GB1286224A - Process for producing acetic acid - Google Patents
Process for producing acetic acidInfo
- Publication number
- GB1286224A GB1286224A GB2207771A GB2207771A GB1286224A GB 1286224 A GB1286224 A GB 1286224A GB 2207771 A GB2207771 A GB 2207771A GB 2207771 A GB2207771 A GB 2207771A GB 1286224 A GB1286224 A GB 1286224A
- Authority
- GB
- United Kingdom
- Prior art keywords
- rhodium
- halogen
- catalyst
- rhcl
- halides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 6
- 239000010948 rhodium Substances 0.000 abstract 16
- 229910052703 rhodium Inorganic materials 0.000 abstract 9
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 6
- 229910052736 halogen Inorganic materials 0.000 abstract 6
- -1 Rh(SO 4 ) 3 Chemical class 0.000 abstract 5
- 150000002367 halogens Chemical class 0.000 abstract 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- TYLYVJBCMQFRCB-UHFFFAOYSA-K trichlororhodium;trihydrate Chemical compound O.O.O.[Cl-].[Cl-].[Cl-].[Rh+3] TYLYVJBCMQFRCB-UHFFFAOYSA-K 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- FERQZYSWBVOPNX-UHFFFAOYSA-N carbonyl dichloride;rhodium;triphenylphosphane Chemical compound [Rh].ClC(Cl)=O.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 FERQZYSWBVOPNX-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010574 gas phase reaction Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 150000004694 iodide salts Chemical class 0.000 abstract 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1601870A JPS493513B1 (enrdf_load_stackoverflow) | 1970-02-25 | 1970-02-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1286224A true GB1286224A (en) | 1972-08-23 |
Family
ID=11904819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2207771A Expired GB1286224A (en) | 1970-02-25 | 1971-04-19 | Process for producing acetic acid |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS493513B1 (enrdf_load_stackoverflow) |
| CA (1) | CA930373A (enrdf_load_stackoverflow) |
| DE (1) | DE2109025C3 (enrdf_load_stackoverflow) |
| FR (1) | FR2079035A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1286224A (enrdf_load_stackoverflow) |
| NL (1) | NL7102152A (enrdf_load_stackoverflow) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0060695A1 (en) * | 1981-03-13 | 1982-09-22 | BP Chemicals Limited | Process for the coproduction of a C2 to C10 monocarboxylic acid and formic acid |
| EP0109212A1 (en) * | 1982-11-04 | 1984-05-23 | BP Chemicals Limited | Process for the preparation of acids |
| EP0135286A1 (en) * | 1983-07-15 | 1985-03-27 | BP Chemicals Limited | Production of carboxylic acids |
| WO1985002400A1 (en) * | 1983-12-02 | 1985-06-06 | Union Carbide Corporation | Process for producing organic acids |
| EP0146823A1 (en) * | 1983-12-02 | 1985-07-03 | Union Carbide Corporation | Production of carboxylic acids from organic formate esters |
| GB2156815A (en) * | 1984-04-05 | 1985-10-16 | Daicel Chem | Process for preparing acetic acid |
| EP0158720A1 (en) * | 1983-12-02 | 1985-10-23 | Union Carbide Corporation | Synergistic production of carboxylic acids from organic formate esters |
| US4562284A (en) * | 1983-03-02 | 1985-12-31 | Shell Oil Company | Process for the preparation of carboxylic acids |
| US4613693A (en) * | 1981-03-13 | 1986-09-23 | Bp Chemicals Limited | Process for the co-production of a C2 to C10 monocarboxylic acid and formic acid |
| US4670570A (en) * | 1984-07-20 | 1987-06-02 | Union Carbide Corporation | Production of carboxylic acids from alcohols using rhodium complex catalysts |
| US4918226A (en) * | 1980-08-04 | 1990-04-17 | Exxon Research And Engineering Company | Process for converting formate esters to carboxylic acids |
| US4927967A (en) * | 1984-07-20 | 1990-05-22 | Union Carbide Chemicals And Plastics Company Inc. | Production of carboxylic acids from organic formate esters using rhodium complex catalysts |
| US4990654A (en) * | 1984-08-16 | 1991-02-05 | Union Carbide Chemicals And Plastics Company Inc. | Production of acetate esters from alcohols using rhodium complex catalysts |
| US5202468A (en) * | 1988-04-25 | 1993-04-13 | Sollac | Process for producing methyl acetate from methyl formate |
| US5344972A (en) * | 1979-12-13 | 1994-09-06 | Mitsubishi Gas Chemical Company, Inc. | Process for producing acetic acid |
| US10196339B2 (en) * | 2014-12-29 | 2019-02-05 | Korea Research Institute Of Chemical Technology | Rh/WxC heterogeneous catalyst for preparing acetic acid by carbonylation reaction |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5660223U (enrdf_load_stackoverflow) * | 1979-10-13 | 1981-05-22 | ||
| DE3333317A1 (de) * | 1983-09-15 | 1985-03-28 | Chemische Werke Hüls AG, 4370 Marl | Katalysatorsystem und verfahren zur herstellung von essigsaeure durch katalytische umlagerung von ameisensaeuremethylester |
| FR2630437B1 (fr) * | 1988-04-25 | 1990-08-24 | Lorraine Laminage | Procede de preparation d'acetate de methyle a partir de formiate de methyle |
-
1970
- 1970-02-25 JP JP1601870A patent/JPS493513B1/ja active Pending
-
1971
- 1971-02-18 NL NL7102152A patent/NL7102152A/xx unknown
- 1971-02-22 CA CA105980A patent/CA930373A/en not_active Expired
- 1971-02-24 FR FR7106347A patent/FR2079035A5/fr not_active Expired
- 1971-02-25 DE DE19712109025 patent/DE2109025C3/de not_active Expired
- 1971-04-19 GB GB2207771A patent/GB1286224A/en not_active Expired
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5344972A (en) * | 1979-12-13 | 1994-09-06 | Mitsubishi Gas Chemical Company, Inc. | Process for producing acetic acid |
| US4918226A (en) * | 1980-08-04 | 1990-04-17 | Exxon Research And Engineering Company | Process for converting formate esters to carboxylic acids |
| US4613693A (en) * | 1981-03-13 | 1986-09-23 | Bp Chemicals Limited | Process for the co-production of a C2 to C10 monocarboxylic acid and formic acid |
| EP0060695A1 (en) * | 1981-03-13 | 1982-09-22 | BP Chemicals Limited | Process for the coproduction of a C2 to C10 monocarboxylic acid and formic acid |
| US4853482A (en) * | 1982-11-04 | 1989-08-01 | Bp Chemicals Limited | Process for the preparation of acids |
| EP0109212A1 (en) * | 1982-11-04 | 1984-05-23 | BP Chemicals Limited | Process for the preparation of acids |
| US4562284A (en) * | 1983-03-02 | 1985-12-31 | Shell Oil Company | Process for the preparation of carboxylic acids |
| EP0135286A1 (en) * | 1983-07-15 | 1985-03-27 | BP Chemicals Limited | Production of carboxylic acids |
| US5047583A (en) * | 1983-07-15 | 1991-09-10 | Bp Chemicals Limited | Production of carboxylic acids |
| WO1985002400A1 (en) * | 1983-12-02 | 1985-06-06 | Union Carbide Corporation | Process for producing organic acids |
| EP0146823A1 (en) * | 1983-12-02 | 1985-07-03 | Union Carbide Corporation | Production of carboxylic acids from organic formate esters |
| EP0144949A3 (en) * | 1983-12-02 | 1985-07-17 | Union Carbide Corporation | Process for producing organic acids |
| EP0158720A1 (en) * | 1983-12-02 | 1985-10-23 | Union Carbide Corporation | Synergistic production of carboxylic acids from organic formate esters |
| US4996357A (en) * | 1984-04-05 | 1991-02-26 | Daicel Chemical Industries, Ltd. | Process for preparing acetic acid |
| GB2156815A (en) * | 1984-04-05 | 1985-10-16 | Daicel Chem | Process for preparing acetic acid |
| US4927967A (en) * | 1984-07-20 | 1990-05-22 | Union Carbide Chemicals And Plastics Company Inc. | Production of carboxylic acids from organic formate esters using rhodium complex catalysts |
| US4670570A (en) * | 1984-07-20 | 1987-06-02 | Union Carbide Corporation | Production of carboxylic acids from alcohols using rhodium complex catalysts |
| US4990654A (en) * | 1984-08-16 | 1991-02-05 | Union Carbide Chemicals And Plastics Company Inc. | Production of acetate esters from alcohols using rhodium complex catalysts |
| US5202468A (en) * | 1988-04-25 | 1993-04-13 | Sollac | Process for producing methyl acetate from methyl formate |
| US10196339B2 (en) * | 2014-12-29 | 2019-02-05 | Korea Research Institute Of Chemical Technology | Rh/WxC heterogeneous catalyst for preparing acetic acid by carbonylation reaction |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2109025C3 (de) | 1979-04-19 |
| FR2079035A5 (enrdf_load_stackoverflow) | 1971-11-05 |
| DE2109025B2 (de) | 1978-08-24 |
| DE2109025A1 (enrdf_load_stackoverflow) | 1971-09-09 |
| CA930373A (en) | 1973-07-17 |
| JPS493513B1 (enrdf_load_stackoverflow) | 1974-01-26 |
| NL7102152A (enrdf_load_stackoverflow) | 1971-08-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |