GB1292617A - Photographic physical developer composition - Google Patents
Photographic physical developer compositionInfo
- Publication number
- GB1292617A GB1292617A GB29247/72A GB2924772A GB1292617A GB 1292617 A GB1292617 A GB 1292617A GB 29247/72 A GB29247/72 A GB 29247/72A GB 2924772 A GB2924772 A GB 2924772A GB 1292617 A GB1292617 A GB 1292617A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- alkylene
- aryl
- formula
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/58—Processes for obtaining metallic images by vapour deposition or physical development
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
- G03C1/346—Organic derivatives of bivalent sulfur, selenium or tellurium
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
1292617 Photographic physical developer composition EASTMAN KODAK CO 1 Oct 1969 [1 Oct 1968] 29247/72 Divided out of 1292616 Heading G2C A photographic physical developer composition contains a photographic silver halide developing agent and/or a suitable reducing agent and a stable (i.e. when the complex is incorporated in a photographic material as described in the parent Specification, the material does not show, compared with a control material, an undesired loss in photographic speed and/or density after being kept for a few days at 50C. and 50% relative humidity) complex of silver and an organic compound which is (a) a thiazoline thione or thiazolidine thione, (b) a thiopyrimidine, (c) a dithiocarbamate in the formula: wherein each of R 1 and R 2 is H, alkyl, alkylene, acyl or aryl; and R 12 is alkyl, aryl, or carboxyaralkyl, (d) a thiourea derivative in the formula:- wherein each of R 1 , R 2 , R 4 and R 5 is H, alkyl, alkylene, acyl or aryl; and R 2 and R 5 are joined to form a heterocyclic ring and may together represent -CO-CH=CH-, -CO-CR 1 R 2 -CO-, -CO-CR 1 R 2 - or -CH(R 1 )-CH(R 2 ) wherein R 1 and R 2 are as defined above, (e) a 2-thioimidazoline or 2-thioimidazolidine in the formula: - respectively wherein R 1 and R 2 are as defined above; and R' represents H atoms or the non- metallic atoms completing a hydrocarbon ring and their corresponding tautomers, (f) an isothiourea derivative in the formula:- [H 2 NC(NH)-S-R 1 ]Ag wherein R 1 is alkyl, alkylene, acyl or aryl, (g) not used, (h) a mercaptoalkylcarboxamide, (i) an alkyne compound in the formula: - wherein R 15 is H, aryl, alkyl, alicyclic or alkylene forming a ring with R 16 ; R 16 is H, aryl, alkyl or alkylene forming a ring with R 15 ; R 17 is -O-R 18 , -S-R 19 , -NR 20 R 21 or an alkylene oxide polymer adduct of the formula:- -O(CH 2 CH 2 O) n H wherein n is an integer; R 18 , R 19 , R 20 and R 21 are each H, acyl or alkyl, (j) a hydroxy carboxylic acid in the formula:- [HO-W-COOH]Ag wherein W is alkylene, (k) a thiaalkyl compound in one of the formulae:- [X-S-S-Z]Ag or wherein X and Z are each heterocylic, aryl, alkyl or acyl; Z' is Z or H; n is a number, and Y is alkylene (l) a phenylenedioxy di(alkylcarboxylic acid), (m) a polymer having a ligand atom for silver, or one of the compounds:- 4- (methylthio) phenol, 2-(2-fusylthio) benzoic acid, 5-thioctic acid, 1,10-phenanthroline, 1-(4- carboxyphenyl)-3, 5-dimethyl-4-phenylpyrazole, sodium dicyanamide, 8-hydroxyquinoline, 8- hydroxyquinoline sulphate, saccharin, 2,4- thiazolidinedione, 5-sulphobenzotriazole, oxalic acid, 3,5-dihydroxybenzoic acid or succinic acid. Many examples are given of these complexes. The alkyl, alkylene, acyl and aryl groups in the Specification may contain various substituents which do not adversely affect the stability and availability of silver for physical development of the described complexes, e.g. carboxyl, hydroxyl or sulphonic acid groups.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US76433068A | 1968-10-01 | 1968-10-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1292617A true GB1292617A (en) | 1972-10-11 |
Family
ID=25070401
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB48305/69A Expired GB1292616A (en) | 1968-10-01 | 1969-10-01 | Photographic physical development process |
GB29247/72A Expired GB1292617A (en) | 1968-10-01 | 1969-10-01 | Photographic physical developer composition |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB48305/69A Expired GB1292616A (en) | 1968-10-01 | 1969-10-01 | Photographic physical development process |
Country Status (5)
Country | Link |
---|---|
US (1) | US3647439A (en) |
JP (1) | JPS516535B1 (en) |
CA (1) | CA922148A (en) |
DE (1) | DE1949418A1 (en) |
GB (2) | GB1292616A (en) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3791829A (en) * | 1972-07-03 | 1974-02-12 | Itek Corp | Physically developable copy medium with photoconductors and complexing agent |
US4052211A (en) * | 1972-11-30 | 1977-10-04 | Fuji Photo Film Co., Ltd. | Image forming material |
GB1478113A (en) * | 1973-09-25 | 1977-06-29 | Agfa Gevaert | Development promoting compounds for silver halide photography |
FR2309901A1 (en) * | 1975-05-02 | 1976-11-26 | Kodak Pathe | PROCESS AND PRODUCT FOR OBTAINING PHOTOGRAPHIC IMAGES BY DIFFUSION-TRANSFER |
JPS5253427A (en) * | 1975-10-27 | 1977-04-30 | Fuji Photo Film Co Ltd | Color photograph processing |
JPS53134430A (en) * | 1977-04-27 | 1978-11-24 | Mitsubishi Paper Mills Ltd | Silver halide photosensitive materials for multiilayer color photograph |
US4168980A (en) * | 1977-08-19 | 1979-09-25 | Eastman Kodak Company | Heat developable photographic material and process |
US4178180A (en) * | 1977-09-15 | 1979-12-11 | Eastman Kodak Company | Copper physical development using heterocyclic ligand copper (I) complexes |
US4156610A (en) * | 1977-09-15 | 1979-05-29 | Eastman Kodak Company | Copper physical development using heterocyclic ligand copper(I) complexes |
DE2752046C2 (en) * | 1977-11-22 | 1985-10-03 | Agfa-Gevaert Ag, 5090 Leverkusen | Light sensitive photographic recording material |
US4220709A (en) * | 1977-12-08 | 1980-09-02 | Eastman Kodak Company | Heat developable imaging materials and process |
JPS5948369B2 (en) * | 1980-06-11 | 1984-11-26 | コニカ株式会社 | Photographic image forming method |
GB9005753D0 (en) * | 1990-03-14 | 1990-05-09 | Janssen Pharmaceutica Nv | Light stable physical developer |
JP5000037B2 (en) * | 1997-10-10 | 2012-08-15 | ピュア バイオサイエンス | Fungicide |
US6605751B1 (en) * | 1997-11-14 | 2003-08-12 | Acrymed | Silver-containing compositions, devices and methods for making |
US6043013A (en) * | 1998-01-29 | 2000-03-28 | Eastman Kodak Company | Color photographic element containing elemental silver and heterocyclic thiol in a non-light sensitive layer |
US7261905B2 (en) * | 1999-04-07 | 2007-08-28 | Pure Bioscience | Disinfectant and method of making |
EP1244476B1 (en) | 1999-12-30 | 2006-05-31 | Acrymed | Methods and compositions for improved delivery devices |
US6890953B2 (en) * | 2000-04-06 | 2005-05-10 | Innovative Medical Services | Process for treating water |
US6649330B2 (en) * | 2001-12-28 | 2003-11-18 | Eastman Kodak Company | Silver halide imaging element containing sequestered silver ions |
CN1678277B (en) | 2002-07-29 | 2010-05-05 | 艾克里麦德公司 | Methods and compositions for treatment of dermal conditions |
US20040044073A1 (en) * | 2002-08-31 | 2004-03-04 | Innovative Medical Services | Composition and process for treating acne |
US6689335B1 (en) | 2002-12-19 | 2004-02-10 | Eastman Kodak Company | Silver ion sequester and release agent |
US7435438B1 (en) * | 2003-05-16 | 2008-10-14 | Pure Bioscience | Disinfectant and method of use |
US20050202066A1 (en) * | 2003-08-28 | 2005-09-15 | Arata Andrew B. | Silver dihydrogen citrate compositions comprising a second antimicrobial agent |
US8361553B2 (en) | 2004-07-30 | 2013-01-29 | Kimberly-Clark Worldwide, Inc. | Methods and compositions for metal nanoparticle treated surfaces |
