GB1366367A - Methanol synthesis catalysts - Google Patents

Methanol synthesis catalysts

Info

Publication number
GB1366367A
GB1366367A GB5334171A GB5334171A GB1366367A GB 1366367 A GB1366367 A GB 1366367A GB 5334171 A GB5334171 A GB 5334171A GB 5334171 A GB5334171 A GB 5334171A GB 1366367 A GB1366367 A GB 1366367A
Authority
GB
United Kingdom
Prior art keywords
methanol synthesis
mixed crystal
nov
reduced
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5334171A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1366367A publication Critical patent/GB1366367A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1366367 Methanol synthesis catalyst BADISCHE ANILIN- & SODA-FABRIK AG 17 Nov 1971 [18 Nov 1970] 53341/71 Heading BIE [Also in Divisions Cl and C2] A catalyst for the methanol synthesis (see Division C2) is prepared by precipitating at a pH of 4.5-5.5 a compound of the mixed crystal series (Cu x Zn v ) Al 2 (OH) 16 .CO 3 .4H 2 O wherein x and y are numbers from 0.5 to 5.5 such that x+y=6, with an alkali metal carbonate and/or bicarbonate from an aqueous solution containing salts,' e.g. nitrates of Cu, Zn and Al in relative proportions sufficient to form the mixed crystal compound which is thereafter calcined, e.g. at 200‹-500‹C, and reduced, e.g. with a mixture of H 2 and N 2 at 150-350‹C. A continuous precipitation procedure is described. Examples describe the precipitation of the mixed crystal compounds (1) CuZn 5 Al 2 (OH) 16 CO 3 .4.H 2 O, (2) Cu 2 Zn 4 Al 2 (OH) 16 CO 3 .4H 2 O and (6) Cu 3 Zn 3 Al 2 (OH) 16 CO 3 . 4H 2 O which are dried, calcined, pelleted, may be with graphite, and then reduced. Specification 1,159,035 is referred to.
GB5334171A 1970-11-18 1971-11-17 Methanol synthesis catalysts Expired GB1366367A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2056612A DE2056612C3 (en) 1970-11-18 1970-11-18 Process for the production of methanol

Publications (1)

Publication Number Publication Date
GB1366367A true GB1366367A (en) 1974-09-11

Family

ID=5788398

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5334171A Expired GB1366367A (en) 1970-11-18 1971-11-17 Methanol synthesis catalysts

Country Status (6)

Country Link
JP (1) JPS5521728B1 (en)
DE (1) DE2056612C3 (en)
FR (1) FR2114792A5 (en)
GB (1) GB1366367A (en)
IT (1) IT944852B (en)
NL (1) NL172052C (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4393144A (en) * 1978-09-20 1983-07-12 Sagami Chemical Research Center Method for producing methanol
US5302569A (en) * 1991-08-17 1994-04-12 Hoechst Aktiengesellschaft Copper/zinc oxide/aluminum oxide-containing catalysts
US6936237B2 (en) 1999-08-17 2005-08-30 Battelle Memorial Institute Reforming catalysts and methods of alcohol steam reforming
US7754651B2 (en) 2001-12-08 2010-07-13 Süd -Chemie AG Cu/Zn/Al catalyst for methanol synthesis
US7820128B2 (en) 2005-05-03 2010-10-26 Sud-Chemie Ag Production of Cu/Zn/A1 catalysts via the formate route
NL2006535C2 (en) * 2011-04-04 2012-10-08 Btg Biomass Technology Group B V Method for the manufacture of methanol.
WO2013072197A1 (en) * 2011-11-16 2013-05-23 Süd-Chemie Ip Gmbh & Co. Kg Methanol synthesis catalyst on the basis of copper, zinc and aluminum
US10035137B2 (en) 2012-09-28 2018-07-31 Clariant International Ltd. Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material
US10226760B2 (en) 2014-03-26 2019-03-12 Clariant International Ltd. Hydrogenation catalyst and method for producing same
US11993519B2 (en) 2017-03-06 2024-05-28 Oxford University Innovation Limited Layered double hydroxide precursor, their preparation process and catalysts prepared therefrom

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2846614C3 (en) * 1978-10-26 1982-05-19 Basf Ag, 6700 Ludwigshafen Process for the production of methanol
DE3005551A1 (en) * 1980-02-14 1981-08-20 Süd-Chemie AG, 8000 München CATALYST FOR THE SYNTHESIS OF METHANOL AND ALCOHOL MIXTURES CONTAINING HIGHER ALCOHOLS
FR2558738B1 (en) * 1984-01-27 1987-11-13 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF CATALYSTS CONTAINING COPPER, ZINC AND ALUMINUM FOR USE IN THE PRODUCTION OF METHANOL FROM SYNTHESIS GAS
DE3403492A1 (en) * 1984-02-02 1985-08-08 Metallgesellschaft Ag, 6000 Frankfurt METHOD FOR PRODUCING A MIXTURE OF METHANOL AND HIGHER ALCOHOLS
EP0234745B1 (en) * 1986-01-29 1991-06-12 Dyson Refractories Limited Catalysts
IN170837B (en) * 1987-11-17 1992-05-30 Council Scient Ind Res
EP2599541B1 (en) * 2011-12-02 2017-05-03 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for preparing a water gas shift catalyst operating at medium temperatures
EP3305404A1 (en) 2016-10-10 2018-04-11 National Petrochemical Company Copper/zinc/aluminium catalyst for the methanol synthesis prepared from a binary zinc-aluminium precursor solution

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS545690B2 (en) * 1972-03-06 1979-03-20

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4393144A (en) * 1978-09-20 1983-07-12 Sagami Chemical Research Center Method for producing methanol
US5302569A (en) * 1991-08-17 1994-04-12 Hoechst Aktiengesellschaft Copper/zinc oxide/aluminum oxide-containing catalysts
US6936237B2 (en) 1999-08-17 2005-08-30 Battelle Memorial Institute Reforming catalysts and methods of alcohol steam reforming
US7754651B2 (en) 2001-12-08 2010-07-13 Süd -Chemie AG Cu/Zn/Al catalyst for methanol synthesis
US7820128B2 (en) 2005-05-03 2010-10-26 Sud-Chemie Ag Production of Cu/Zn/A1 catalysts via the formate route
NL2006535C2 (en) * 2011-04-04 2012-10-08 Btg Biomass Technology Group B V Method for the manufacture of methanol.
WO2013072197A1 (en) * 2011-11-16 2013-05-23 Süd-Chemie Ip Gmbh & Co. Kg Methanol synthesis catalyst on the basis of copper, zinc and aluminum
US10035137B2 (en) 2012-09-28 2018-07-31 Clariant International Ltd. Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material
US10226760B2 (en) 2014-03-26 2019-03-12 Clariant International Ltd. Hydrogenation catalyst and method for producing same
US11993519B2 (en) 2017-03-06 2024-05-28 Oxford University Innovation Limited Layered double hydroxide precursor, their preparation process and catalysts prepared therefrom

Also Published As

Publication number Publication date
NL7115455A (en) 1972-05-23
NL172052B (en) 1983-02-01
JPS5521728B1 (en) 1980-06-12
NL172052C (en) 1983-07-01
DE2056612B2 (en) 1979-01-18
FR2114792A5 (en) 1972-06-05
DE2056612A1 (en) 1972-05-31
IT944852B (en) 1973-04-20
DE2056612C3 (en) 1979-09-13

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee