-dichloro-vinylphosphoric acid ester amides | |
ES269967A1 (en) | Pyrazolones and processes for their preparation | |
ES8604543A1 (en) | Piperazine derivatives with anticholinergic and/or antihistaminic activity | |
GB1232748A (en) | ||
GB1312211A (en) | Phosphorus-containing dibromoeopentyl glycol ester derivatives | |
ES387834A1 (en) | Acid amides | |
ES448549A1 (en) | Process for preparing azomethines | |
GB1524727A (en) | Aliphatic sulphamates | |
GB1299954A (en) | Monophosphoryl alkylene diamine derivatives | |
GB1353196A (en) | C1-c4 alkyl 2,3-dibromopropyl acid phosphates | |
GB1304786A (en) | ||
ES392294A1 (en) | 2-amino-4,6-disalicyloyl-hydrazino-s-triazines | |
GB901455A (en) | C-substituted piperazinones and the manufacture thereof | |
ATE27811T1 (en) | ESTERS OF 2-ADAMANTANONE OXIME. | |
ES451209A1 (en) | Antispasmodic substituted sulphoximides | |
GB1061424A (en) | Anthraquinone dyes | |
GB1054338A (en) | ||
ES394484A1 (en) | 1,4-benzodiazepine derivatives | |
ES422040A1 (en) | Hydrazide salts | |
GB1021946A (en) | Alkyleniminopropionic compounds and the preparation thereof | |
GB1131467A (en) | New basic derivatives of benzoxazine and methods for their production | |
ES334297A1 (en) | Process for preparing benzodiazepines | |
GB1466623A (en) | Nutrient compsoitions including heterocyclic compounds and methods involving the use of such compounds | |
GB1071815A (en) | Phenothiazine derivatives |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |