GB988828A - Modified polyesters - Google Patents

Modified polyesters

Info

Publication number
GB988828A
GB988828A GB2337263A GB2337263A GB988828A GB 988828 A GB988828 A GB 988828A GB 2337263 A GB2337263 A GB 2337263A GB 2337263 A GB2337263 A GB 2337263A GB 988828 A GB988828 A GB 988828A
Authority
GB
United Kingdom
Prior art keywords
acid
xylene
imidocarboxylic
acids
mixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2337263A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beck & Co Dr GmbH
Original Assignee
Beck & Co Dr GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beck & Co Dr GmbH filed Critical Beck & Co Dr GmbH
Publication of GB988828A publication Critical patent/GB988828A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4615Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen
    • C08G18/4638Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/4646Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing one nitrogen atom in the ring
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/42Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Imidocarboxylic acids of the formula <FORM:0988828/C2/1> where R is an inert, aromatic, aliphatic or cycloaliphatic, saturated or unsaturated hydrocarbon radical are made by reacting primary amines with tricarboxylic acid anhydrides. Examples (1) and (3) describe the reaction of trimellitic anhydride with a fatty amine.ALSO:A method of making a modified polyester comprises reacting at least one polyhydric alcohol with at least one polycarboxylic acid reactive derivative thereof, and at least one monocarboxylic acid as modifying agent, wherein said polyhydric alcohol or at least one of said polyhydric alcohols has three or more hydroxyl groups and/or said polycarboxylic acid or at least one of said polycarboxylic acids has three or more carboxyl groups, wherein the amount of said reaction component or components having three or more reactive groups is at least equal to the amount of monocarboxylic acid or acids used, and wherein said monocarboxylic acid or at least one of said monocarboxylic acids is an imidocarboxylic acid of the formula <FORM:0988828/C3/1> where R is an inert, aromatic, aliphatic or cycloaliphatic, saturated or unsaturated hydrocarbon radical. Polyesteramides may be made by replacing part of the polyhydric alcohol by a polyamine. The products are suitable for use in impregnating varnishes in admixture with cross-linking agents, e.g. phenolic resins, aminoplasts and polyisocyanates. In the examples, polymers are made from:-(1) the trimethylol propane monoester of an imidocarboxylic acid derived from trimellitic anhydride and a fatty amine, ethylene glycol and isophthalic acid in the presence of butyl titanate and (3) an imidocarboxylic acid derived from trimellitic acid and a fatty amine and a polyester made by reacting isophthalic acid, trimethylol propane, ethylene glycol and 1:4-butanediol, the products being:-(1) dissolved in xylene and mixed with a butylated melamine-formaldehyde condensate and (3) dissolved in methyl glycol acetate, butyl acetate and xylene and mixed with polymerized phenol-masked toluylene diisocyanate. In Example (2) a solution in xylene of the modified polyester of (1) is mixed with a solution in xylene of a butylated urea-formaldehyde condensate.
GB2337263A 1962-06-20 1963-06-12 Modified polyesters Expired GB988828A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB0067740 1962-06-20
DEB0080778 1962-06-20

Publications (1)

Publication Number Publication Date
GB988828A true GB988828A (en) 1965-04-14

Family

ID=25966296

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2337263A Expired GB988828A (en) 1962-06-20 1963-06-12 Modified polyesters

Country Status (2)

Country Link
DE (2) DE1495098A1 (en)
GB (1) GB988828A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1720323A1 (en) * 1966-12-16 1971-06-16 Beck & Co Ag Dr Process for the production of nitrogen-containing unsaturated polyesters
DE2522386A1 (en) * 1975-05-21 1976-11-25 Chem Fab Dr Wiedeking Gmbh Electrical insulation lacquer for wires - comprises polyester imide and diacetone alcooccohoool and or glycol solvent
EP0161413A1 (en) * 1984-03-24 1985-11-21 Hoechst Aktiengesellschaft Wholly aromatic polyesters, process for their preparation and shaped articles made therefrom
EP0173207A2 (en) * 1984-08-30 1986-03-05 Bayer Ag Polyamide-imides with modified end groups

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2445302C2 (en) * 1974-09-21 1985-01-10 Dr. Beck & Co Ag, 2000 Hamburg Impregnating varnishes for electrical insulation purposes
US4622379A (en) * 1984-10-05 1986-11-11 General Electric Company Polyestercarbonate from amide substituted aromatic dicarboxylic acid

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1720323A1 (en) * 1966-12-16 1971-06-16 Beck & Co Ag Dr Process for the production of nitrogen-containing unsaturated polyesters
DE1795857B1 (en) * 1966-12-16 1980-12-11 Beck & Co Ag Dr Process for the production of moldings from unsaturated polyesters
DE1795857C3 (en) * 1966-12-16 1981-11-26 Dr. Beck & Co Ag, 2000 Hamburg Process for the production of moldings from unsaturated polyesters
DE2522386A1 (en) * 1975-05-21 1976-11-25 Chem Fab Dr Wiedeking Gmbh Electrical insulation lacquer for wires - comprises polyester imide and diacetone alcooccohoool and or glycol solvent
EP0161413A1 (en) * 1984-03-24 1985-11-21 Hoechst Aktiengesellschaft Wholly aromatic polyesters, process for their preparation and shaped articles made therefrom
US4661579A (en) * 1984-03-24 1987-04-28 Hoechst Aktiengesellschaft Completely aromatic polyesters, a process for their preparation and corresponding shaped articles
EP0173207A2 (en) * 1984-08-30 1986-03-05 Bayer Ag Polyamide-imides with modified end groups
EP0173207A3 (en) * 1984-08-30 1988-03-02 Bayer Ag Polyamide-imides with modified end groups
US4829140A (en) * 1984-08-30 1989-05-09 Bayer Aktiengesellschaft Polyamidimides having modified end groups

Also Published As

Publication number Publication date
DE1570242A1 (en) 1970-06-04
DE1495098A1 (en) 1969-02-20

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