US3051570A - Antifoggants and stabilizers for photographic silver halide emulsions - Google Patents
Antifoggants and stabilizers for photographic silver halide emulsions Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/08—1,2,4-Thiadiazoles; Hydrogenated 1,2,4-thiadiazoles
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
- G03C1/346—Organic derivatives of bivalent sulfur, selenium or tellurium
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- This invention relates to the stabilization of photographic materials. More particularly, this invention relates to light-sensitive photographic silver halide emulsions containing mercapto-1,2,4-thiadiazoles as stabilizing and antifogging agents, and to methods of producing photographic emulsions containing them.
- mercapto-1,-2,4-thiadiazoles are eminently suitable as antifoggants or stabilizers for light-sensitive silver halide emulsions and, furthermore, are capable of performing their function without seriously affecting the speed and/or contrast of the emulsion with which they are associated,
- mercapto-l,2,4-thiadiazoles the use of'which is contemplated herein as stabilizers or antifoggants, may be represented by the following structural formula:
- R is hydroxy, alkoxy such as methoxy, ethoxy, propoxy, butoxy, amoxy, hexoxy, heptoxy, octoxy, nonoxy, decoxy, undecoxy, etc.; -NR R wherein R and R represent hydrogen, alkyl, e.g., methyl, ethyl, n-propyl, n-butyl, iso-butyl, n-amyl, n-hexyl, n-heptyl, n-octyl, nnonyl, n-decyL- n-undecyl, and together, R and.R can complete a heterocyclic ring system such as morpholine, piperidine, pyr-rolidine, etc.; carboxy lower alkyl, e.g., carboxymethyl, carboxyethyl, carboxypropyl, etc., and the salts and esters thereof; sulfo lower alkyl
- the mercapto-1,2,-4-thiadiazoles of the-type employed herein may be prepared according .to methods described by J. Goerdeler, 'H. Groschoti and U. Sommerlad in Ber., 90,-pp. 182 -187 (1957), and Ber., 90, pp. 892-901 (1957).
- these methods comprisereacting ,an amidine hydrohalide salt or a thiuronium salt with perchloromethylmercaptan in the presence of sodium hydroxide to produce a -chloro-1,2,4-thiadiazole which, in turn, can be reacted with a wide variety of reagents and transformed into the numerous thiadiazole compounds previously listed.
- 5-hydroxy-1,2,4-thiadiazole can be readily produced by acid hydrolysis of the corresponding 5-chloro base.
- the S-hydroxy and 5-mercapto derivatives can be further transformed by methods well-known in the art into their corresponding ethers and thioethers. If it is desired to produce carboxyalkylmercapto derivatives, these may be obtained by refluxing the 5-mercapto-1,2,4-thiadiazole with prerequisite halo fatty acid in the presence of sodium hydroxide. The so obtained carboxyalkylmercapto-1,2,4thiadiazole can then be converted into the ester, if so desired, or into an alkali metal or ammonium salt.
- the aforementioned compounds are effective in reducing the fog of silver halide photographic emulsions and may be added or contacted with the emulsion at any stage during its processing. (Thus, they may be added as ripening finals or as coating finals. Ripening finals are added during the ripening or sensitivity increasing stage of the emulsion-making process and such addition may be made before, during or after the addition of the soluble silver salt to the soluble halide in the presence of a suitable colloid such as gelatin, polyvinyl alcohol, solubilized casein, albumin, or the like.
- the compounds of the present invention are combined with the emulsion just prior to coating and when maximum sensitivity has almost been attained. Such emulsions are coated on the usual supports familiar to the art as exemplified by glass, paper or film.
- the antifogging and stabilizing compounds in separate layers adjacent to the emulsion as, for example, in a separate undercoating layer or in the anti-abrasion gelatin surface.
- the desired result may best be achieved by adding the antifoggant and stabilizer to one or all of the processing baths for the involved emulsion.
- the thiadiazoles of our invention are advantageously used in concentrations ranging from 0.1 mg. to 5 mg. per 0.4 mole of silver halide. In the case of coating finals, the concentrations range from 0.5 mg. to 50 mg. per 0.4 mole of silver halide. Since the concentration depends primarily on the type of emulsion employed, it is advisable to determine the optimum quantities of antifoggant or stabilizer in each instance. 7
- thiadiazoles of the present invention are used in combination with known antifoggants and stabilizers.
- emulsion adjuncts namely, sulfur sensitizers, metal and reduction sensitizers, accelerators such as the polyoxyethylenes and their derivatives, are compatible with the aforesaid thiadiazoles.
- non-sensitized orthochromatic, panchromatic and X-ray emulsions, paper emulsions and color emulsions are typical.
- Example IA silver halide emulsion in gelatin was prepared in a conventional manner and brought up to its maximum light-sensitivity.
- the silver halide used to form the emulsion consisted of 2% silver iodide and 98% silver bromide.
- the emulsion was then prepared for coating, after which the finals such as sensitizing dyes and hardening agents were added.
- a 0.10% methyl alcoholic solution of 5-mercapto-3-methyl-1,2,4-thiadiazole was prepared and added in varying amounts to samples of the emulsion as antifoggant and stabilizer. Each sample contained about 0.4 mole of silver halide.
- the so prepared emulsion samples were each coated on a suitable cellulose ester such as cellulose triacetate base and dried. These coated film samples were then exposed in a type 113 Sensitometer and developed in a developer of the following composition:
- Example II This example'was carried out in a manner similar to Example I except that a conventional antifoggant and stabilizer was present in the emulsion, in addition to the 5-mercapto-3-methyl-1,2,4-thiadiazole of the antifoggant of the preceding example.
- the results obtained were as follows:
- Example V The procedure of Example I was repeated excepting that the stabilizer in this case was S-mercapto-3-phenyl- 1,2,4-thiadiazole.
- the preparation of the thiadiazole is given in Ben, 90, 182-187 (1957).
- Example VI The procedure was the same as in Example I except that the stabilizer, as used therein, was replaced by S-carboxymethyl-3-ethylmercapto-1,2,4-thiadiazole.
- Example VIII The procedure was the same as in Example I except that the stabilizer, as used therein, was replaced by S-mercapto-3-phenyl-1,2,4-thiadiazole.
- Example IX The procedure was the same as given in Example I except that 5-heptylmercapto-3-cyclohexyl-1,2,4-thiadiazole was substituted for the stabilizer of said Example I.
- Example X The same procedure was followed as outlined in Example I except that the antifoggant in this instance was 5-diethylamino-3-methylmercapto-1,2,4-thiadiazole.
- Example Xl In this example, -diethylamino-3-methylmercapto-l,2, 4-thiadiazole was also used as the antifoggant except that 6 the photographic emulsion consisted of 2% silver iodide and 98% silver bromide. The results are presented in table form below. i
- R is selected from the class consisting of an alkoxy group of from 1 to 11 carbon atoms, a hydroxy group, a carboxy lower alkyl group and the alkali metal, ammonium and silver salts and lower alkyl esters thereof, a sulfo lower alkyl group and the alkali metal and ammonium salts thereof, an -SR grouping wherein R is selected from the class consisting of hydrogen, an alkyl group of from 1 to 11 carbon atoms and a carboxy lower alkyl group and the alkali metal and ammonium salts and lower alkyl esters thereof, a radical of the formula -NR R wherein R and R are each selected from the class consisting of an alkyl group of from 1 to 10 carbon atoms and taken together can complete a heterocyclic
- a light-sensitive photographic material comprising a base and a light-sensitive silver halide emulsion carried thereby, said photographic material containing, in fog inhibiting amounts, the compound of the formula:
- a light-sensitive photographic material comprising a base and a light-sensitive silver halide emulsion carried thereby, said photographic material containing, in fog inhibiting amounts, a compound of the formula:
- N o-somooon 7 6.
- the process of reducing and'minimizing fog in lightsensitive silver halide materials comprising a base having a light-sensitive silver halide emulsion thereon which com prises exposing said emuslion and developing the same in the presence of a compound of. the following general formula:
- R is selected from the class consisting of an alkoxy group of from 1 to 11f carbon atoms, a hydroxy group, a carboxy lower alkyl group and the alkali metal, ammonium and silver salts and lower alkyl esters thereof, a sulfo lower alkyl group andathe alkalimetal and-ammonium salts thereof, an SR grouping wherein R is selected fi'omtthe class consisting of hydrogen, an alkyl group of from 1 to 11 carbon atoms and a carboxy lower alkyl group and the alkali metal and ammonium salts and lower alkyl esters thereof, a radical of the formula -NR R wherein R and R are each selected from the class consisting of an alkyl group of from 1 to 10 carbon atoms and taken together can complete a heterocyclic ring selected from the class consisting of morpholine, piperidine, and pyrrolidine; R is selected from the class consisting of an alkyl group of from 1 to 8 carbon atoms
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Description
United States Patent ()1 W 3,051,570 Patented Aug. 28, 1962.
"ice
3,051,570 ANTIFOGGANTS AND STABILIZERS FOR PHGTO- GRAPHIC SILVER HALIDE EMULSIONS Fritz Dersch, Frank J. Kaszuba, and Emil B. Ranch, Binghamton, N.Y., assignors to General Aniline & Film' Corporation, New York, N.Y., a corporation of Delaware No Drawing. Filed Oct. 1, 1958, Ser. No. 764,529 8 Claims. (Cl. 9667) This invention relates to the stabilization of photographic materials. More particularly, this invention relates to light-sensitive photographic silver halide emulsions containing mercapto-1,2,4-thiadiazoles as stabilizing and antifogging agents, and to methods of producing photographic emulsions containing them.
It is well-known in the photographic art that lightsensitive emulsions such as gelatin-silver halide emulsions have a tendency to fog. Conditions under which fogging occurs are: prolonged ripening of the emulsions, storage over prolonged periods of time especially under conditions of elevated temperature and humidity, and by prolonged developing. These troublesome properties of photographic emulsions have long harassed the art and numerous. remedies havebeen proposed to overcome them. Thus, it is the practice to add certain chemical compounds such as benzimidazole and its derivatives, particularly 2- merc-aptobenzimidazole, to-photographic emulsions to increase their stability and reduce their tendency to fog. However, such compounds, referred to in the art as stabilizing and/or antifogging agents, as used heretofore, have the disadvantage that upon addition to the emulsion an excessive loss of speed and/ or contrast of the emulsion occurs as an undesirable side reaction. 7
It has now been discovered that mercapto-1,-2,4-thiadiazoles are eminently suitable as antifoggants or stabilizers for light-sensitive silver halide emulsions and, furthermore, are capable of performing their function without seriously affecting the speed and/or contrast of the emulsion with which they are associated,
The use of the aforesaid compounds to inhibit fog and to stabilize silver halide emulsions, either by incorporating the same in the emulsion or in layers adjacent thereto or in processing baths for such emulsions, constitutes the purposes and objects of the present invention.
The mercapto-l,2,4-thiadiazoles, the use of'which is contemplated herein as stabilizers or antifoggants, may be represented by the following structural formula:
wherein R is hydroxy, alkoxy such as methoxy, ethoxy, propoxy, butoxy, amoxy, hexoxy, heptoxy, octoxy, nonoxy, decoxy, undecoxy, etc.; -NR R wherein R and R represent hydrogen, alkyl, e.g., methyl, ethyl, n-propyl, n-butyl, iso-butyl, n-amyl, n-hexyl, n-heptyl, n-octyl, nnonyl, n-decyL- n-undecyl, and together, R and.R can complete a heterocyclic ring system such as morpholine, piperidine, pyr-rolidine, etc.; carboxy lower alkyl, e.g., carboxymethyl, carboxyethyl, carboxypropyl, etc., and the salts and esters thereof; sulfo lower alkyl, e.g., sulfomethyl, sulfoethyl, e'tc., and the salts and esters thereof; a mercapto group, alkylmercapto, e.g., methyl'mercapto, ethylmercapto, n-propylmercapto, n-butylmercapto,1 namylmercapto, n-hexylmercapto, n-heptylmercapto, noctylmercapto, n-nonylmercapto, n-hexylmercapto, nundecylmercapto, etc.; carboxy lower alkylrnercapto, e.g., carboxym'ethylmercapto, carboxyethylmercapto, carboxypropylmercapto, etc., and the salts and esters thereof, and R is alkyl as above for R and R arloweralkyl, e.g.,
benzyl, phenethyl, naphth-yL- naphthylmethyl, naphthylethyl, etc. an aryl group of the benzene and naphthalene series, alkylmercapto as above for R,-at least one of said R and R always being a mercapto group.
Examples of compounds which fall within the scope of the above formula'and which are effective as antifoggants or stabilizers are typified in the following formulae:
The mercapto-1,2,-4-thiadiazoles of the-type employed herein may be prepared according .to methods described by J. Goerdeler, 'H. Groschoti and U. Sommerlad in Ber., 90,-pp. 182 -187 (1957), and Ber., 90, pp. 892-901 (1957). In general, these methods comprisereacting ,an amidine hydrohalide salt or a thiuronium salt with perchloromethylmercaptan in the presence of sodium hydroxide to produce a -chloro-1,2,4-thiadiazole which, in turn, can be reacted with a wide variety of reagents and transformed into the numerous thiadiazole compounds previously listed. 4 Thus, 5-hydroxy-1,2,4-thiadiazole can be readily produced by acid hydrolysis of the corresponding 5-chloro base. Treatment of the S-chlorothiadiazole with thiourea in the presence of base, yields the corresponding S-mercapto derivative, whereas reaction with amines produces a 5-amino-1,2,4-thiadiazole. The S-hydroxy and 5-mercapto derivatives can be further transformed by methods well-known in the art into their corresponding ethers and thioethers. If it is desired to produce carboxyalkylmercapto derivatives, these may be obtained by refluxing the 5-mercapto-1,2,4-thiadiazole with prerequisite halo fatty acid in the presence of sodium hydroxide. The so obtained carboxyalkylmercapto-1,2,4thiadiazole can then be converted into the ester, if so desired, or into an alkali metal or ammonium salt.
The aforementioned compounds are effective in reducing the fog of silver halide photographic emulsions and may be added or contacted with the emulsion at any stage during its processing. (Thus, they may be added as ripening finals or as coating finals. Ripening finals are added during the ripening or sensitivity increasing stage of the emulsion-making process and such addition may be made before, during or after the addition of the soluble silver salt to the soluble halide in the presence of a suitable colloid such as gelatin, polyvinyl alcohol, solubilized casein, albumin, or the like. When added as coating finals, the compounds of the present invention are combined with the emulsion just prior to coating and when maximum sensitivity has almost been attained. Such emulsions are coated on the usual supports familiar to the art as exemplified by glass, paper or film.
In some instances, it is advantageous to apply the antifogging and stabilizing compounds in separate layers adjacent to the emulsion as, for example, in a separate undercoating layer or in the anti-abrasion gelatin surface. In other instances, the desired result may best be achieved by adding the antifoggant and stabilizer to one or all of the processing baths for the involved emulsion.
When used as ripening finals, the thiadiazoles of our invention are advantageously used in concentrations ranging from 0.1 mg. to 5 mg. per 0.4 mole of silver halide. In the case of coating finals, the concentrations range from 0.5 mg. to 50 mg. per 0.4 mole of silver halide. Since the concentration depends primarily on the type of emulsion employed, it is advisable to determine the optimum quantities of antifoggant or stabilizer in each instance. 7
Especially good results are obtained when the thiadiazoles of the present invention are used in combination with known antifoggants and stabilizers. Other emulsion adjuncts, namely, sulfur sensitizers, metal and reduction sensitizers, accelerators such as the polyoxyethylenes and their derivatives, are compatible with the aforesaid thiadiazoles.
Of the various types of emulsionswhich can be stabilized with the antifoggants and stabilizers of our invention, non-sensitized orthochromatic, panchromatic and X-ray emulsions, paper emulsions and color emulsions are typical.
The invention is illustrated in greater detail by the following examples but it is to be understood that the invention 'is not restricted thereto.
Example I IA silver halide emulsion in gelatin was prepared in a conventional manner and brought up to its maximum light-sensitivity. The silver halide used to form the emulsion consisted of 2% silver iodide and 98% silver bromide. The emulsion was then prepared for coating, after which the finals such as sensitizing dyes and hardening agents were added. A 0.10% methyl alcoholic solution of 5-mercapto-3-methyl-1,2,4-thiadiazole was prepared and added in varying amounts to samples of the emulsion as antifoggant and stabilizer. Each sample contained about 0.4 mole of silver halide. The so prepared emulsion samples were each coated on a suitable cellulose ester such as cellulose triacetate base and dried. These coated film samples were then exposed in a type 113 Sensitometer and developed in a developer of the following composition:
Metol 1.5 Sodium sulfite, anhydrous 45.0 Sodium bisulfi 1.0 Hydroquinone 3.0 Sodium carbonate, monohydrated 6.0 Potassium bromid 0.8
Water to make 1.0 liter.
The results obtained were as follows:
Quantity of Relative Fog at 12 Oven Fog Antiioggant Speed at 3 Minute Deat 6 Compound Minute Development Minute De- Added, mg. velopment velopment The 5-mercapto-3-methyl-1,2,4-thiadiazole was prepared according to the procedure given in Ben, 90, 186 (1957).
Example II This example'was carried out in a manner similar to Example I except that a conventional antifoggant and stabilizer was present in the emulsion, in addition to the 5-mercapto-3-methyl-1,2,4-thiadiazole of the antifoggant of the preceding example. The results obtained were as follows:
Relative Speed at 3 Minute Development Quantity of Antifoggant Compound Added, mg.
Fog at 12 Minute Development Oven Fog at 6 Minute Development Example 111 In'this example, a similar procedure and a similar emulsion was used as in Examples 1 and H. However, 5-carboxymethylmercapto-3-methyl-1,2,4-thiadiazole was substituted for the 5-mercapto-3-methyl-1,2,4-thiadiazole of the two preceding examples. A conventional antifogging agent was also used, as in Example II, together with the antifogging agent of our invention. The results obtained were as follows:
Quantity of Relative Fog at 12 Oven Fog Antifoggant Speed at 3 Minute Deat 6 Compound Minute Development Minute De- Added, mg. veiopment velopment Several samples of conventional photographic film were exposed in a Type IIB Sensitometer and then divided into two groups. One group of samples was developed for twelve minutes at 65 F. in a standard metol-hydroquinone developer. The other group of samples was developed for the same length of time and at the same temperature as the first group in a standard metol-hydroquinone developer to which has been added 20 mg. of 5-mercapto-3-methyl-1,2,4-thiadiazole per liter of developer. It was found that the samples developed in the standard developer showed a fog of .30, whereas the samples developed in the developer containing the novel antifogging agent of our invention showed a fog of .20.
Example V The procedure of Example I was repeated excepting that the stabilizer in this case was S-mercapto-3-phenyl- 1,2,4-thiadiazole. The preparation of the thiadiazole is given in Ben, 90, 182-187 (1957).
Example VI The procedure was the same as in Example I except that the stabilizer, as used therein, was replaced by S-carboxymethyl-3-ethylmercapto-1,2,4-thiadiazole.
The latter compound was prepared by reacting S-chloro-3-mercaptol,2,4-thiadiazole with malonic ester in the presence of alkali followed by acid hydrolysis. This procedure is given in the previously cited Berichte references.
Example VIII The procedure was the same as in Example I except that the stabilizer, as used therein, was replaced by S-mercapto-3-phenyl-1,2,4-thiadiazole.
The latter compound was prepared from the method disclosed in the above Berichte references.
Example IX The procedure was the same as given in Example I except that 5-heptylmercapto-3-cyclohexyl-1,2,4-thiadiazole was substituted for the stabilizer of said Example I.
Example X The same procedure was followed as outlined in Example I except that the antifoggant in this instance was 5-diethylamino-3-methylmercapto-1,2,4-thiadiazole.
Oven Test Quantity Relative Fog at 12 of Antifog- Speed at 4 Minute gant Gom- Minute Develop- Speed at 4 pound Development Minute Fog Added, ment Developmg. ment The photographic emulsion employed in compiling the above table is a type well-known to the art and contained 4% silver iodide and 96% silver bromide.
Example Xl In this example, -diethylamino-3-methylmercapto-l,2, 4-thiadiazole was also used as the antifoggant except that 6 the photographic emulsion consisted of 2% silver iodide and 98% silver bromide. The results are presented in table form below. i
Oven Test Quantity Relative Fog at 12 of Antifog- Speed at 3 Minute gant Oom- Minute Develop- Speed at 6 pound Development Minute Fog Added, ment Developmg. ment wherein R is selected from the class consisting of an alkoxy group of from 1 to 11 carbon atoms, a hydroxy group, a carboxy lower alkyl group and the alkali metal, ammonium and silver salts and lower alkyl esters thereof, a sulfo lower alkyl group and the alkali metal and ammonium salts thereof, an -SR grouping wherein R is selected from the class consisting of hydrogen, an alkyl group of from 1 to 11 carbon atoms and a carboxy lower alkyl group and the alkali metal and ammonium salts and lower alkyl esters thereof, a radical of the formula -NR R wherein R and R are each selected from the class consisting of an alkyl group of from 1 to 10 carbon atoms and taken together can complete a heterocyclic ring selected from the class consisting of morpholine, piperidine and pyrrolidine; R is selected from the class consisting of an alkyl group of from 1 to 8 carbon atoms, an -SR grouping wherein R is selected from the class consisting of hydrogen, an alkyl group of from 1 to 11 carbon atoms and a carboxy lower alkyl group and the alkali metal and ammonium salts and the lower alkyl esters thereof, an aralkyl group of the benzene and naphthalene series wherein the alkyl chain contains from 1 to 2 carbon atoms and at least one of said R and R always being a --SR grouping.
2. The product as defined in claim 1 wherein said mercapto-l,2,4-thiadiazole is located in the silver halide emulsion.
3. The product as defined in claim 1 wherein said mercapto-l,2,4-thiadiazole is located in a layer adjacent to said silver halide emulsion layer.
4. A light-sensitive photographic material comprising a base and a light-sensitive silver halide emulsion carried thereby, said photographic material containing, in fog inhibiting amounts, the compound of the formula:
5. A light-sensitive photographic material comprising a base and a light-sensitive silver halide emulsion carried thereby, said photographic material containing, in fog inhibiting amounts, a compound of the formula:
N o-somooon 7 6. The process of reducing and'minimizing fog in lightsensitive silver halide materials comprising a base having a light-sensitive silver halide emulsion thereon which com prises exposing said emuslion and developing the same in the presence of a compound of. the following general formula:
wherein R is selected from the class consisting of an alkoxy group of from 1 to 11f carbon atoms, a hydroxy group, a carboxy lower alkyl group and the alkali metal, ammonium and silver salts and lower alkyl esters thereof, a sulfo lower alkyl group andathe alkalimetal and-ammonium salts thereof, an SR grouping wherein R is selected fi'omtthe class consisting of hydrogen, an alkyl group of from 1 to 11 carbon atoms and a carboxy lower alkyl group and the alkali metal and ammonium salts and lower alkyl esters thereof, a radical of the formula -NR R wherein R and R are each selected from the class consisting of an alkyl group of from 1 to 10 carbon atoms and taken together can complete a heterocyclic ring selected from the class consisting of morpholine, piperidine, and pyrrolidine; R is selected from the class consisting of an alkyl group of from 1 to 8 carbon atoms, an -SR grouping wherein R is selected from the class consisting of hydrogen, an alkyl group of from 1 to 11 carbon atoms and a carboxy lower alkyl group and the alkali metal and ammonium salts and the lower alkyl esters thereof, an aralkyl group of the benzene and naphthalene series wherein the alkyl chain contains from 1 to 2 carbon atoms and at least one of said R and R always being a SR grouping. e
7. The process as defined in claim 6 wherein theantifoggant is a compound of the-following formula? 'HCG'N- 'iLsomoo'on i 8. The process as definedin claim 6 wherein the anti foggant is a compound of the following formula:
4 mosi mr N\ :/C- N(CzHr)2 S a Reterences Cited in the file of this'patent UNITED STATES PATENTS 2,226,183 Staud et al. Dec. 24, 1940 2,285,410 Bousquet et a1. June 9, 1942 2,453,346 Russell -a Nov. 9, 1948 2,819,965 Murray et al. Jan. 14, 1958 r 2,824,001 Allen et a1. Feb. 18', 1958 2,843,491 Allen et al July 15, 1958
Claims (2)
1. A PHOTOGRAPHIC MATERIAL COMPRISING A BASE AND A LIGHT-SENSITIVE SILVER HALIDE EMULSION CARRIED THEREBY, SAID PHOTOGRAPHIC MATERIAL CONTAINING, IN FOG INHIBITING AMOUNT, A MERCAPTO-1,2,4-THIADIAZOLE OF THE FOLLOWING GENERAL FORMULA:
3. THE PRODUCT AS DEFINED IN CLAIM 1 WHEREIN SAID MERCAPTO-1,2,4-THIADIAZOLE IS LOCATED IN A LAYER ADJACENT TO SAID SILVER HALIDE EMULSION LAYER.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3334995A (en) * | 1961-07-31 | 1967-08-08 | Minnesota Mining & Mfg | Process of precipitating silver |
US3362826A (en) * | 1963-04-27 | 1968-01-09 | Agfa Ag | Photographic paper containing yellow fog-preventing agents |
US3365294A (en) * | 1963-04-27 | 1968-01-23 | Agfa Ag | Photographic material containing yellow fog-preventing agents |
DE1622259A1 (en) * | 1967-02-15 | 1970-10-29 | Agfa Gevaert Ag | Photographic material |
US3650760A (en) * | 1969-09-17 | 1972-03-21 | Eastman Kodak Co | Alkoxy mercaptophenols as photographic addenda for photographic elements |
USRE29439E (en) * | 1969-10-18 | 1977-10-11 | Fisons Limited | Certain 1,2,4-Oxa- and -thiadiazol-5-ylthioalkanoic acid derivatives |
US4689286A (en) * | 1985-04-19 | 1987-08-25 | Agfa Gevaert Aktiengesellschaft | Color photographic recording material developable by heat treatment |
US5478721A (en) * | 1995-01-31 | 1995-12-26 | Eastman Kodak Company | Photographic elements containing emulsion stabilizers |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2226183A (en) * | 1939-12-27 | 1940-12-24 | Eastman Kodak Co | Mold inhibitor for photographic elements |
US2285410A (en) * | 1941-02-27 | 1942-06-09 | Du Pont | Pest control |
US2453346A (en) * | 1945-10-25 | 1948-11-09 | Eastman Kodak Co | Stabilization of processed photographic emulsions to high temperatures and humidities |
US2819965A (en) * | 1956-02-23 | 1958-01-14 | Eastman Kodak Co | Carboxymethylmercapto compounds as stabilizers for photographic emulsions |
US2824001A (en) * | 1956-01-16 | 1958-02-18 | Eastman Kodak Co | Stabilized photographic silver halide emulsions |
US2843491A (en) * | 1956-05-23 | 1958-07-15 | Eastman Kodak Co | 2-mercapto-1, 3, 4-oxadiazoles as antifoggants |
-
1958
- 1958-10-01 US US764529A patent/US3051570A/en not_active Expired - Lifetime
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2226183A (en) * | 1939-12-27 | 1940-12-24 | Eastman Kodak Co | Mold inhibitor for photographic elements |
US2285410A (en) * | 1941-02-27 | 1942-06-09 | Du Pont | Pest control |
US2453346A (en) * | 1945-10-25 | 1948-11-09 | Eastman Kodak Co | Stabilization of processed photographic emulsions to high temperatures and humidities |
US2824001A (en) * | 1956-01-16 | 1958-02-18 | Eastman Kodak Co | Stabilized photographic silver halide emulsions |
US2819965A (en) * | 1956-02-23 | 1958-01-14 | Eastman Kodak Co | Carboxymethylmercapto compounds as stabilizers for photographic emulsions |
US2843491A (en) * | 1956-05-23 | 1958-07-15 | Eastman Kodak Co | 2-mercapto-1, 3, 4-oxadiazoles as antifoggants |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3334995A (en) * | 1961-07-31 | 1967-08-08 | Minnesota Mining & Mfg | Process of precipitating silver |
US3362826A (en) * | 1963-04-27 | 1968-01-09 | Agfa Ag | Photographic paper containing yellow fog-preventing agents |
US3365294A (en) * | 1963-04-27 | 1968-01-23 | Agfa Ag | Photographic material containing yellow fog-preventing agents |
DE1622259A1 (en) * | 1967-02-15 | 1970-10-29 | Agfa Gevaert Ag | Photographic material |
US3650760A (en) * | 1969-09-17 | 1972-03-21 | Eastman Kodak Co | Alkoxy mercaptophenols as photographic addenda for photographic elements |
USRE29439E (en) * | 1969-10-18 | 1977-10-11 | Fisons Limited | Certain 1,2,4-Oxa- and -thiadiazol-5-ylthioalkanoic acid derivatives |
US4689286A (en) * | 1985-04-19 | 1987-08-25 | Agfa Gevaert Aktiengesellschaft | Color photographic recording material developable by heat treatment |
US5478721A (en) * | 1995-01-31 | 1995-12-26 | Eastman Kodak Company | Photographic elements containing emulsion stabilizers |
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