CN101010004B (en) * | 2004-07-30 | 2012-10-03 | 金伯利-克拉克环球有限公司 | Antimicrobial devices and compositions |
EP2789235B1 (en) * | 2004-07-30 | 2015-12-23 | Avent, Inc. | Method of preparing silver nanoparticles |
US20060051430A1 (en) * | 2004-09-07 | 2006-03-09 | Arata Andrew B | Silver dihydrogen citrate compositions |
US9289378B2 (en) * | 2004-09-20 | 2016-03-22 | Avent, Inc. | Antimicrobial amorphous compositions |
EP2015722B1 (en) * | 2006-04-28 | 2016-11-16 | Avent, Inc. | Antimicrobial site dressings |
AU2009316270B2 (en) * | 2008-11-24 | 2015-08-27 | Avent, Inc. | Antimicrobial laminate constructs |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB439812A (en) * | 1933-07-25 | 1935-12-16 | Ig Farbenindustrie Ag | Process for the production of photographic pictures |
NL232192A (en) * | 1958-10-11 | |||
BE586348A (en) * | 1959-01-10 | |||
US3155518A (en) * | 1963-10-21 | 1964-11-03 | Du Pont | Silver halide compositions, layers and elements |
FR89467E (en) * | 1961-12-08 | |||
DE1214083B (en) * | 1964-08-14 | 1966-04-07 | Agfa Gevaert Ag | Photographic light-sensitive material comprising at least one silver salt emulsion light-sensitive layer |
US3407068A (en) * | 1964-10-13 | 1968-10-22 | Du Pont | Photosolubilization |
US3446619A (en) * | 1964-11-16 | 1969-05-27 | Eastman Kodak Co | Radiation sensitive silver-dye complexes |
DE1472757C3 (en) * | 1965-05-19 | 1973-11-08 | Agfa-Gevaert Ag, 5090 Leverkusen | Process for producing photographic images |
-
1968
- 1968-10-01 US US764330A patent/US3647439A/en not_active Expired - Lifetime
-
1969
- 1969-09-09 CA CA061504A patent/CA922148A/en not_active Expired
- 1969-09-25 JP JP44075902A patent/JPS516535B1/ja active Pending
- 1969-09-30 DE DE19691949418 patent/DE1949418A1/en active Pending
- 1969-10-01 GB GB48305/69A patent/GB1292616A/en not_active Expired
- 1969-10-01 GB GB29247/72A patent/GB1292617A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB1292616A (en) | 1972-10-11 |
CA922148A (en) | 1973-03-06 |
DE1949418A1 (en) | 1970-10-29 |
US3647439A (en) | 1972-03-07 |
JPS516535B1 (en) | 1976-02-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1292617A (en) | Photographic physical developer composition | |
DE3203661C2 (en) | ||
US4310622A (en) | Photographic development process | |
US4033771A (en) | Stabilized bleach-fixing baths | |
GB1054123A (en) | ||
US3650749A (en) | Photographic development | |
GB976261A (en) | Direct print photographic materials | |
US3954474A (en) | Developing method | |
US3765901A (en) | Spectral sensitization of light-sensitive silver halide emulsions | |
US3390998A (en) | Stabilized physical developers | |
GB1190678A (en) | Photographic Elements having Thiazolidine Compounds in Light-Insensitive Layers | |
US3240603A (en) | Photographic developer solution containing non-sludging silver halide solvent | |
US3764339A (en) | Silver halide emulsions stabilized with n-(1,3,4-thiadiazol-2-yl)-dithiocarbamic acid esters | |
US3051570A (en) | Antifoggants and stabilizers for photographic silver halide emulsions | |
US3335009A (en) | Antifoggant combination for processing evaporated silver halide layers | |
US2173628A (en) | Stabilization of photographic sensitive materials | |
DE68917945T2 (en) | Process for photographic processing. | |
US3554758A (en) | Photographic light-sensitive material | |
US3046130A (en) | Photographic materials containing a chemical sensitizer | |
GB1066007A (en) | Improvements in or relating to gelatin-containing compositions | |
US4299913A (en) | Photographic reversal process without second exposure | |
GB1281393A (en) | Methine dyes | |
US3615521A (en) | Photographic compositions and processes-a | |
DE1797027A1 (en) | Photographic material with improved properties | |
DE1472774C3 (en) | Stabilized silver halide photographic emulsion |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PLNP | Patent lapsed through nonpayment of renewal fees |