IE33622B1 - Improvements in or relating to unsaturated polyester-based coating compositions - Google Patents

Improvements in or relating to unsaturated polyester-based coating compositions

Info

Publication number
IE33622B1
IE33622B1 IE152969A IE152969A IE33622B1 IE 33622 B1 IE33622 B1 IE 33622B1 IE 152969 A IE152969 A IE 152969A IE 152969 A IE152969 A IE 152969A IE 33622 B1 IE33622 B1 IE 33622B1
Authority
IE
Ireland
Prior art keywords
maleic anhydride
benzoic acid
ethylene glycol
polyester
styrene
Prior art date
Application number
IE152969A
Other versions
IE33622L (en
Inventor
D J Crimlisk
A Wright
T E Groves
Original Assignee
Sissons Brothers & Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sissons Brothers & Co Ltd filed Critical Sissons Brothers & Co Ltd
Publication of IE33622L publication Critical patent/IE33622L/en
Publication of IE33622B1 publication Critical patent/IE33622B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/676Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/553Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

1295043 Curing unsaturated polyesters by electron irradiation SISSONS BROS & CO Ltd 13 Nov 1969 [15 Nov 1968] 54360/68 Heading C3P Coating compositions comprising at least one unsaturated polyester resin of number average molecular weight between 800 and 1500 and with a level of aliphatic unsaturation of at least 3. preferably at least 3À5 double bonds per 1000 gms. (defined as meaning that it contains a total of at least 3À5 gram moles of the unsaturated component per 1000 gms. of resin), mixed with or dissolved in at least one olefinically unsaturated comonomer, are cured by irradiation with electrons which preferably have an average potential in the range 100 to 250 keV. The "feed ratio", the ratio of unsaturation in the comonomer(s), to unsaturation in the polyester, is preferably in the range 1À0 to 1À5. Examples describe the preparation and curing with styrene by the above process, of polyesters derived from (1) maleic anhydride, ethylene glycol and benzoic acid, modified with dicyclopentadiene; (2) maleic anhydride or fumaric acid, and diethylene glycol and isophthalic acid; (3) maleic anhydride, tetrahydrophthalic anhydride, ethylene glycol and benzoic acid; (4) maleic anhydride, tetrahydrophthalic anhydride, neopentyl glycol and benzoic acid; (6) maleic anhydride, tetrahydrophthalic anhydride, phenyl indene dicarboxylic acid, ethylene glycol, and benzoic acid; (7) maleic anhydride, tetrahydrophthalic anhydride, ethylene glycol, cyclohexane-1,2-diol and benzoic acid; (8) maleic anhydride or fumaric acid, and propane- 1,2-diol and benzoic acid, both modified with dicyclopentadiene; (9) maleic anhydride, ethylene glycol and benzoic acid, modified with dicyclopentadiene, and cured in trichloroethylene solution. Examples (10) and (11) describe paint compositions using the polyester of Example (1), cured with styrene and methylmethacrylate respectively. In all the examples, before the dissolution in styrene an inhibitor, hydroquinone, is added. The polyester resin in Example (1) is made into a paint by mixing with a melamine formaldehyde resin, a cellulose acetate/butyrate, a silicone oil, and curing with methylmethacrylate. The polyester in Example 6 is also dissolved in styrene and mixed with TiO 2 and a melamine formaldehyde resin, to give a curable paint. The polyester resin of Example 9 is similarly treated. [GB1295043A]
IE152969A 1968-11-15 1969-11-11 Improvements in or relating to unsaturated polyester-based coating compositions IE33622B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5436068 1968-11-15

Publications (2)

Publication Number Publication Date
IE33622L IE33622L (en) 1970-05-15
IE33622B1 true IE33622B1 (en) 1974-09-04

Family

ID=10470749

Family Applications (1)

Application Number Title Priority Date Filing Date
IE152969A IE33622B1 (en) 1968-11-15 1969-11-11 Improvements in or relating to unsaturated polyester-based coating compositions

Country Status (14)

Country Link
JP (1) JPS4910817B1 (en)
AT (1) AT313441B (en)
BE (1) BE741723A (en)
CA (1) CA924263A (en)
CH (1) CH518320A (en)
DE (1) DE1957424A1 (en)
FI (1) FI49625C (en)
FR (1) FR2023438A1 (en)
GB (1) GB1295043A (en)
IE (1) IE33622B1 (en)
LU (1) LU59819A1 (en)
NL (1) NL6917117A (en)
NO (1) NO134382C (en)
SE (1) SE376923B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2302842C3 (en) * 1973-01-20 1980-08-28 Bayer Ag, 5090 Leverkusen Molding compounds based on unsaturated polyester, polymerizable vinyl monomers and cellulose esters
FR2426345A1 (en) * 1978-05-18 1979-12-14 Carpano & Pons CONNECTION BODY, FOR TELEPHONE SYSTEMS
BE888519A (en) * 1981-04-22 1981-10-22 Gni I P Institutlakokrasochnoi COMPOSITION FOR PAINTS AND VARNISHES
NL1005809C2 (en) * 1997-04-14 1998-10-19 Dsm Nv Powder paint binder composition.
ES2525145T3 (en) * 2009-03-25 2014-12-18 Dsm Ip Assets B.V. Resin composition
CA3165370A1 (en) * 2020-01-24 2021-07-29 Mercene Coatings Ab Coating including primer

Also Published As

Publication number Publication date
NO134382B (en) 1976-06-21
LU59819A1 (en) 1970-01-14
CH518320A (en) 1972-01-31
GB1295043A (en) 1972-11-01
BE741723A (en) 1970-04-16
FR2023438A1 (en) 1970-08-21
AT313441B (en) 1974-02-25
NL6917117A (en) 1970-05-20
DE1957424A1 (en) 1970-07-23
CA924263A (en) 1973-04-10
NO134382C (en) 1976-09-29
IE33622L (en) 1970-05-15
FI49625C (en) 1975-08-11
JPS4910817B1 (en) 1974-03-13
FI49625B (en) 1975-04-30
SE376923B (en) 1975-06-16

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