GB1282950A - Process for manufacturing gels containing iron and molybdenum and the uses thereof - Google Patents

Process for manufacturing gels containing iron and molybdenum and the uses thereof

Info

Publication number
GB1282950A
GB1282950A GB561870A GB561870A GB1282950A GB 1282950 A GB1282950 A GB 1282950A GB 561870 A GB561870 A GB 561870A GB 561870 A GB561870 A GB 561870A GB 1282950 A GB1282950 A GB 1282950A
Authority
GB
United Kingdom
Prior art keywords
molybdenum
compounds
compound
atomic ratio
containing iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB561870A
Inventor
Philippe Courty
Hubert Ajot
Bernard Delmon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of GB1282950A publication Critical patent/GB1282950A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/0018—Mixed oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/02—Amorphous compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Optics & Photonics (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Optical Filters (AREA)
  • Compounds Of Iron (AREA)

Abstract

1282950 Gels containing iron and molybdenum INSTITUT FRANCAIS DU PETROLE DES CARBURANTS ET LUBRIFIANTS 5 Feb 1970 [7 Feb 1969] 5618/70 Heading C1A A process for producing a transparent gel containing iron and molybdenum comprises mixing at least one of molybdic anhydride or a salt comprising a molybdenum containing anion with the exception of alkali metal molybdates with at least one ferric compound and, optionally, at least one compound containing, in simple cationic form, a metal M selected from Co, Ni, Mn, Cr, Sc, Y, and the rare earth metals (At. Nos. 57-71 inc.), in the presence of a quantity of water not greater than that required to form individual saturated aqueous solutions of the compounds, and at a temperature between the freezing temperature of the saturated solutions of the compounds and 150‹ C., the compounds being used in such amounts that the atomic ratio M/(Fe + M) is from 0 to 0À5 and the atomic ratio Mo/(Fe+M) is from 0À4 to 5. The Mo compound may also be mixed with at least one compound containing, in the form of an oxygencontaining complex, a metal N selected from, Cr, W, Mn, V and U, the compounds being used in such amounts that the ratios M/(Fe+M) and N(Mo+N) are 0 to 5 and the ratio (Mo+N)/ (Fe+M) is 0À4 to 5. The gels in which the atomic ratio Mo/(Fe+M) or (Mo+N)/(Fe+M) is from 1À5 to 5 may be heated to from 300‹ to 500‹ C. to produce a mixed oxide catalyst which may be used in the oxidation of an alcohol to an aldehyde.
GB561870A 1969-02-07 1970-02-05 Process for manufacturing gels containing iron and molybdenum and the uses thereof Expired GB1282950A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR6902995A FR2031818A6 (en) 1969-02-07 1969-02-07

Publications (1)

Publication Number Publication Date
GB1282950A true GB1282950A (en) 1972-07-26

Family

ID=9028817

Family Applications (1)

Application Number Title Priority Date Filing Date
GB561870A Expired GB1282950A (en) 1969-02-07 1970-02-05 Process for manufacturing gels containing iron and molybdenum and the uses thereof

Country Status (15)

Country Link
JP (1) JPS505679B1 (en)
AU (1) AU1100270A (en)
BE (1) BE745203A (en)
CA (1) CA949543A (en)
CH (1) CH521788A (en)
CS (1) CS170143B2 (en)
DE (2) DE2039162A1 (en)
ES (1) ES376282A1 (en)
FR (1) FR2031818A6 (en)
GB (1) GB1282950A (en)
HU (1) HU168924B (en)
LU (1) LU60306A1 (en)
NL (1) NL7001762A (en)
RO (1) RO58832A7 (en)
SU (1) SU504457A3 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5017542A (en) * 1988-08-16 1991-05-21 Basf Aktiengesellschaft Catalyst for the oxidation and ammonoxidation of α-, β-unsaturated hydrocarbons
WO2000041810A1 (en) * 1999-01-15 2000-07-20 Akzo Nobel N.V. A mixed metal catalyst composition, its preparation and use
EP1674156A1 (en) 2004-12-23 2006-06-28 Süd Chemie - Catalysts Italia S.R.L. Method for preparing a catalyst for oxidation of methanol to formaldehyde
US7229548B2 (en) 1997-07-15 2007-06-12 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US7232515B1 (en) 1997-07-15 2007-06-19 Exxonmobil Research And Engineering Company Hydrofining process using bulk group VIII/Group VIB catalysts
US7288182B1 (en) 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US7513989B1 (en) 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
EP2103347A1 (en) 2008-03-17 2009-09-23 ExxonMobil Research and Engineering Company Hydrocarbon hydroprocessing using bulk catalyst composition

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2243021B1 (en) * 1973-09-12 1978-02-17 Inst Francais Du Petrole
JPS5641974U (en) * 1979-09-10 1981-04-17
DE19506843A1 (en) * 1995-02-28 1996-08-29 Studiengesellschaft Kohle Mbh Microporous amorphous mixed metal oxides for shape-selective catalysis
DE19957416A1 (en) * 1999-11-29 2001-06-13 Aventis Res & Tech Gmbh & Co Process for the catalytic production of halobenzaldehydes and catalysts for carrying out the process
ITMI20042456A1 (en) * 2004-12-22 2005-03-22 Sued Chemie Mt Srl CATALYSTS FOR METHANOL OXIDATION IN FORMALDEHYDE
RU2695617C1 (en) * 2019-05-24 2019-07-24 Акционерное общество "Техметалл-2002" Method of producing a catalyst for oxidising methanol to formaldehyde

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5017542A (en) * 1988-08-16 1991-05-21 Basf Aktiengesellschaft Catalyst for the oxidation and ammonoxidation of α-, β-unsaturated hydrocarbons
US7513989B1 (en) 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
US7229548B2 (en) 1997-07-15 2007-06-12 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US7232515B1 (en) 1997-07-15 2007-06-19 Exxonmobil Research And Engineering Company Hydrofining process using bulk group VIII/Group VIB catalysts
US7288182B1 (en) 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
WO2000041810A1 (en) * 1999-01-15 2000-07-20 Akzo Nobel N.V. A mixed metal catalyst composition, its preparation and use
AU761109B2 (en) * 1999-01-15 2003-05-29 Albemarle Netherlands B.V. A mixed metal catalyst composition, its preparation and use
KR100706364B1 (en) * 1999-01-15 2007-04-10 알베마를 네덜란드 비.브이. A mixed metal catalyst composition, its preparation and use
EP1674156A1 (en) 2004-12-23 2006-06-28 Süd Chemie - Catalysts Italia S.R.L. Method for preparing a catalyst for oxidation of methanol to formaldehyde
US7572752B2 (en) 2004-12-23 2009-08-11 Sud-Chemie Catalysts Italia S.R.L. Method for preparing a catalyst for oxidation of methanol to formaldehyde
CN1792444B (en) * 2004-12-23 2011-07-13 舒德化学催化剂意大利有限责任公司 Method for preparing a catalyst for oxidation of methanol to formaldehyde
TWI402101B (en) * 2004-12-23 2013-07-21 Sud Chemie Catalysts Italia S R L Method for preparing catalyst for oxidation of methanol to formaldehyde
EP2103347A1 (en) 2008-03-17 2009-09-23 ExxonMobil Research and Engineering Company Hydrocarbon hydroprocessing using bulk catalyst composition

Also Published As

Publication number Publication date
LU60306A1 (en) 1970-04-06
CS170143B2 (en) 1976-08-27
NL7001762A (en) 1970-08-11
ES376282A1 (en) 1972-06-16
CA949543A (en) 1974-06-18
DE2005099A1 (en) 1970-11-05
RO58832A7 (en) 1975-10-15
SU504457A3 (en) 1976-02-25
BE745203A (en) 1970-07-01
JPS505679B1 (en) 1975-03-06
FR2031818A6 (en) 1970-11-20
HU168924B (en) 1976-08-28
DE2039162A1 (en) 1971-08-26
CH521788A (en) 1972-04-30
AU1100270A (en) 1971-08-05

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee