GB1287327A - A catalyst for use in the production of methanol, its production and use - Google Patents
A catalyst for use in the production of methanol, its production and useInfo
- Publication number
- GB1287327A GB1287327A GB28680/70A GB2868070A GB1287327A GB 1287327 A GB1287327 A GB 1287327A GB 28680/70 A GB28680/70 A GB 28680/70A GB 2868070 A GB2868070 A GB 2868070A GB 1287327 A GB1287327 A GB 1287327A
- Authority
- GB
- United Kingdom
- Prior art keywords
- manganese
- zinc
- copper
- constitutes
- precipitate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 9
- 239000003054 catalyst Substances 0.000 title abstract 7
- 239000002244 precipitate Substances 0.000 abstract 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- 239000010949 copper Substances 0.000 abstract 4
- 229910052802 copper Inorganic materials 0.000 abstract 4
- 239000011701 zinc Substances 0.000 abstract 4
- 229910052725 zinc Inorganic materials 0.000 abstract 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 3
- 229910052748 manganese Inorganic materials 0.000 abstract 3
- 239000011572 manganese Substances 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000002156 mixing Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002823 nitrates Chemical class 0.000 abstract 2
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 2
- 238000005406 washing Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Lead Frames For Integrated Circuits (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1287327 Catalysts for methanol synthesis METALLGESELLSCHAFT AG 12 June 1970 [18 June 1969] 28680/70 Heading B1E [Also in Divisions C2 and C5] A catalyst for use in the synthesis of methanol from a gas mixture comprising hydrogen, carbon monoxide and carbon dioxide comprises (a) copper, (b) vanadium and (c) zinc and/or manganese, which metals are present in oxide form and in relative proportions such that, of the total number of atoms of such metals, copper constitutes 30 to 80 per cent, vanadium constitutes 1 to 25 per cent, and zinc constitutes 10 to 50 per cent and/or manganese constitutes 10 to 50 per cent. The catalyst may be prepared either by mixing an aqueous solution containing nitrates of copper and of zinc and/or manganese with an aqueous solution containing sodium carbonate and sodium metavanadate, separating the resulting precipitate and subjecting the precipitate to washing with water until free from alkali metal, drying and calcining at 300-500C or by mixing an aqueous solution containing nitrates of copper and of zinc and/or manganese with an aqueous solution of sodium carbonate, separating the resulting precipitate, washing the precipitate with water until free from alkali metal, kneading the washed precipitate with vanadium pentoxide and subjecting the resulting mixture to drying and calcining at 300-500C. Exemplified catalysts contain, in atom percentages, 60Cu-10V-30Zn (Example 1), 50Cu-20V-30Mn (Example 2) and 60Cu-10V-20Zn-10Mn (Example 4), the catalyst of Example 1 being prepared by the former method and thereafter being compacted into 4x4 mm tablets and the catalysts of Examples 2 and 4 being prepared by the latter method.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1930702A DE1930702C3 (en) | 1969-06-18 | 1969-06-18 | Process for the production of methanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1287327A true GB1287327A (en) | 1972-08-31 |
Family
ID=5737223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28680/70A Expired GB1287327A (en) | 1969-06-18 | 1970-06-12 | A catalyst for use in the production of methanol, its production and use |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS4943924B1 (en) |
| AT (2) | AT300745B (en) |
| BE (1) | BE752180A (en) |
| CS (2) | CS164272B2 (en) |
| DE (1) | DE1930702C3 (en) |
| ES (1) | ES380718A1 (en) |
| FI (1) | FI51585C (en) |
| FR (1) | FR2049193B1 (en) |
| GB (1) | GB1287327A (en) |
| NL (1) | NL169726B (en) |
| NO (1) | NO128368B (en) |
| RO (1) | RO56266A (en) |
| SE (1) | SE367391B (en) |
| ZA (1) | ZA703546B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020058822A1 (en) * | 2018-09-17 | 2020-03-26 | Sabic Global Technologies B.V. | Catalysts for producing alcohols and ethers from synthesis gas |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3805407A1 (en) * | 1988-02-22 | 1989-08-31 | Draegerwerk Ag | Chemisorption composition for breathing apparatuses |
| DE69123432D1 (en) * | 1990-09-18 | 1997-01-16 | Csir | Catalyst for methanol synthesis |
-
1969
- 1969-06-18 DE DE1930702A patent/DE1930702C3/en not_active Expired
-
1970
- 1970-05-25 ZA ZA703546A patent/ZA703546B/en unknown
- 1970-05-26 AT AT473270A patent/AT300745B/en not_active IP Right Cessation
- 1970-05-26 AT AT640671A patent/AT305218B/en not_active IP Right Cessation
- 1970-05-27 RO RO63459A patent/RO56266A/ro unknown
- 1970-06-05 FR FR707020800A patent/FR2049193B1/fr not_active Expired
- 1970-06-10 FI FI701649A patent/FI51585C/en active
- 1970-06-10 NL NLAANVRAGE7008476,A patent/NL169726B/en not_active Application Discontinuation
- 1970-06-12 GB GB28680/70A patent/GB1287327A/en not_active Expired
- 1970-06-12 CS CS4155A patent/CS164272B2/cs unknown
- 1970-06-12 CS CS2926*[A patent/CS164273B2/cs unknown
- 1970-06-12 ES ES380718A patent/ES380718A1/en not_active Expired
- 1970-06-13 JP JP45051468A patent/JPS4943924B1/ja active Pending
- 1970-06-16 NO NO02332/70A patent/NO128368B/no unknown
- 1970-06-17 SE SE08406/70A patent/SE367391B/xx unknown
- 1970-06-18 BE BE752180D patent/BE752180A/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020058822A1 (en) * | 2018-09-17 | 2020-03-26 | Sabic Global Technologies B.V. | Catalysts for producing alcohols and ethers from synthesis gas |
| CN112672823A (en) * | 2018-09-17 | 2021-04-16 | 沙特基础工业全球技术公司 | Catalyst for producing alcohols and ethers from synthesis gas |
Also Published As
| Publication number | Publication date |
|---|---|
| CS164272B2 (en) | 1975-11-07 |
| DE1930702B2 (en) | 1974-04-18 |
| NL7008476A (en) | 1970-12-22 |
| BE752180A (en) | 1970-12-01 |
| FR2049193A1 (en) | 1971-03-26 |
| SE367391B (en) | 1974-05-27 |
| FI51585B (en) | 1976-11-01 |
| AT305218B (en) | 1973-02-12 |
| AT300745B (en) | 1972-08-10 |
| ZA703546B (en) | 1971-01-27 |
| DE1930702C3 (en) | 1974-11-28 |
| NL169726B (en) | 1982-03-16 |
| NO128368B (en) | 1973-11-05 |
| CS164273B2 (en) | 1975-11-07 |
| RO56266A (en) | 1974-04-01 |
| DE1930702A1 (en) | 1971-01-07 |
| ES380718A1 (en) | 1972-08-16 |
| FI51585C (en) | 1977-02-10 |
| FR2049193B1 (en) | 1973-04-06 |
| JPS4943924B1 (en) | 1974-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |