CA930373A - Rhodium-catalyzed halogen-promoted preparation of acetic acid from methyl formate - Google Patents

Rhodium-catalyzed halogen-promoted preparation of acetic acid from methyl formate

Info

Publication number
CA930373A
CA930373A CA105980A CA105980A CA930373A CA 930373 A CA930373 A CA 930373A CA 105980 A CA105980 A CA 105980A CA 105980 A CA105980 A CA 105980A CA 930373 A CA930373 A CA 930373A
Authority
CA
Canada
Prior art keywords
rhodium
acetic acid
methyl formate
catalyzed halogen
promoted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA105980A
Other languages
English (en)
Other versions
CA105980S (en
Inventor
Sato Jiro
Hamaoka Tatsunori
Wakamatsu Hachiro
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Application granted granted Critical
Publication of CA930373A publication Critical patent/CA930373A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA105980A 1970-02-25 1971-02-22 Rhodium-catalyzed halogen-promoted preparation of acetic acid from methyl formate Expired CA930373A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1601870A JPS493513B1 (enrdf_load_stackoverflow) 1970-02-25 1970-02-25

Publications (1)

Publication Number Publication Date
CA930373A true CA930373A (en) 1973-07-17

Family

ID=11904819

Family Applications (1)

Application Number Title Priority Date Filing Date
CA105980A Expired CA930373A (en) 1970-02-25 1971-02-22 Rhodium-catalyzed halogen-promoted preparation of acetic acid from methyl formate

Country Status (6)

Country Link
JP (1) JPS493513B1 (enrdf_load_stackoverflow)
CA (1) CA930373A (enrdf_load_stackoverflow)
DE (1) DE2109025C3 (enrdf_load_stackoverflow)
FR (1) FR2079035A5 (enrdf_load_stackoverflow)
GB (1) GB1286224A (enrdf_load_stackoverflow)
NL (1) NL7102152A (enrdf_load_stackoverflow)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5660223U (enrdf_load_stackoverflow) * 1979-10-13 1981-05-22
JPS5683439A (en) * 1979-12-13 1981-07-08 Mitsubishi Gas Chem Co Inc Preparation of acetic acid
US4918226A (en) * 1980-08-04 1990-04-17 Exxon Research And Engineering Company Process for converting formate esters to carboxylic acids
US4613693A (en) * 1981-03-13 1986-09-23 Bp Chemicals Limited Process for the co-production of a C2 to C10 monocarboxylic acid and formic acid
EP0060695B1 (en) * 1981-03-13 1985-02-13 BP Chemicals Limited Process for the coproduction of a c2 to c10 monocarboxylic acid and formic acid
DE3371779D1 (en) * 1982-11-04 1987-07-02 Bp Chem Int Ltd Process for the preparation of acids
CA1226300A (en) * 1983-03-02 1987-09-01 Eit Drent Process for the preparation of carboxylic acids
GB8319184D0 (en) * 1983-07-15 1983-08-17 Bp Chem Int Ltd Carboxylic acids
DE3333317A1 (de) * 1983-09-15 1985-03-28 Chemische Werke Hüls AG, 4370 Marl Katalysatorsystem und verfahren zur herstellung von essigsaeure durch katalytische umlagerung von ameisensaeuremethylester
CA1231964A (en) * 1983-12-02 1988-01-26 David J. Schreck Synergistic production of carboxylic acids from organic formate esters
CA1231967A (en) * 1983-12-02 1988-01-26 Richard W. Wegman Production of carboxylic acids from organic formate esters
DE3468015D1 (en) * 1983-12-02 1988-01-21 Union Carbide Corp Process for producing organic acids
JPS60214756A (ja) * 1984-04-05 1985-10-28 Daicel Chem Ind Ltd 酢酸の製造方法
CA1237728A (en) * 1984-07-20 1988-06-07 Anthony G. Abatjoglou Production of carboxylic acids from alcohols using rhodium complex catalysts
US4927967A (en) * 1984-07-20 1990-05-22 Union Carbide Chemicals And Plastics Company Inc. Production of carboxylic acids from organic formate esters using rhodium complex catalysts
US4990654A (en) * 1984-08-16 1991-02-05 Union Carbide Chemicals And Plastics Company Inc. Production of acetate esters from alcohols using rhodium complex catalysts
FR2630437B1 (fr) * 1988-04-25 1990-08-24 Lorraine Laminage Procede de preparation d'acetate de methyle a partir de formiate de methyle
US5202468A (en) * 1988-04-25 1993-04-13 Sollac Process for producing methyl acetate from methyl formate
KR101667223B1 (ko) * 2014-12-29 2016-10-18 한국화학연구원 카보닐화 반응에 의한 초산 제조용 Ｒｈ/ＷｘＣ 불균일 촉매

Also Published As

Publication number Publication date
DE2109025C3 (de) 1979-04-19
FR2079035A5 (enrdf_load_stackoverflow) 1971-11-05
DE2109025B2 (de) 1978-08-24
DE2109025A1 (enrdf_load_stackoverflow) 1971-09-09
JPS493513B1 (enrdf_load_stackoverflow) 1974-01-26
NL7102152A (enrdf_load_stackoverflow) 1971-08-27
GB1286224A (en) 1972-08-23

Similar Documents

Publication Publication Date Title
CA930373A (en) Rhodium-catalyzed halogen-promoted preparation of acetic acid from methyl formate
CA934392A (en) Process for the preparation of unsaturated carbonyl compounds
CA956971A (en) Process for the preparation of unsaturated carbonyl compounds
CA981280A (en) Production of acetic acid from methyl formate
PH9953A (en) Process for the preparation of(4-pyridylthio)acetic acid
CA952918A (en) Process for the preparation of acetic acid
CA971974A (en) Intermediates for preparing phenylalkanoic acids
CA961856A (en) PREPARATION OF TERTIARY ALKYL ESTERS OF .alpha.-ISOTHIOCYANATE CARBOXYLIC ACIDS
CA846184A (en) Derivatives of acetic acid
CA854727A (en) Derivatives of acetic acid
CA846191A (en) Derivatives of acetic acid
CA854236A (en) Preparation of propionic acids
CA960695A (en) Process for the preparation of aldehydes
CA958032A (en) Process for preparing 1-benzylidene-3-indenyl acetic acids
CA939681A (en) Process for the preparation of carboxylic acids
CA839757A (en) Process for the preparation of 2,3-dichloro-4-butyryl-phenoxy acetic acid
CA859744A (en) Indolyl acetic acid derivatives
CA831540A (en) Process for the preparation of carboxylic acid esters
CA938302A (en) Process for the preparation of 1-indancarboxylic acids
CA850678A (en) Preparation of diorganoantimony carboxylates
AU294889B2 (en) Derivatives of acetic acid anda process for their preparation
CA845129A (en) Process for preparing indolyl acetic acids
CA859738A (en) Process for preparing indolyl acetic acids
CA845128A (en) Process for preparing indolyl acetic acids
CA845105A (en) Process for preparing indolyl acetic acids