GB1364096A - Process for the production of methanol and catalyst therefor - Google Patents
Process for the production of methanol and catalyst thereforInfo
- Publication number
- GB1364096A GB1364096A GB5064971A GB5064971A GB1364096A GB 1364096 A GB1364096 A GB 1364096A GB 5064971 A GB5064971 A GB 5064971A GB 5064971 A GB5064971 A GB 5064971A GB 1364096 A GB1364096 A GB 1364096A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copper
- zinc
- didymium
- oxides
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 9
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- 229910000722 Didymium Inorganic materials 0.000 abstract 3
- 241000224487 Didymium Species 0.000 abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 3
- 229910052802 copper Inorganic materials 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- 229910052725 zinc Inorganic materials 0.000 abstract 3
- 239000011701 zinc Substances 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000005453 pelletization Methods 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
1364096 Methanol synthesis catalysts SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 1 Nov 1971 [2 Nov 1970 21 May 1971] 50649/71 Heading B1E [Also in Division C2] Methanol synthesis catalyst comprising oxides of copper and of zinc and of "didymium" (defined as any rare earth metal mixture free from a substantial amount of cerium and containing at least two other rare earth metals in a naturally-occurring ratio) may be prepared by a procedure wherein copper, zinc and "didymium" are co-precipitated in the form of compounds readily convertible to oxides, for example hydroxides and/or basic carbonates and/or carbonates, from solution, for example nitrate solution, and the resulting co-precipitate is collected, washed, dried, calcined at a temperature of from 200 to 400C to convert the convertible compounds into oxides, shaped for example by pelletizing under pressure using graphite as lubricant and, optionally, treated with hydrogen or a mixture of hydrogen and carbon monoxide. The catalyst maycontain copper oxide and zinc oxide in a copper:zinc weight ratio of from 1:0.05 to 1:10 and from 1 to 25 weight per cent of "didymium" oxide, calculated as metal; the catalyst additionally may comprise inert support material, for example silica or alumina.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8635770A | 1970-11-02 | 1970-11-02 | |
| US14594671A | 1971-05-21 | 1971-05-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1364096A true GB1364096A (en) | 1974-08-21 |
Family
ID=26774660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5064971A Expired GB1364096A (en) | 1970-11-02 | 1971-11-01 | Process for the production of methanol and catalyst therefor |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5438081B1 (en) |
| AT (1) | AT313863B (en) |
| AU (1) | AU464265B2 (en) |
| BE (1) | BE774745A (en) |
| CA (1) | CA988946A (en) |
| DE (1) | DE2154074C3 (en) |
| ES (1) | ES396575A1 (en) |
| FR (1) | FR2113467A5 (en) |
| GB (1) | GB1364096A (en) |
| IT (1) | IT949513B (en) |
| NL (1) | NL7114914A (en) |
| SE (1) | SE371637B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0047345B1 (en) * | 1980-08-28 | 1983-12-07 | Theodore Oscar Wentworth | Process for the synthesis of methanol from hydrogen and the oxides of carbon using catalysts |
| ES2914350A1 (en) * | 2020-12-09 | 2022-06-09 | Blueplasma Power S L | Device and process to produce dimethyl carbonate (Machine-translation by Google Translate, not legally binding) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2441420A1 (en) * | 1978-11-17 | 1980-06-13 | Catalyse Soc Prod Francais | CATALYST CONTAINING COPPER OXIDE, ZINC OXIDE AND RARE EARTH, ITS PREPARATION AND ITS USE IN CARBON MONOXIDE CONVERSION REACTIONS |
| DE3005550A1 (en) * | 1980-02-14 | 1981-08-20 | Süd-Chemie AG, 8000 München | METHOD FOR PRODUCING OLEFINS |
| DE3005551A1 (en) * | 1980-02-14 | 1981-08-20 | Süd-Chemie AG, 8000 München | CATALYST FOR THE SYNTHESIS OF METHANOL AND ALCOHOL MIXTURES CONTAINING HIGHER ALCOHOLS |
| US4565803A (en) * | 1983-12-16 | 1986-01-21 | Shell Oil Company | Methanol synthesis catalyst |
| FR2558738B1 (en) * | 1984-01-27 | 1987-11-13 | Inst Francais Du Petrole | PROCESS FOR THE MANUFACTURE OF CATALYSTS CONTAINING COPPER, ZINC AND ALUMINUM FOR USE IN THE PRODUCTION OF METHANOL FROM SYNTHESIS GAS |
| US5254520A (en) * | 1990-09-18 | 1993-10-19 | Csir | Catalyst for the synthesis of methanol |
-
1971
- 1971-10-29 BE BE774745A patent/BE774745A/en unknown
- 1971-10-29 AT AT938271A patent/AT313863B/en not_active IP Right Cessation
- 1971-10-29 DE DE2154074A patent/DE2154074C3/en not_active Expired
- 1971-10-29 NL NL7114914A patent/NL7114914A/xx not_active Application Discontinuation
- 1971-10-30 IT IT30630/71A patent/IT949513B/en active
- 1971-11-01 AU AU35221/71A patent/AU464265B2/en not_active Expired
- 1971-11-01 JP JP8631271A patent/JPS5438081B1/ja active Pending
- 1971-11-01 CA CA126,595A patent/CA988946A/en not_active Expired
- 1971-11-01 GB GB5064971A patent/GB1364096A/en not_active Expired
- 1971-11-01 SE SE7113869A patent/SE371637B/xx unknown
- 1971-11-02 FR FR7139214A patent/FR2113467A5/fr not_active Expired
- 1971-11-02 ES ES396575A patent/ES396575A1/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0047345B1 (en) * | 1980-08-28 | 1983-12-07 | Theodore Oscar Wentworth | Process for the synthesis of methanol from hydrogen and the oxides of carbon using catalysts |
| ES2914350A1 (en) * | 2020-12-09 | 2022-06-09 | Blueplasma Power S L | Device and process to produce dimethyl carbonate (Machine-translation by Google Translate, not legally binding) |
Also Published As
| Publication number | Publication date |
|---|---|
| CA988946A (en) | 1976-05-11 |
| DE2154074B2 (en) | 1981-04-16 |
| DE2154074A1 (en) | 1972-05-04 |
| SE371637B (en) | 1974-11-25 |
| ES396575A1 (en) | 1974-05-16 |
| JPS5438081B1 (en) | 1979-11-19 |
| AU464265B2 (en) | 1975-08-21 |
| AT313863B (en) | 1974-03-11 |
| DE2154074C3 (en) | 1981-12-03 |
| IT949513B (en) | 1973-06-11 |
| NL7114914A (en) | 1972-05-04 |
| AU3522171A (en) | 1973-05-10 |
| FR2113467A5 (en) | 1972-06-23 |
| BE774745A (en) | 1972-05-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0146165B1 (en) | Modified copper- and zinc-containing catalyst and process for producing methanol using said catalyst | |
| EP0296734B1 (en) | Copper catalyst for carbon oxide conversion | |
| US4576968A (en) | Catalyst composition and its use in a process for the production of alcohols from synthesis gas | |
| US4149009A (en) | Process for producing methyl formate | |
| GB1213343A (en) | Catalytic reaction of carbon monoxide with steam | |
| CA1119147A (en) | Method for the preparation of dimethyl ether and catalyst therefor | |
| US2211022A (en) | Hydrogenation of carbon monoxide | |
| GB1471794A (en) | Process for regenerating a solid reactant | |
| US4604375A (en) | Manganese-spinel catalysts in CO/H2 olefin synthesis | |
| EP0101645B1 (en) | Catalytic process for the production of methanol | |
| GB1347475A (en) | Process for increasing the activity of supported catalysts | |
| GB1364096A (en) | Process for the production of methanol and catalyst therefor | |
| EP0320301A2 (en) | Process for preparation of hydrocarbons | |
| US4181630A (en) | Catalyst for synthesis of methanol | |
| US1746781A (en) | Catalyst and catalytic process | |
| CN111992209A (en) | Catalyst for synthesizing dimethyl oxalate and preparation method and application thereof | |
| CA1259632A (en) | Catalytic reduction process | |
| Matsuura et al. | Oxidative coupling of methane over lithium-promoted zinc oxide catalyst | |
| GB1364001A (en) | Oxidation of ammonia | |
| US4203870A (en) | Catalyst for hydrogenation of glycolic acid | |
| US2363739A (en) | Production of hydrocarbons | |
| GB2121412A (en) | Process for preparing alcohols | |
| JPS62503100A (en) | Synthesis gas conversion catalysts, their production and their use | |
| JPH0615041B2 (en) | Ammonia production catalyst and method for preparing the same | |
| SU133890A1 (en) | The method of obtaining higher alkylamines |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |