GB1286224A - Process for producing acetic acid - Google Patents

Process for producing acetic acid

Info

Publication number
GB1286224A
GB1286224A GB2207771A GB2207771A GB1286224A GB 1286224 A GB1286224 A GB 1286224A GB 2207771 A GB2207771 A GB 2207771A GB 2207771 A GB2207771 A GB 2207771A GB 1286224 A GB1286224 A GB 1286224A
Authority
GB
United Kingdom
Prior art keywords
rhodium
halogen
catalyst
rhcl
halides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2207771A
Inventor
Hachiro Wakamatsu
Jiro Sato
Tatsunori Hamaoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Publication of GB1286224A publication Critical patent/GB1286224A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1286224 Catalysts AJINOMOTO CO Inc 19 April 1971 [25 Feb 1970] 22077/71 Heading B1E [Also in Division C2] A catalyst system comprising rhodium or a rhodium containing catalyst and a halogen or halogen containing promotor is used for the preparation of acetic acid by heating methyl formate. Rhodium metal, oxide, hydroxide, halide, inorganic or organic salts, e.g. Rh(SO 4 ) 3 , Rh(NO 3 ) 3 , and Rh(C 17 H 35 COO) 3 and organorhodium compounds, e.g. Rh 2 (CO 4 ) Cl 2 , Rh 2 (CO) 8 , Rh(CO)Cl[(C 6 H 5 ) 3 P] 2 , RhCl[(C 6 H 5 ) 3 P] 2 (CH 3 I) 2 , RhCl[(C 6 H 5 ) 3 P] 3 H 2 , RhCl(CO)[(C 6 H 5 ) 3 AS] 2 , RhI(CO)[(C 6 H 5 ) 3 Sb] 2 , and K 4 Rh 2 Br 2 (SnBr 3 ) 4 , may be used and the halogen may be free or as hydrogen halides, alkyl halides, or amonium and stibonium halides. Iodides are preferred and a ratio of rhodium to halogen of 1-1000 atoms halogen per atom of rhodium may be used. A carrier such as active carbon, alumina, silica gel, silica-alumina, magnesia or zeolitic molecular sieves may support the rhodium catalyst in gas phase reactions. The halogen promoter may be incorporated in the carrier supported rhodium catalyst or separately charged in the gaseous state to the reactor. Examples describe the use of bis(triphenylphosphine) rhodium carbonyl chloride, rhodium chloride trihydrate, dirhodium-tetracarbonyldichloride with methyl iodide and the preparation of an active carbon supported rhodium catalyst by calcining rhodium chloride trihydrate and bis(triphenylhposphine) rhodium carbonyl on the carbon bed.
GB2207771A 1970-02-25 1971-04-19 Process for producing acetic acid Expired GB1286224A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1601870A JPS493513B1 (en) 1970-02-25 1970-02-25

Publications (1)

Publication Number Publication Date
GB1286224A true GB1286224A (en) 1972-08-23

Family

ID=11904819

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2207771A Expired GB1286224A (en) 1970-02-25 1971-04-19 Process for producing acetic acid

Country Status (6)

Country Link
JP (1) JPS493513B1 (en)
CA (1) CA930373A (en)
DE (1) DE2109025C3 (en)
FR (1) FR2079035A5 (en)
GB (1) GB1286224A (en)
NL (1) NL7102152A (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0060695A1 (en) * 1981-03-13 1982-09-22 BP Chemicals Limited Process for the coproduction of a C2 to C10 monocarboxylic acid and formic acid
EP0109212A1 (en) * 1982-11-04 1984-05-23 BP Chemicals Limited Process for the preparation of acids
EP0135286A1 (en) * 1983-07-15 1985-03-27 BP Chemicals Limited Production of carboxylic acids
WO1985002400A1 (en) * 1983-12-02 1985-06-06 Union Carbide Corporation Process for producing organic acids
EP0146823A1 (en) * 1983-12-02 1985-07-03 Union Carbide Corporation Production of carboxylic acids from organic formate esters
GB2156815A (en) * 1984-04-05 1985-10-16 Daicel Chem Process for preparing acetic acid
EP0158720A1 (en) * 1983-12-02 1985-10-23 Union Carbide Corporation Synergistic production of carboxylic acids from organic formate esters
US4562284A (en) * 1983-03-02 1985-12-31 Shell Oil Company Process for the preparation of carboxylic acids
US4613693A (en) * 1981-03-13 1986-09-23 Bp Chemicals Limited Process for the co-production of a C2 to C10 monocarboxylic acid and formic acid
US4670570A (en) * 1984-07-20 1987-06-02 Union Carbide Corporation Production of carboxylic acids from alcohols using rhodium complex catalysts
US4918226A (en) * 1980-08-04 1990-04-17 Exxon Research And Engineering Company Process for converting formate esters to carboxylic acids
US4927967A (en) * 1984-07-20 1990-05-22 Union Carbide Chemicals And Plastics Company Inc. Production of carboxylic acids from organic formate esters using rhodium complex catalysts
US4990654A (en) * 1984-08-16 1991-02-05 Union Carbide Chemicals And Plastics Company Inc. Production of acetate esters from alcohols using rhodium complex catalysts
US5202468A (en) * 1988-04-25 1993-04-13 Sollac Process for producing methyl acetate from methyl formate
US5344972A (en) * 1979-12-13 1994-09-06 Mitsubishi Gas Chemical Company, Inc. Process for producing acetic acid
US10196339B2 (en) * 2014-12-29 2019-02-05 Korea Research Institute Of Chemical Technology Rh/WxC heterogeneous catalyst for preparing acetic acid by carbonylation reaction

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5660223U (en) * 1979-10-13 1981-05-22
DE3333317A1 (en) * 1983-09-15 1985-03-28 Chemische Werke Hüls AG, 4370 Marl CATALYTIC SYSTEM AND METHOD FOR PRODUCING ACETIC ACID BY CATALYTIC REVERSE OF METAL METALYLATE
FR2630437B1 (en) * 1988-04-25 1990-08-24 Lorraine Laminage PROCESS FOR THE PREPARATION OF METHYL ACETATE FROM METHYL FORMIATE

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5344972A (en) * 1979-12-13 1994-09-06 Mitsubishi Gas Chemical Company, Inc. Process for producing acetic acid
US4918226A (en) * 1980-08-04 1990-04-17 Exxon Research And Engineering Company Process for converting formate esters to carboxylic acids
EP0060695A1 (en) * 1981-03-13 1982-09-22 BP Chemicals Limited Process for the coproduction of a C2 to C10 monocarboxylic acid and formic acid
US4613693A (en) * 1981-03-13 1986-09-23 Bp Chemicals Limited Process for the co-production of a C2 to C10 monocarboxylic acid and formic acid
EP0109212A1 (en) * 1982-11-04 1984-05-23 BP Chemicals Limited Process for the preparation of acids
US4853482A (en) * 1982-11-04 1989-08-01 Bp Chemicals Limited Process for the preparation of acids
US4562284A (en) * 1983-03-02 1985-12-31 Shell Oil Company Process for the preparation of carboxylic acids
EP0135286A1 (en) * 1983-07-15 1985-03-27 BP Chemicals Limited Production of carboxylic acids
US5047583A (en) * 1983-07-15 1991-09-10 Bp Chemicals Limited Production of carboxylic acids
EP0146823A1 (en) * 1983-12-02 1985-07-03 Union Carbide Corporation Production of carboxylic acids from organic formate esters
EP0158720A1 (en) * 1983-12-02 1985-10-23 Union Carbide Corporation Synergistic production of carboxylic acids from organic formate esters
EP0144949A3 (en) * 1983-12-02 1985-07-17 Union Carbide Corporation Process for producing organic acids
EP0144949A2 (en) * 1983-12-02 1985-06-19 Union Carbide Corporation Process for producing organic acids
WO1985002400A1 (en) * 1983-12-02 1985-06-06 Union Carbide Corporation Process for producing organic acids
GB2156815A (en) * 1984-04-05 1985-10-16 Daicel Chem Process for preparing acetic acid
US4996357A (en) * 1984-04-05 1991-02-26 Daicel Chemical Industries, Ltd. Process for preparing acetic acid
US4670570A (en) * 1984-07-20 1987-06-02 Union Carbide Corporation Production of carboxylic acids from alcohols using rhodium complex catalysts
US4927967A (en) * 1984-07-20 1990-05-22 Union Carbide Chemicals And Plastics Company Inc. Production of carboxylic acids from organic formate esters using rhodium complex catalysts
US4990654A (en) * 1984-08-16 1991-02-05 Union Carbide Chemicals And Plastics Company Inc. Production of acetate esters from alcohols using rhodium complex catalysts
US5202468A (en) * 1988-04-25 1993-04-13 Sollac Process for producing methyl acetate from methyl formate
US10196339B2 (en) * 2014-12-29 2019-02-05 Korea Research Institute Of Chemical Technology Rh/WxC heterogeneous catalyst for preparing acetic acid by carbonylation reaction

Also Published As

Publication number Publication date
DE2109025C3 (en) 1979-04-19
JPS493513B1 (en) 1974-01-26
DE2109025B2 (en) 1978-08-24
NL7102152A (en) 1971-08-27
DE2109025A1 (en) 1971-09-09
CA930373A (en) 1973-07-17
FR2079035A5 (en) 1971-11-05

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee