GB1295043A - - Google Patents
Info
- Publication number
- GB1295043A GB1295043A GB1295043DA GB1295043A GB 1295043 A GB1295043 A GB 1295043A GB 1295043D A GB1295043D A GB 1295043DA GB 1295043 A GB1295043 A GB 1295043A
- Authority
- GB
- United Kingdom
- Prior art keywords
- maleic anhydride
- benzoic acid
- ethylene glycol
- polyester
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyesters Or Polycarbonates (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Developing Agents For Electrophotography (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1295043 Curing unsaturated polyesters by electron irradiation SISSONS BROS & CO Ltd 13 Nov 1969 [15 Nov 1968] 54360/68 Heading C3P Coating compositions comprising at least one unsaturated polyester resin of number average molecular weight between 800 and 1500 and with a level of aliphatic unsaturation of at least 3. preferably at least 3À5 double bonds per 1000 gms. (defined as meaning that it contains a total of at least 3À5 gram moles of the unsaturated component per 1000 gms. of resin), mixed with or dissolved in at least one olefinically unsaturated comonomer, are cured by irradiation with electrons which preferably have an average potential in the range 100 to 250 keV. The "feed ratio", the ratio of unsaturation in the comonomer(s), to unsaturation in the polyester, is preferably in the range 1À0 to 1À5. Examples describe the preparation and curing with styrene by the above process, of polyesters derived from (1) maleic anhydride, ethylene glycol and benzoic acid, modified with dicyclopentadiene; (2) maleic anhydride or fumaric acid, and diethylene glycol and isophthalic acid; (3) maleic anhydride, tetrahydrophthalic anhydride, ethylene glycol and benzoic acid; (4) maleic anhydride, tetrahydrophthalic anhydride, neopentyl glycol and benzoic acid; (6) maleic anhydride, tetrahydrophthalic anhydride, phenyl indene dicarboxylic acid, ethylene glycol, and benzoic acid; (7) maleic anhydride, tetrahydrophthalic anhydride, ethylene glycol, cyclohexane-1,2-diol and benzoic acid; (8) maleic anhydride or fumaric acid, and propane- 1,2-diol and benzoic acid, both modified with dicyclopentadiene; (9) maleic anhydride, ethylene glycol and benzoic acid, modified with dicyclopentadiene, and cured in trichloroethylene solution. Examples (10) and (11) describe paint compositions using the polyester of Example (1), cured with styrene and methylmethacrylate respectively. In all the examples, before the dissolution in styrene an inhibitor, hydroquinone, is added. The polyester resin in Example (1) is made into a paint by mixing with a melamine formaldehyde resin, a cellulose acetate/butyrate, a silicone oil, and curing with methylmethacrylate. The polyester in Example 6 is also dissolved in styrene and mixed with TiO 2 and a melamine formaldehyde resin, to give a curable paint. The polyester resin of Example 9 is similarly treated.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5436068 | 1968-11-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1295043A true GB1295043A (en) | 1972-11-01 |
Family
ID=10470749
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1295043D Expired GB1295043A (en) | 1968-11-15 | 1968-11-15 |
Country Status (14)
Country | Link |
---|---|
JP (1) | JPS4910817B1 (en) |
AT (1) | AT313441B (en) |
BE (1) | BE741723A (en) |
CA (1) | CA924263A (en) |
CH (1) | CH518320A (en) |
DE (1) | DE1957424A1 (en) |
FI (1) | FI49625C (en) |
FR (1) | FR2023438A1 (en) |
GB (1) | GB1295043A (en) |
IE (1) | IE33622B1 (en) |
LU (1) | LU59819A1 (en) |
NL (1) | NL6917117A (en) |
NO (1) | NO134382C (en) |
SE (1) | SE376923B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL1005809C2 (en) * | 1997-04-14 | 1998-10-19 | Dsm Nv | Powder paint binder composition. |
WO2010108941A1 (en) * | 2009-03-25 | 2010-09-30 | Dsm Ip Assets B.V. | Resin composition |
CN115210305A (en) * | 2020-01-24 | 2022-10-18 | 莫赛纳涂层公司 | Primer-containing coating |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2302842C3 (en) * | 1973-01-20 | 1980-08-28 | Bayer Ag, 5090 Leverkusen | Molding compounds based on unsaturated polyester, polymerizable vinyl monomers and cellulose esters |
FR2426345A1 (en) * | 1978-05-18 | 1979-12-14 | Carpano & Pons | CONNECTION BODY, FOR TELEPHONE SYSTEMS |
BE888519A (en) * | 1981-04-22 | 1981-10-22 | Gni I P Institutlakokrasochnoi | COMPOSITION FOR PAINTS AND VARNISHES |
-
1968
- 1968-11-15 GB GB1295043D patent/GB1295043A/en not_active Expired
-
1969
- 1969-11-11 IE IE152969A patent/IE33622B1/en unknown
- 1969-11-13 NL NL6917117A patent/NL6917117A/xx unknown
- 1969-11-14 SE SE1566669A patent/SE376923B/xx unknown
- 1969-11-14 DE DE19691957424 patent/DE1957424A1/en active Pending
- 1969-11-14 FI FI329969A patent/FI49625C/en active
- 1969-11-14 BE BE741723D patent/BE741723A/xx unknown
- 1969-11-14 JP JP9132869A patent/JPS4910817B1/ja active Pending
- 1969-11-14 CA CA067466A patent/CA924263A/en not_active Expired
- 1969-11-14 LU LU59819D patent/LU59819A1/xx unknown
- 1969-11-14 FR FR6939295A patent/FR2023438A1/fr not_active Withdrawn
- 1969-11-14 CH CH1701769A patent/CH518320A/en not_active IP Right Cessation
- 1969-11-14 NO NO452869A patent/NO134382C/no unknown
- 1969-11-14 AT AT1069969A patent/AT313441B/en not_active IP Right Cessation
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL1005809C2 (en) * | 1997-04-14 | 1998-10-19 | Dsm Nv | Powder paint binder composition. |
WO1998046690A1 (en) * | 1997-04-14 | 1998-10-22 | Dsm N.V. | Powder paint binder composition |
US6337137B1 (en) | 1997-04-14 | 2002-01-08 | Dsm N.V. | Powder paint binder composition |
WO2010108941A1 (en) * | 2009-03-25 | 2010-09-30 | Dsm Ip Assets B.V. | Resin composition |
US9221973B2 (en) | 2009-03-25 | 2015-12-29 | Dsm Ip Assets B.V. | Resin composition |
CN115210305A (en) * | 2020-01-24 | 2022-10-18 | 莫赛纳涂层公司 | Primer-containing coating |
Also Published As
Publication number | Publication date |
---|---|
NO134382C (en) | 1976-09-29 |
IE33622L (en) | 1970-05-15 |
IE33622B1 (en) | 1974-09-04 |
FI49625C (en) | 1975-08-11 |
FI49625B (en) | 1975-04-30 |
CH518320A (en) | 1972-01-31 |
FR2023438A1 (en) | 1970-08-21 |
SE376923B (en) | 1975-06-16 |
AT313441B (en) | 1974-02-25 |
CA924263A (en) | 1973-04-10 |
DE1957424A1 (en) | 1970-07-23 |
LU59819A1 (en) | 1970-01-14 |
BE741723A (en) | 1970-04-16 |
NL6917117A (en) | 1970-05-20 |
JPS4910817B1 (en) | 1974-03-13 |
NO134382B (en) | 1976-06-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
746 | Register noted 'licences of right' (sect. 46/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |